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Natural gas-fueled vehicles impose unique requirements on exhaust aftertreatment systems. Methane conversion, which is very difficult for conventional automotive catalysts, may be required, depending on future regulatory directions. Three-way converter operating windows for simultaneous conversion of HC, CO, and NOx are considerably more narrow with gas engine exhaust. While several studies have demonstrated acceptable fresh converter performance, aged performance remains a concern. This paper presents the results of a durability study of eight catalytic converters specifically developed for natural gas engines. The converters were aged for 300 hours on a natural gas-fueled 7.0L Chevrolet engine operated at net stoichiometry. Catalyst performance was evaluated using both air/fuel traverse engine tests and FTP vehicle tests. Durability cycle severity and a comparison of results for engine and vehicle tests are discussed.

The UBHC emissions during cold starting need to be controlled in order to meet the future stringent standards. This requires a better understanding of the characteristics of the time resolved UBHC signal measured by a high frequency FID and its phasing with respect to the valve events. The computer program supplied with the instrument and currently used to compute the phase shift has many uncertainties due to the unsteady nature of engine operation during starting. A new technique is developed to measure the in-situ phase shift of the UBHC signal under the transient thermodynamic and dynamic conditions of the engine. The UBHC concentration is measured at two locations in the exhaust manifold of one cylinder in a multicylinder port injected gasoline engine. The two locations are 77 mm apart. The downstream probe is positioned opposite to a solenoid-operated injector which delivers a gaseous jet of hydrocarbon-free nitrogen upon command.

Vacuum insulation and phase-change thermal storage have been used to enhance the heat retention of a prototype catalytic converter. Storing heat in the converter between trips allows exhaust gases to be converted more quickly, significantly reducing cold-start emissions. Using a small metal hydride, the thermal conductance of the vacuum insulation can be varied continuously between 0.49 and 27 W/m2K (R-12 to R-0.2 insulation) to prevent overheating of the catalyst. A prototype was installed in a Dodge Neon with a 2.0-liter engine. Following a standard preconditioning and a 23-hour cold soak, an FTP (Federal Test Procedure) emissions test was performed. Although exhaust temperatures during the preconditioning were not hot enough to melt the phase-change material, the vacuum insulation performed well, resulting in a converter temperature of 146°C after the 23-hour cold soak at 27°C.

An extensive program has been established to screen and evaluate heat- and corrosion-resistant alloys that may have some potential application in emission-control systems anywhere from the exhaust manifold to the tailpipe. The various phases of this program, which include tests conducted in air and controlled exhaust atmospheres at temperatures between 1300-2200°F are described. Some selected test data and the results of metallographic studies are presented to illustrate how representative alloys react to the various test conditions. The characteristics and functions of the basic emission-control devices are reviewed in light of their effect upon materials requirements.