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Lean NOx trap (LNT) is a great potential NOx abatement method for lean-burn gasoline engines in consideration of exhaust aftertreatment cost and installation space. NOx firstly is adsorbed on storage sites during the lean-burn period, then reduced to N2 under catalysis of the catalyst sites in the rich-burn phase. There must be a spillover of NOx species between both types of sites. For a better understanding of this spillover process of NOx species between Pt (as the catalytic center) and BaO sites (as storage components in commercial catalyst), this work focused on the vital first step of spillover, the adsorption of NOx on clean substrate surface (γ-Al2O3 (110) surface) and Ba\Pt cluster supported by the surface. Based on first principles software VASP (Vienna Ab-initio Simulation Package), the most stable adsorption structures of NO with Pt3 clusters and (BaO)3 clusters on carrier γ- Al2O3 (110) surface were confirmed and the adsorption energy of these structures were compared.

Two-stroke engines have to face the problems of insufficient charge for short intake time and the loss of intake air caused by long valve overlap. In order to promote the power of a two-stroke poppet valve diesel engine, measures are taken to help optimize intake port structure. In this work, the scavenging and combustion processes of three common types of intake ports including horizontal intake port (HIP), combined swirl intake port (CSIP) and reversed tumble intake port (RTIP) were studied and their characteristics are summarized based on three-dimensional simulation. Results show that the RTIP has better performance in scavenging process for larger intake air trapped in the cylinder. Its scavenging efficiency reaches 84.7%, which is 1.7% higher than the HIP and the trapping ratio of the RTIP reaches 72.3% due to less short-circuiting loss, 11.2% higher than the HIP.

The exhaust aftertreatment strategy is one of the most fundamental aspects of spark ignition engine technologies. For various types of engines (e.g., carburetor engine, PFI engine and GDI engine), measuring, purifying, modeling, and control strategies regarding the exhaust aftertreatment systems vary significantly. The primary goal of exhaust aftetreatment systems is to reduce the exhaust emission levels of NOx, HC and CO as well as to lower combustion soot. In general, there is a tradeoff among different engine performance aspects. The exhaust catalytic systems, such as the three way catalyst (TWC) and lean NOx trap (LNT) converters, can be applied together with the development of other engine technologies (e.g., variable valve timing, cold start). With respect to engine soot, some advanced diagnosing techniques are essential to obtain thorough investigation of exhaust emission mechanisms.

Chinese new legislations on two wheels and mopeds have been published recently. Depending on the latest exhaust statistic analyses, with the resulting of tighter limits, the application of catalytic converters is becoming a prevalent and a cost-efficient solution for Chinese motorcycle manufacturers. The phenomenon of exhaust temperature changes rapidly during real driving process is well known as one of major destructive factors which have effects upon converter's durability. One 125 cm3 motorcycle is selected as a typical model in this research project. Exhaust temperature of the 125 cm3 motorcycle is measured and recorded during the process of ECE 40 driving cycle. A simulation test system has been set up successfully depending on those temperature data. Conversion ratio of converter sample lost distinctly after 18 hours' thermal impact tests. After further analyses, there were not evident changes in microstructure and substance on the surface of converter.

The combustion in low-speed two-stroke marine diesel engines can be characterized as large spatial and temporal scales combustion. One of the most effective measures to reduce NOx emissions is to reduce the local maximum combustion temperature. In the current study, multi-dimensional numerical simulations have been conducted to explore the potential of Miller cycle, high compression ratio coupled with EGR (Exhaust Gas Recirculation) and WEF (water emulsified fuel) to improve the trade-off relationship of NOx-ISFC (indicated specific fuel consumption) in a low-speed two-stroke marine engine. The results show that the EGR ratio could be reduced combined with WEF to meet the Tier III emission regulation. The penalty on fuel consumption with EGR and WEF could be offset by Miller cycle and high geometric compression ratio.

For uniflow scavenged two-stroke marine diesel engines, the main function of scavenging process is to replace the burned gas with fresh charge. The end state of scavenging process is integral to the subsequent compression and combustion, thereby affecting the engine’s fuel economy, power output and emissions. In this paper, a complete working cycle of a large marine diesel engine was simulated by using the 3D-CFD software CONVERGE. The model was validated by mesh sensitivity test and experiment data. Based on this calibrated model, the influences of swirl ratio and exhaust valve closing (EVC) timing on the scavenging process were investigated. The parameters evaluating the performance of scavenging process were introduced. The results show that, by adjusting the swirl orientation angle(SOA) from SOA=10° to SOA=30°, different swirl ratios are generated and have obvious differences in flow characteristics and scavenging performance.

Recent toxicological and epidemiologic studies have shown that diesel emissions have been a significant toxic air contaminant. Catalyzed DPF (CDPF) not only significantly reduces the PM mass emissions (>90%), but also further promotes carrier self-regeneration and oxidize more harmful gaseous pollutants by the catalyst coated on the carrier. However, some ultrafine particles and potentially harmful gaseous pollutants, such as VOCs species, originally emitted in the vapor-phase at high plume temperature, may penetrate through the CDPF filter. Furthermore, the components and content of catalyst coated on the CDPF could influence the physicochemical properties and toxicity intensity of those escaping ultrafine particles and gaseous pollutants. In this work, (1) we investigated the influence of precious metal content as a variable parameter on the physicochemical properties and catalytic activities of the small CDPF samples.

Although diesel engines have higher output torque, lower fuel consumption, and lower HC pollutant emissions, larger amounts of NOx and PM are emitted, compared with equivalent gasoline engines. The diesel particulate filters (DPF) have proved one of the most promising aftertreatment technologies due to the more stringent particulate matters (PM) regulations. In this study, the computational fluid dynamics (CFD) model of DPF was built by utilizing AVL-Fire software code. The main objective of this paper was to investigate the pressure drop and soot regeneration characteristics of hexagonal and conventional square cell DPFs with various inlet mass flow rates, inlet temperatures, cell densities, soot loads and ash loads. Different cell geometry shapes of DPF were evaluated under various ash distribution types.

Although diesel engines offer higher thermal efficiency and lower fuel consumption, larger amounts of Particulate Matters (PM) are emitted in comparison with gasoline engines. The Diesel Particulate Filters (DPF) have proved one of the most promising technologies due to the “particle number” emissions regulations. In this study, the Computational Fluid Dynamics (CFD) multi-channel model of DPF was built properly by utilizing AVL-Fire software code to evaluate the pressure drop and soot accumulation characteristics of DPF. The main objective of this paper was to investigate the effects of soot (capacity and deposit forms) and ash (capacity and distribution factors) interaction on DPF pressure drop and soot accumulation, as well as the effects of DPF boundary conditions (inlet mass flow rate and inlet temperature) on pressure drop.

A two-dimensional mesoscopic approach has been developed to investigate the flow and soot loading in the micro-channels of diesel particulate filter. Soot particle size examined is in the range of 10 nm to 10 μm. The flow is solved by an incompressible lattice Boltzmann model and the transport of solid particle is described in a Lagrangian frame of reference by cell automation probabilistic model. The lattice Boltzmann-cell automation probabilistic model (LB-CA model) is validated with the results of previous studies. The heterogeneous porous wall of DPF is generated by quartet structure generation set (QSGS). The effects of porous wall on the pressure field and velocity field are investigated. The distribution and deposition of soot particles with different sizes in clean channels are simulated. The dynamic evolution of solid boundary in soot particle capture process is investigated and the effects of the deposited soot particles on flow field are evaluated.

As the prime after-treatment device for diesel particulate matter (PM) emission control, Diesel Particulate Filter (DPF) has been widely used for its high particle capture efficiency. In order to study the particle motion and deposition distributions in the DPF inlet channel, a 2-D wall flow DPF microcosmic channel model is built in this paper. The motion trajectories of particles with different sizes are investigated considering the drag force, Brownian motion, gravity and Saffman lift. The effects of the space velocity on particle motion trajectories and deposition distributions inside the inlet channel are evaluated. These results demonstrate that the particle motion trajectories are highly dependent on particle sizes and influenced by the space velocity. The effect of the Brownian motion is obvious for fine particles and suppressed when the space velocity is raised.

In order to achieve high-efficiency and clean combustion in HCCI engines, combustion must be controlled reasonably. A great variety of species with various reactivities can be produced through low temperature oxidation of fuels, which offers possible solutions to the problem of controlling in-cylinder mixture reactivity to accommodate changes in the operating conditions. In this work, in-cylinder combustion characteristics with low temperature reforming (LTR) were investigated in an optical engine fueled with low octane number fuel. LTR was achieved through low temperature oxidation of fuels in a reformer (flow reactor), and then LTR products (oxidation products) were fed into the engine to alter the charge reactivity. Primary Reference Fuels (blended fuel of n-heptane and iso-octane, PRFs) are often used to investigate the effects of octane number on combustion characteristics in engines.

In this study, a new system of assessment method was developed to evaluate the characteristics of urban buses based on remote online monitoring. Four types of buses, including China V emission standards diesel bus, lean-burn CNG bus, air-fuel equivalence ratio combustion CNG bus and gas-electric hybrid bus, were chosen as samples to analyze the emission characteristics of urban buses with different engine types in urban scenario. Based on the traffic conditions in Beijing, the actual emission characteristics of buses under newly-built driving conditions were analyzed. Moreover, the emission factor database of urban buses in Beijing was established to analyze the characteristics of excess emission. The research results are shown as follows. 1) Compared with other types of buses, NOX emission factor and emission rate of lean-burn CNG bus are much higher.

The main objective of this paper was to investigate the pressure drop characteristics of ACT (asymmetric cell technology) design filter with various inlet mass flow rates, soot loads and ash loads by utilizing 1-D computational Fluid Dynamics (CFD) method. The model was established by AVL Boost code. Different ratios of inlet to outlet channel width inside the DPF (Diesel Particulate Filter) were investigated to determine the optimal structure in practical applications, as well as the effect of soot and ash interaction on pressure loss. The results proved that pressure drop sensitivity of different inlet/outlet channel width ratios increases with the increased inlet mass flow rate and soot load. The pressure drop increases with the increased channel width ratio at the same mass flow rate. When there is little soot deposits inside DPF, the pressure drop increases with the bigger inlet.

Ethanol-Gasoline was being promoted in China. Ethanol as substitute fuel could save such nature resource that cannot be regenerated. At the same time, oxygen additives also have potential dangerous, such as, poisonous organic compound. In this paper, a typical 125 mL four stroke single cylinder motorcycle was driven on chassis dynamometer at 5 different stable conditions which is specified in ECE 40 driving cycle. At each stably driving condition, raw gas from exhaust pipe was collected in corresponding bags respectively. Those samples were analyzed by means of gas chromatogram and mass spectrum analyzer (Agilent GC6890-MS5973). Poisonous ethanol compound such as benzene, toluene had been found in samples from ethanol blended fueled motorcycle exhausts and compared with samples from that of pure gasoline.