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A recent endeavor has been undertaken to understand the performance of Shuttle Orbiter lithium hydroxide (LiOH) canisters used during STS-114. During this mission, the crew relied on both fresh LiOH and aged LiOH stored on the International Space Station (ISS). Due to the Space Shuttle being grounded after the Columbia accident, the canisters stored on ISS had passed the certified two-year shelf life and were considered expired. The focus of the analysis was to determine the performance of expired LiOH in relation to fresh LiOH and the accuracy of previous predictions1 regarding the performance of expired LiOH. Understanding the performance of expired LiOH is crucial in enabling the extension of the useful life of LiOH canisters. Extending the shelf life has ramifications not only in the current Shuttle program, but in regard to future exploration missions fulfilling the Vision for Space Exploration as well.

Recent efforts have been pursued to establish the usefulness of Space Shuttle Orbiter lithium hydroxide (LiOH) canisters beyond their certified two-year shelf life, at which time they are currently considered “expired.” A stockpile of Orbiter LiOH canisters are stowed on the International Space Station (ISS) as a backup system for maintaining ISS carbon dioxide Canisters with older (CO2) control. Canister with older pack dates must routinely be replaced with newly packed canisters off-loaded from the Orbiter Middeck. Since conservation of upmass is critical for every mission, the minimization of canister swap-out rate is paramount. LiOH samples from canisters with expired dates that had been returned from the ISS were tested for CO2 removal performance at the NASA Johnson Space Center (JSC) Crew and Thermal Systems Division (CTSD). Through this test series and subsequent analysis, performance degradation was established.