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Particulate matter (PM) trapping and oxidation in regeneration on the surface of a diesel particulate catalyst-membrane filter (DPMFs) were investigated in detail using an all-in-focus optical microscope. The DPMF consists of two-layer sintered filters, where a SiC-nanoparticle membrane (made from a mixture of 80 nm and 500 nm powders) covers the surface of a conventional SiC filter. Using a visualization experiment, it was shown that PMs were trapped homogeneously along fine surface pores of the membrane's top surface, whereas in the regeneration process, the particulates in contact with the membrane may have been oxidized with some catalytic effect of the SiC nanoparticles. A soot cake was reacted continuously on the nanoparticles since pushed by a gas flow. The oxidation temperature of particulate trapped on the SiC-nanoparticle membrane was about 75 degrees lower than that on the conventional diesel particulate filters (DPF) without a catalyst.

In a state-of-the-art lean-burn spark ignition engine, a strong in-cylinder flow field with enhanced turbulence intensity is formed, and understanding the wall heat transfer mechanism of such a complex flow is required. The flow velocity and temperature profiles inside the wall boundary layer are strongly related to the heat transfer mechanism. In this study, two-dimensional three-component (2D3C) velocity distribution near the piston top surface was measured during the compression stroke in a strong tumble flow using a rapid compression and expansion machine (RCEM) and a stereoscopic micro-PIV system. The bore, stroke, compression ratio, and compression time were 75 mm, 128 mm, 15, and 30 ms (equivalent to 1000 rpm), respectively.

The diesel particulate membrane filter (DPMF) is a good solution to the problem of high pressure drop that exists across diesel particulate filters (DPFs) as a result of the soot trapping process. Moreover, DPMFs that have a membrane layer composed of SiC nanoparticles can reduce the oxidation temperature of soot and the apparent activation energy. The SiC nanoparticles have an oxide layer on their surface, with a thickness less than 10 nm. From the visualization of soot oxidation on the surface of SiC nanoparticles by an environmental transmission electron microscope (ETEM), soot oxidation is seen to occur at the interface between the soot and oxide layers. The soot oxidation temperature dependency of the contact area between soot and SiC nanoparticles was evaluated using a temperature programmed reactor (TPR). The contact area between soot and SiC nanoparticles was varied by changing the ratio of SiC nanoparticles and carbon black (CB), which was used as an alternative to soot.

Trapping and regeneration processes in a SiC wall-flow diesel particulate filter (DPF) without a catalyst were investigated in detail through microscopic visualization. By microscopic observation of the cross section and surface, the transition from depth filtration to surface filtration could be observed clearly. The open pores on the wall surface were strongly related to the filtration depth of diesel particulate matter (PM). During the regeneration process, after the soot cake was burnt out, the particulates trapped inside the surface pores were oxidized. As a result, the particulate trapping and oxidation behaviors were strongly dependent on the microstructural surface pores.

In order to investigate the mechanism of heat transfer on the chamber wall of direct-injection diesel engines, 2-D temperature imaging and heat flux measurement in the flame impinging region on the chamber wall were conducted using laser-induced phosphorescence technique. The temperature of the chamber wall surface was measured by the calibrated intensity variation of the 355nm-excited laser-induced phosphorescence from an electrophoretically deposited thin layer of La2O2S:Eu phosphor on a quartz glass plate placed in a rapid compression and expansion machine (RCEM). Instantaneous 2-D images of wall temperature at different timings after start of injection and time-resolved (10kHz) heat flux near the flame impinging region were obtained for combusting and non-combusting diesel sprays with impinging distance of 23.4mm at different injection pressures (80 and 120MPa).

Through microscopic visualization experiments, a process generally known as depth filtration was shown to be caused by surface pores. Moreover, the existence of a soot cake layer was an important advantage for filtration performance because it could trap most of the particulates. We proposed an ideal diesel particulate filter (DPF), in which a silicon carbide (SiC) nanoparticle membrane (made from a mixture of 80 nm and 500 nm powders) instead of a soot cake was sintered on the DPF wall surface; this improved the filtration performance at the beginning of the trapping process and reduced energy consumption during the regeneration process. The proposed filter was called a diesel particulate membrane filter (DPMF). A diesel fuel lamp was used in the trapping process to verify the trapping and oxidation mechanisms of ultrafine particulate matter. Thus, the filtration performance of the membrane filters was shown to be better than that of conventional DPFs.

Time-lapse images of particulate matter (PM) deposition on diesel particulate filters (DPFs) at the PM-particle scale were obtained via field-emission scanning electron microscopy (FE-SEM). This particle scale time-series visualization showed the detailed processes of PM accumulation inside the DPF. First, PM introduced into a micro-pore of the DPF wall was deposited onto the surface of SiC grains composing the DPF, where it formed dendritic structures. The dendrite structures were locally grown at the contracted flow area between the SiC grains by accumulation of PM, ultimately constructing a bridge and closing the porous channel. To investigate the dominant parameters governing bridge formation, the filtration efficiency by Brownian diffusion and by interception obtained using theoretical filtration efficiency analysis of a spherical collector model were compared with the visualization results.

In this study, particle transport and captured behaviors in a Diesel Particulate Filter (DPF) was investigated with Lattice Boltzmann Method. LBM calculation was performed to a 3D-reconstructed micro porous DPF substrate, which was obtained by micro-focus 3D X-ray technique. Simulating advection-diffusion behaviors of diesel particulates in micro porous channel, we adapted a LBM method used for high Peclet number flow, simulating flow conditions in DPFs. We investigated flow behaviors in a wide variety of inlet velocity. LBM simulation has clearly shown that non-dimensional flow field is similar in wide range of flow conditions in the DPF, because flow Reynolds number in the micro porous substrate is sufficiently low, dominated by laminar flow regime. It was also revealed that less than 40% pore channels was responsible for more than 80% volume flux in the porous substrate without particle loading.

A diesel particulate membrane filter (DPMF) has good trapping efficiency of soot and reduces the pressure loss through the soot accumulation process on the diesel particulate filter wall. The activation energy reduction effect of the soot oxidation reaction by DPMF was clarified. The membrane consists of SiC nanoparticles with a diameter of 10-100 nm. A thin oxide layer is formed on the SiC particle surface, and nanoscale noble metal particles are distributed on the surface. The reduction mechanism for the activation energy was investigated in detail. Nanoscale soot was accumulated on DPMF from a diesel lamp. Furthermore, the soot oxidation in the regeneration process was observed using an optical microscope. An Arrhenius plot was made from the change of the concentration of the product gases CO and CO₂ with respect to time. The performance and the temperature dependence of oxygen desorption on the oxide layer was measured by thermal desorption spectroscopy (TDS).

Local heat flux from the flame to the combustion chamber wall, q̇, was measured the wall surfaces of a rapid compression-expansion machine which can simulate diesel combustion. Temperature of the flame zone, T1, was calculated by a thermodynamic two-zone model using measured values of cylinder pressure and flame volume. A local heat transfer coefficient was proposed which is defined as q̇/(T1-Tw). Experiments showed that the local heat transfer coefficient depends slightly on the temperature difference, T1-Tw, but depends significantly on the velocity of the flame which contacts the wall surface.

The local heat fluxes from impinging combusting and evaporating diesel sprays to the wall of a square combustion chamber were measured in a rapid compression machine. It was revealed that the ratio of local heat flux between the combusting and evaporating spray, q̇c/q̇e, is of the same order of magnitude as (Tc-Tw)/(Te-Tw) and its values estimated by a two-zone model agree roughly with the measured ones. The time-mean local heat flux during the spray impingement was found to be approximately proportional to the 0.8th power of the injection velocity and the heat-transfer phenomenon depends largely on whether the ignition starts before or after the impingement.

A diesel particulate membrane filter (DPMF) offers good trapping efficiency of soot and reduces the pressure loss through the soot-trapping process. We found that one specific design of DPMF has the effect of reducing the apparent activation energy of the soot oxidation. The membrane is made of SiC nanoparticles with a diameter of 10-100 nm, which are covered with a thin silicon-oxy-carbide layer with a thickness of about 5 nm. The apparent activation energy of soot oxidation on the DPMF was reduced by 30-40 kJ/mol than conventional SiC-DPF. Furthermore, the light-off temperature of soot oxidation on the DPMF (with single nanosized Pt) is about 100°C lower than that of the DPMF (without Pt). The single nanosized Pt particles are embedded in the silicon-oxy-carbide layer. The formation of additional Pt is different from that which takes place in a conventional catalyzed soot filter (CSF). In a conventional CSF, the surface of the Pt particles is exposed to the atmosphere.

Diesel engine is one the effective solutions for reducing CO2 and recognized as a leading candidate for mitigating global warming. To comply with increasingly stringent emission standards, all diesel engines require some sort of NOx control systems such as selective catalytic reduction (SCR) systems. The SCR catalyst for reducing NOx from diesel engines is classified into two groups, urea-SCR and HC-SCR catalyst, respectively. Although the urea-SCR catalyst is widely recognized as promising de-NOx technology in respect to the NOx conversion efficiency, it have some outstanding issues such as ammonia slip, urea injection, storage space, freezing and some infrastructures for supplying urea water solutions. In an attempt to overcome the inherent shortcoming of existing urea-SCR catalyst, hydrocarbons have been considered as alternative reducing agents for SCR process, instead of NH3.

The exhaust emissions from diesel combustion are the sources of particulate matter emitted to the atmosphere, which are components of air pollution that implicated in human health such as lung cancer. At present the diesel particulate filter can remove PM from the exhaust gas before emitted to the atmosphere. This research is investigating morphology and structure of acicular mullite to develop the fabrication process filter in order to study particulate matters trapping and oxidation mechanisms. This paper used two main substances to study the structure of diesel particulate filter (DPFs); Aluminum oxide (Al2O3) and Silicon dioxide (SiO2). These are mainly in the conventional DPFs. The variable substances are Titanium dioxide (TiO2) and Vanadium oxide (V2O5), which added to investigate and produce the acicular mullite DPFs structure. The mullite samples were sintered at 1300 oC with holding time of 1 h.

Surface pores that are open to the inlet channel below the surface play a particularly important role in the filtration of particulate matter (i.e., soot) inside the walls of a diesel particulate filter (DPF); they are closely related to the pressure drop and filtration efficiency through the DPF as well as the performance of the regeneration process. In this study, a scanning electron microscope (SEM) was used to dynamically visualize the soot deposition process at the particle scale as “time-lapse” images corresponding to the different increases in the pressure drop at each time step. The soot was first trapped at the deepest areas of the surface pores because the porous channels in this area were constricted by silicon carbide grains; soot dendrite structures were observed to grow and finally cause obstructions here.

Development of the diesel particulate filter (DPF) aims to attain fast oxidation of accumulated soot at low temperature. Numerous researchers have explored the characteristics of soot oxidation under ambient conditions of simulated exhaust gas using thermogravimetric analysis or a flow reactor. In this study, temperature programmed oxidation (TPO) experiments were carried out for soot entrapped in miniaturized DPFs, cut-out from practical particulate filters, yielding wall-flow features typically encountered in real-world DPFs. Furthermore, when using the miniaturized samples, highly accurate lab-scale measurements and investigations can be facilitated. Examining different temperature ramping rates used for the TPO experiments, we propose a rate of 10°C/min as the most effective in analyzing soot oxidation in the practical filter substrates.

Every year, exhaust gas regulations are getting stricter with the intention to solve the average air pollution problem, however, local roadside pollution is still a pressing issue. In order to solve this local roadside pollution problem, it is necessary to evaluate and/or predict “where” and “how much” pollutants such as NOx are emitted. To predict the local roadside pollution, it is necessary to collect emissions data from various kinds of vehicles driving on real-world and analyze them. In recent years, Real Driving Emission regulations using PEMS (Portable Emission Measurement System) have been introduced mainly in Europe. A typical PEMS configuration can weigh close to 100 kg however, and its weight affects the driving conditions of vehicles running on actual roads. In this study, we focused on the analysis of real-world emissions using SEMS (Sensor-based Emission Measurement System).

To investigate the heat transfer phenomena inside the combustion chamber of a diesel engine, a correlation for the heat transfer coefficient in a combustion chamber of a diesel engine was investigated based on heat flux measured by the authors in the previous study(8) using the rapid compression and expansion machine. In the correlation defined in the present study, thermodynamically estimated two-zone temperatures in the burned zone and the unburned zone are applied. The characteristic velocity given in the correlation is related to the speed of spray flame impinging on the wall during the fuel injection period. After the fuel injection period, the velocity term of the Woschni’s equation is applied. It was shown that the proposed correlation well expresses heat transfer phenomena in diesel engines.

As well-known, the diesel engine has the highest thermal efficiency at the same load as compared with internal combustion engine but its disadvantage is particulate matter (PM) emitted to the atmosphere. The studies of this paper were divided into two parts. The first part studied the quantity of PM from the both diesel and biodiesel fuels at 80% load (2400 rpm) by the trapping process on diesel particulate filter (DPF) used in a partial flow dilution tunnel. The second part studied the regeneration process of PM under the flow rate of oxygen and nitrogen gas of 13.5 L/min with 10%, 15%, and 21% of oxygen gas. The result showed that amount of PM from biodiesel fuel was lower around two times than PM from diesel fuel. The duration in regeneration process of biodiesel's PM was shorter than diesel while increasing of oxygen percentage can reduce regeneration time.

A multi-functional membrane filter was developed through deposition of agglomerated Three-Way Catalyst particles with a size of 1 ~ 2 microns on the conventional bare particulate filter. The filtration efficiency reaches almost 100 % from the beginning of soot trapping with a low pressure drop and both reductions of NO and CO emission were achieved.