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Battery Electric Vehicles and Extended Range Electric Vehicles, like the Chevrolet Volt, can use electrical energy from the Grid to meet the majority of a driver�s transportation needs. This has the positive societal effects of displace petroleum consumption and associated pollutants from combustion on a well to wheels basis, as well as reduced energy costs for the driver. CO2 may also be lower, but this depends upon the nature of the grid energy generation. There is a mix of sources � coal-fired, gas -fired, nuclear or renewables, like hydro, solar, wind or biomass for grid electrical energy. This mix changes by region, and also on the weather and time of day. By monitoring the grid mix and communicating it to drivers (or to their vehicles) in real-time, electrically driven vehicles may be recharged to take advantage of the lowest CO2, and potentially lower cost charging opportunities.

Emissions of nitrogen oxides (NOx) from heavy-duty diesel engines are subject to more stringent environmental legislation. Selective catalytic reduction (SCR) over metal ion-exchanged zeolites is in this connection an efficient method to reduce NOx. Understanding durability of the SCR catalyst is crucial for correct design of the aftertreatment system. In the present paper, thermal and chemical ageing of Fe-BEA as NH3-SCR catalyst is studied. Experimental results of hydrothermal ageing, and chemical ageing due to phosphorous and potassium exposure are presented. The catalyst is characterized by flow reactor experiments, nitrogen physisorption, DRIFTS, XRD, and XPS. Based on the experimental results, a multisite kinetic model is developed to describe the activity of the fresh Fe-BEA catalyst.

The interaction between a combusting diesel spray and a wall was studied by measuring the spray flame temperature time and spatially resolved. The influence of injection sequences, injection pressure and gas conditions on the heat transfer between the combusting spray and the wall was investigated by measuring the flame temperature during the complete injection event. The flame temperature was measured by an emission based optical method and determined by comparing the relative emission intensities from the soot in the flame at two wavelength intervals. The measurements were done by employing a monochromatic and non intensified high speed camera, an array of mirrors, interference filters and a beam splitter. The studies were carried out in the Chalmers High Pressure High Temperature (HP/HT) spray rig at conditions similar to those prevailing in a direct injected diesel engine prior to the injection of fuel.

Analysis of spray-wall interaction is a major issue in the study of the combustion process in DI diesel engines. Along with spray characteristics, the investigation of impinging sprays and of liquid wall film development is fundamental for predicting the mixture formation. Simulations of these phenomena for diesel sprays need to be validated and improved; nevertheless they can extend and complement experimental measurements. In this paper the wall film thickness for impinging sprays was investigated by evaluating the heat transfer across a temperature controlled wall. In fact, heat transfer is significantly affected by the wall film thickness, and both experiments and simulations were carried out to correlate the wall temperature variations and film height. The numerical simulations were carried out using the STAR-CD and the KIVA-3V, rel. 2, codes.

The effect of ammoniac deoxidizing agent (Urea) on the reduction of NOx produced in the Diesel engine was investigated numerically. Urea desolved in water was directly injected into the engine cylinder during the expansion stroke. The NOx deoxidizing process was described using a simplified chemical kinetic model coupled with the comprehensive kinetics of Diesel oil surrogate combustion. If the technology of DWI (Direct Water Injection) with the later injection timing is supposed to be used, the deoxidizing reactants could be delivered in a controlled amount directly into the flame plume zones, where NOx are forming. Numerical simulations for the Isotta Fraschini DI Diesel engine are carried out using the KIVA-3V code, modified to account for the “co-fuel” injection and reaction with combustion products. The results showed that the amount of NOx could be substantially reduced up to 80% with the injection timing and the fraction of Urea in the solution optimized.

In order to acquire knowledge about temperature vs. equivalence ratio, T-ϕ, conditions in which emissions are formed and destroyed, T-ϕ parametric maps were constructed for: 1 Soot and soot precursors (C2H2) 2 Nitrogen oxides (NO and NO2) 3 Unburnt intermediates (CH2O, H2 and CO) 4 Important radicals (HO2 and OH) Each map was obtained by plotting data from a large number of simulations for various T-ϕ combinations in a zero-dimensional, 0D, closed Perfectly Stirred Reactor, PSR. Initially, the influences of elapsed reaction time, pressure and EGR level were examined, varying one parameter at a time. Then, since both the elapsed time and pressure change in an engine cycle, the maps were constructed according to engine pressure traces obtained from Computational Fluid Dynamics, CFD, simulations. Since the pressure is changing in elapsed time intervals the maps are called transient.

In order to meet future emissions legislation for Diesel engines and reduce their CO2 emissions it is necessary to improve diesel combustion by reducing the emissions it generates, while maintaining high efficiency and low fuel consumption. Advanced injection strategies offer possible ways to improve the trade-offs between NOx, PM and fuel consumption. In particular, use of high EGR levels (⥸ 40%) together with multiple injection strategies provides possibilities to reduce both engine-out NOx and soot emissions. Comparisons of optical engine measurements with CFD simulations enable detailed analysis of such combustion concepts. Thus, CFD simulations are important aids to understanding combustion phenomena, but the models used need to be able to model cases with advanced injection strategies.

During the development of the aerodynamic properties of fore coming road vehicles down scaled models are often used in the initial phase. However, if scale models are to be utilised even further in the aerodynamic development they have to include geometrical representatives of most of the components found in the real vehicle. As the cooling package is one of the biggest single generators of aerodynamic drag the heat exchangers are essential to include in a wind tunnel model. However, due mainly to limitations in manufacturing techniques it is complicated to make a down scaled heat exchanger and instead functional dummy heat exchangers have to be developed for scaled wind tunnel models. In this work a Computational Fluid Dynamics (CFD) code has been used to show that it is important that the simplified heat exchanger model has to be of comparable size to that of the full scale unit.

The expansion of current driving cycles for emission regulations to higher load operation in the near future (such as the US06 supplement to the FTP-75 driving cycle) requires attention to low emission combustion concepts in medium to high load regimes. One possibility to reduce NO emissions is to increase the EGR rate. The combustion-temperature reducing effects of high EGR rates can significantly reduce NO formation, to the point where engine-out NOx emissions approach zero levels. However, engine-out soot and CO emissions typically increase at high EGR levels, due to the reduced soot and CO oxidation rates at reduced combustion temperatures and oxygen concentrations. The work presented in this paper focuses on different strategies to reduce soot and CO emissions associated with EGR rates of up to 50%, at which NO formation is largely avoided, but combustion temperatures are not low enough to consider the process as Low-Temperature Combustion (LTC).

Wall wetting can occur irrespective of combustion concept in diesel engines, e.g. during the compression stroke. This action has been related to engine-out emissions in different ways, and an experimental investigation of impinging diesel sprays is thus made for a standard diesel fuel and a two-component model fuel (IDEA). The experiment was performed at conditions corresponding to those found during the compression stroke in a heavy duty diesel engine. The spray characteristics of two fuels were measured using two different optical methods: a Phase Doppler Particle Analyzer (PDPA) and high-speed imaging. A temperature controlled wall equipped with rapid, coaxial thermocouples was used to record the change in surface temperature from the heat transfer of the impinging sprays.

Soot formation and oxidation are complex and competing processes during diesel combustion. The balance between the two processes and their history determines engine-out soot values. Besides the efforts to lower soot formation with measures to influence the flame lift-off distance for example or to use HCCI-combustion, enhancement of late soot oxidation is of equal importance for low-λ diffusion-controlled low emissions combustion with EGR. The purpose of this study is to investigate soot oxidation in a heavy duty diesel engine by statistical analysis of engine data and in-cylinder endoscopic high speed photography together with CFD simulations with a main focus on large scale in-cylinder gas motion. Results from CFD simulations using a detailed soot model were used to reveal details about the soot oxidation.

The possibilities of operating a direct injection Diesel engine in HCCI combustion mode with early injection of conventional Diesel fuel were investigated. In order to properly phase the combustion process in the cycle and to prevent knock, the geometric compression ratio was reduced from 17.0:1 to 13.4:1 or 11.5:1. Further control of the phasing and combustion rate was achieved with high rates of cooled EGR. The engine used for the experiments was a single cylinder version of a modern passenger car type common rail engine with a displacement of 480 cc. An injector with a small included angle was used to prevent interaction of the spray and the cylinder liner. In order to create a homogeneous mixture, the fuel was injected by multiple short injections during the compression stroke. The low knock resistance of the Diesel fuel limited the operating conditions to low loads. Compared to conventional Diesel combustion, the NOx emissions were dramatically reduced.

The influence of ethanol content in gasoline on speciated emissions from a direct injection stratified charge (DISC) SI engine is assessed. The engine tested is a commercial DISC one that has a wall guided combustion system. The emissions were analyzed using both Fourier transform infrared (FTIR) spectroscopy and conventional emission measurement equipment. Seven fuels were compared in the study. The first range of fuels was of alkylate type, designed to have 0, 5, 10 and 15 % ethanol in gasoline without changing the evaporation curve. European emissions certification fuel was tested, with and without 5 % ethanol, and finally a specially blended high volatility gasoline was also tested. The measurements were conducted at part-load, where the combustion is in stratified mode. The engine used a series engine control unit (ECU) that regulated the fuel injection, ignition and exhaust gas recirculation (EGR).

A validation study of the numerical model of n-heptane spray combustion based on experimental constant-volume data [1] was done, by comparing auto-ignition delays for different pre - turbulence levels and initial temperatures, flame contours, and soot distributions under Diesel-like conditions. The basic novelty of the methodology developed in [2] - [3] is the implementation of the partially stirred reactor (PaSR) model accounting for detailed chemistry / turbulence interactions. It is based on the assumption that the chemical processes proceed in two successive steps: micro mixing, simulated on a sub - grid scale, is followed by the reaction act. When the all Re number RNG k-ε or LES models are employed, the micro mixing time can be consistently defined giving the combustion model a “well-closed” form incorporated into the KIVA-3V code.

For the application to Gasoline Homogenous Charge Compression Ignition (HCCI) modeling, a multi-zone model was developed. For this purpose, the detailed-chemistry code SENKIN from the CHEMKIN library was modified. In a previous paper, the authors explained how piston motion and a heat transfer model were implemented in the SENKIN code to make it applicable to engine modeling. The single-zone model developed was successfully implemented in the engine cycle simulation code AVL BOOST™. A multi-zone model, including a crevice volume, a quench layer and multiple core zones, is introduced here. A temperature distribution specified over these zones gives this model a wider range of application than the single-zone model, since fuel efficiency, emissions and heat release can now be predicted more accurately. The SENKIN-BOOST multi-zone model predictions are compared with experimental data.

A single cylinder, naturally aspirated, four-stroke and camless (Otto) engine was operated in homogeneous charge compression ignition (HCCI) mode with commercial gasoline. The valve timing could be adjusted during engine operation, which made it possible to optimize the HCCI engine operation for different speed and load points in the part-load regime of a 5-cylinder 2.4 liter engine. Several tests were made with differing combinations of speed and load conditions, while varying the valve timing and the inlet manifold air pressure. Starting with conventional SI combustion, the negative valve overlap was increased until HCCI combustion was obtained. Then the influences of the equivalence ratio and the exhaust valve opening were investigated. With the engine operating on HCCI combustion, unthrottled and without preheating, the exhaust valve opening, the exhaust valve closing and the intake valve closing were optimized next.

Heat transfer to the walls of the combustion chamber is increased by engine knock. In this study the influence of knock onset and knock intensity on the heat flux is investigated by examining over 10 000 individual engine cycles with a varying degree of knock. The heat transfer to the walls was estimated by measuring the combustion chamber wall temperature in an SI engine under knocking conditions. The influence of the air-fuel ratio and the orientation of the oscillating cylinder pressure-relative to the combustion chamber wall-were also investigated. It was found that knock intensities above 0.2 Mpa influenced the heat flux. At knock intensities above 0.6 Mpa, the peak heat flux was 2.5 times higher than for a non-knocking cycle. The direction of the oscillations did not affect the heat transfer.

Simulations of a Direct Injection Spark Ignition (DISI) engine have been performed for both early injection with homogeneous charge combustion and for late injection with stratified charge combustion. The purpose has been to study flow characteristics, fuel/air mixing, combustion, and NOx and soot formation. Focus is put on the combustion modeling. Two different full load cases with early injection are simulated, 2000 rpm and 6000 rpm. One load point with late injection is simulated, 2000 rpm and 2.8 bar net MEP. Three different injection timings are simulated at the low load point: 77, 82, and 87 CAD bTDC. The spray simulations are tuned to match measured spray penetrations and droplet size distributions at both atmospheric and elevated pressure. Boundary conditions for the engine simulations are taken from 1-D gas exchange simulations that are tuned to match engine tests.

A complex chemistry model of reduced size (65 species and 268 reaction steps) derived on the basis of n-heptane auto-ignition kinetics, low hydrocarbon oxidation chemistry, poly-aromatic hydrocarbon (PAH) and NOx formation kinetics together with a phenomenological soot model have been integrated with the KIVA code for multidimensional diesel simulations. A partially stirred reactor model is used to handle the turbulence-chemistry interaction. The results obtained from numerical simulations for a direct-injection (DI) diesel spray, which is injected into a constant-volume combustion vessel at engine-like conditions, show that the approach is able to reproduce the transient diesel auto-ignition and combustion processes as observed in many optical imaging studies. The simulated results indicate that the auto-ignition of DI diesel spray occurs at a lean site close to the mean stoichiometric line for the cases tested.

The effects of injection pressure and duration on exhaust gas emissions, sooting flame temperature, and soot distribution for a heavy–duty single cylinder DI diesel engine were investigated experimentally. The experimental analysis included use of two–color pyrometry as well as “conventional” measuring techniques. Optical access into the engine was obtained through an endoscope mounted in the cylinder head. The sooting flame temperature and soot distribution were evaluated from the flame images using the AVL VisioScope™ system. The results show that the NOx/soot trade–off curves could be improved by increasing injection pressure. An additional reduction could also be obtained if, for the same level of injection pressure, the injection duration was prolonged.