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Diesel injection parameters effect on liquid-phase diesel spray penetration after the end-of-injection (EOI) is investigated in a constant-volume chamber over a range of ambient and injector conditions typical of a diesel engine. Our past work showed that the maximum liquid penetration length of a diesel spray may recede towards the injector after EOI at some conditions. Analysis employing a transient jet entrainment model showed that increased fuel-ambient mixing occurs during the fuel-injection-rate ramp-down as increased ambient-entrainment rates progress downstream (i.e. the entrainment wave), permitting complete fuel vaporization at distances closer to the injector than the quasi-steady liquid length. To clarify the liquid-length recession process, in this study we report Mie-scatter imaging results near EOI over a range of injection pressure, nozzle size, fuel type, and rate-of-injection shape. We then use a transient jet entrainment model for detailed analysis.

The objective of this research is a detailed investigation of unburned hydrocarbon (UHC) in a highly-dilute diesel low temperature combustion (LTC) regime. This research concentrates on understanding the mechanisms that control the formation of UHC via experiments and simulations in a 0.48L signal-cylinder light duty engine operating at 2000 r/min and 5.5 bar IMEP with multiple injections. A multi-gas FTIR along with other gas and smoke emissions instruments are used to measure exhaust UHC species and other emissions. Controlled experiments in the single-cylinder engine are then combined with three computational tools, namely heat release analysis of measured cylinder pressure, analysis of spray trajectory with a phenomenological spray model using in-cylinder thermodynamics [1], and KIVA-3V Chemkin CFD computations recently tested at LTC conditions [2].

Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

Long chain alcohols possess major advantages over the currently used ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. The rapid developments in biofuel technology have made it possible to produce C 4 -C 5 alcohols cost effectively. These higher alcohols could significantly expand the biofuel content and potentially substitute ethanol in future gasoline mixtures. This study characterizes some fundamental properties of a C 5 alcohol, isopentanol, as a fuel for HCCI engines. Wide ranges of engine speed, intake temperature, intake pressure, and equivalence ratio are investigated. Results are presented in comparison with gasoline or ethanol data previously reported. For a given combustion phasing, isopentanol requires lower intake temperatures than gasoline or ethanol at all tested speeds, indicating a higher HCCI reactivity.

Mixture formation in an optically accessible hydrogen-fueled engine was investigated using Planar Laser-Induced Fluorescence (PLIF) of acetone as a fuel tracer. The engine was motored and fueled by direct high-pressure injection. This paper presents the evolution of the spatial distribution of the ensemble-mean equivalence ratio for six different combinations of nozzle design and injector geometry, each for three different injection timings after intake-valve closure. Asymmetric single-hole and 5-hole nozzles as well as symmetric 6-hole and 13-hole nozzles were used. For early injection, the low in-cylinder pressure and density allow the jet to preserve its momentum long enough to undergo extensive jet-wall and (for multi-hole nozzles) jet-jet interaction, but the final mixture is fairly homogeneous. Intermediately timed injection yields inhomogeneous mixtures with surprisingly similar features observed for all multi-hole injectors.

The liquid and vapor-phase spray penetrations of #2 diesel and neat (100%) soybean-derived biodiesel have been studied at late expansion-cycle conditions in a constant-volume optical chamber. In modern diesel engines, late-cycle staged injections may be used to assist in the operation of exhaust stream aftertreatment devices. These late-cycle injections occur well after top-dead-center (TDC), when post-combustion temperatures are relatively high and densities are low. The behavior of diesel sprays under these conditions has not been well-established in the literature. In the current work, high-speed Mie-scatter and schlieren imaging are employed in an optically accessible chamber to characterize the transient and quasi-steady liquid penetration behavior of diesel sprays under conditions relevant for late-cycle post injections, with very low densities (1.2 - 3 kg/m 3 ) and moderately high temperatures (800 - 1400 K).

The influence of soy- and palm-based biofuels on the in-cylinder sources of unburned hydrocarbons (UHC) and carbon monoxide (CO) was investigated in an optically accessible research engine operating in a partially premixed, low-temperature combustion regime. The biofuels were blended with an emissions certification grade diesel fuel and the soy-based biofuel was also tested neat. Cylinder pressure and emissions of UHC, CO, soot, and NOx were obtained to characterize global fuel effects on combustion and emissions. Planar laser-induced fluorescence was used to capture the spatial distribution of fuel and partial oxidation products within the clearance and bowl volumes of the combustion chamber. In addition, late-cycle (30° and 50° aTDC) semi-quantitative CO distributions were measured above the piston within the clearance volume using a deep-UV LIF technique.

The potential of boosted HCCI for achieving high loads has been investigated for intake pressures (Piⁿ) from 100 kPa (naturally aspirated) to 325 kPa absolute. Experiments were conducted in a single-cylinder HCCI research engine (0.98 liters) equipped with a compression-ratio 14 piston at 1200 rpm. The intake charge was fully premixed well upstream of the intake, and the fuel was a research-grade (R+M)/2 = 87-octane gasoline with a composition typical of commercial gasolines. Beginning with Piⁿ = 100 kPa, the intake pressure was systematically increased in steps of 20 - 40 kPa, and for each Piⁿ, the fueling was incrementally increased up to the knock/stability limit, beyond which slight changes in combustion conditions can lead to strong knocking or misfire. A combination of reduced intake temperature and cooled EGR was used to compensate for the pressure-induced enhancement of autoignition and to provide sufficient combustion-phasing retard to control knock.

The characteristics of ethanol autoignition and the associated HCCI performance are examined in this work. The experiments were conducted over wide ranges of engine speed, load and intake boost pressure (Piⁿ) in a single-cylinder HCCI research engine (0.98 liters) with a CR = 14 piston. The data show that pure ethanol is a true single-stage ignition fuel. It does not exhibit low-temperature heat release (LTHR), not even for boosted operation. This makes ethanol uniquely different from conventional distillate fuels and offers several benefits: a) The intake temperature (Tiⁿ) does not have to be adjusted much with changes of engine speed, load and intake boost pressure. b) High Piⁿ can be tolerated without running out of control authority because of an excessively low Tiⁿ requirement. However, by maintaining true single-stage ignition characteristics, ethanol also shows a relatively low temperature-rise rate just prior to its hot ignition point.

The behavior of the engine-out UHC and CO emissions from a light-duty diesel optical engine operating at two PPCI conditions was investigated for fifteen different fuels, including diesel fuels, biofuel blends, n-heptane-iso-octane mixtures, and n-cetane-HMN mixtures. The two highly dilute (9-10% O₂) early direct injection PPCI conditions included a low speed (1500 RPM) and load (3.0 bar IMEP) case~where the UHC and CO have been found to stem from overly-lean fuel-air mixtures~and a condition with a relatively higher speed (2000 RPM) and load (6.0 bar IMEP)~where globally richer mixtures may lead to different sources of UHC and CO. The main objectives of this work were to explore the general behavior of the UHC and CO emissions from early-injection PPCI combustion and to gain an understanding of how fuel properties and engine load affect the engine-out emissions.

This paper first summarizes a new theoretical description that quantifies the effects of real-fluid thermodynamics on liquid fuel injection processes as a function of pressure at typical engine operating conditions. It then focuses on the implications this has on modeling such flows with emphasis on application of the Large Eddy Simulation (LES) technique. The theory explains and quantifies the major differences that occur in the jet dynamics compared to that described by classical spray theory in a manner consistent with experimental observations. In particular, the classical view of spray atomization as an appropriate model at some engine operating conditions is questionable. Instead, non-ideal real-fluid behavior must be taken into account using a multicomponent formulation that applies to hydrocarbon mixtures at high-pressure supercritical conditions.

Measurements of ignition behavior, homogeneous reactor simulations employing detailed kinetics, and quantitative in-cylinder imaging of fuel-air distributions are used to delineate the impact of temperature, dilution, pilot injection mass, and injection pressure on the pilot ignition process. For dilute, low-temperature conditions characterized by a lengthy ignition delay, pilot ignition is impeded by the formation of excessively lean mixture. Under these conditions, smaller pilot mass or higher injection pressures further lengthen the pilot ignition delay. Similarly, excessively rich mixtures formed under relatively short ignition delay conditions typical of conventional diesel combustion will also prolong the ignition delay. In this latter case, smaller pilot mass or higher injection pressures will shorten the ignition delay. The minimum charge temperature required to effect a robust pilot ignition event is strongly dependent on charge O2 concentration.

Fuel tracer-based planar laser-induced fluorescence is used to investigate the vaporization and mixing behavior of pilot injections for variations in pilot mass of 1-4 mg, and for two injection pressures, two near-TDC ambient temperatures, and two swirl ratios. The fluorescent tracer employed, 1-methylnaphthalene, permits a mixture of the diesel primary reference fuels, n-hexadecane and heptamethylnonane, to be used as the base fuel. With a near-TDC injection timing of −15°CA, pilot injection fuel is found to penetrate to the bowl rim wall for even the smallest injection quantity, where it rapidly forms fuel-lean mixture. With increased pilot mass, there is greater penetration and fuel-rich mixtures persist well beyond the expected pilot ignition delay period. Significant jet-to-jet variations in fuel distribution due to differences in the individual jet trajectories (included angle) are also observed.

This work contributes to the understanding of physical mechanisms that control flashback, or more appropriately combustion recession, in diesel sprays. A large dataset, comprising many fuels, injection pressures, ambient temperatures, ambient oxygen concentrations, ambient densities, and nozzle diameters is used to explore experimental trends for the behavior of combustion recession. Then, a reduced-order model, capable of modeling non-reacting and reacting conditions, is used to help interpret the experimental trends. Finally, the reduced-order model is used to predict how a controlled ramp-down rate-of-injection can enhance the likelihood of combustion recession for conditions that would not normally exhibit combustion recession. In general, fuel, ambient conditions, and the end-of-injection transient determine the success or failure of combustion recession.

Low-temperature gasoline combustion (LTGC), based on the compression ignition of a premixed or partially premixed dilute charge, can provide thermal efficiencies (TE) and maximum loads comparable to those of turbo-charged diesel engines, and ultra-low NOx and particulate emissions. Intake boosting is key to achieving high loads with dilute combustion, and it also enhances the fuel's autoignition reactivity, reducing the required intake heating or hot residuals. These effects have the advantages of increasing TE and charge density, allowing greater timing retard with good stability, and making the fuel ϕ- sensitive so that partial fuel stratification (PFS) can be applied for higher loads and further TE improvements. However, at high boost the autoignition reactivity enhancement can become excessive, and substantial amounts of EGR are required to prevent overly advanced combustion.

Well-mixed lean SI engine operation can provide improvements of the fuel economy relative to that of traditional well-mixed stoichiometric SI operation. This work examines the use of two methods for improving the stability of lean operation, namely multi-pulse transient plasma ignition and intake air preheating. These two methods are compared to standard SI operation using a conventional high-energy inductive ignition system without intake air preheating. E85 is the fuel chosen for this study. The multi-pulse transient plasma ignition system utilizes custom electronics to generate 10 kHz bursts of 10 ultra-short (12ns), high-amplitude pulses (200 A). These pulses were applied to a custom spark plug with a semi-open ignition cavity. High-speed imaging reveals that ignition in this cavity generates a turbulent jet-like early flame spread that speeds up the transition from ignition to the main combustion event.

A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate.

Spark-ignition (SI) engine efficiency is typically limited by fuel auto-ignition resistance, which is described in practice by the Research Octane Number (RON) and the Motor Octane Number (MON). The goal of this work is to assess whether fuel properties (i.e. RON, MON, and heat of vaporization) are sufficient to describe the antiknock behavior of varying gasoline formulations in modern engines. To this end, the auto-ignition resistance of three compositionally dissimilar gasoline-like fuels with identical RON values and varying or non-varying MON values were evaluated in a modern, prototype, 12:1 compression ratio, high-swirl (by nature of intake valve deactivation), directly injected spark ignition (DISI) engine at 1400 RPM. The three gasolines are an alkylate blend (RON=98, MON=97), a blend with high aromatic content (RON=98, MON=88), and a blend of 30% ethanol by volume with a gasoline BOB (RON=98, MON=87; see Table 2 for details).

Well-mixed lean or dilute SI engine operation can provide efficiency improvements relative to that of traditional well-mixed stoichiometric SI operation. However, the realized gains depend on the ability to ensure stable, complete and fast combustion. In this work, the influence of fuel type is examined for gasoline, E30 and E85. Several enabling techniques are compared. For enhanced ignition stability, a multi-pulse (MP) transient plasma ignition system is compared to a conventional high-energy inductive spark ignition system. Combined effects of fuel type and intake-gas preheating are examined. Also, the effects of dilution type (air or N2-simulated EGR) on lean efficiency gains and stability limits are clarified. The largest efficiency improvement is found for lean gasoline operation using intake preheating, showing the equivalent of a 20% fuel-economy gain relative to traditional non-dilute stoichiometric operation.

Negative Valve Overlap (NVO) is a potential control strategy for enabling Low-Temperature Gasoline Combustion (LTGC) at low loads. While the thermal effects of NVO fueling on main combustion are well-understood, the chemical effects of NVO in-cylinder fuel reforming have not been extensively studied. The objective of this work is to examine the effects of fuel molecular structure on NVO fuel reforming using gas sampling and detailed speciation by gas chromatography. Engine gas samples were collected from a single-cylinder research engine at the end of the NVO period using a custom dump-valve apparatus. Six fuel components were studied at two injection timings: (1) iso-octane, (2) n-heptane, (3) ethanol, (4) 1-hexene, (5) cyclohexane, and (6) toluene. All fuel components were studied neat except for toluene - toluene was blended with 18.9% nheptane by liquid volume to increase the fuel reactivity.