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The effects of biodiesel on the swelling of the elastomers and plastics and the corrosion of metals are studied by the immersion tests. The results indicate that biodiesels make little corrosion effect on aluminum, steel and little swelling impact on plastics, but a significant corrosion may be taken place on cooper and brass for some sourced biodiesels. For nitrile-butadiene rubber, the variation of swelling properties in biodiesels is slightly higher than that in diesel. For the non-diesel-resistant elatomers, the variation of swelling properties is lower than those in diesel. The production process and biodiesel source have an influence on the result of elastomer swelling and corrosion. The relationship between the impact of biodiesel on materials and biodiesels properties are also discussed.