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Journal Article

Development of Clean Diesel NOx After-treatment System with Sulfur Trap Catalyst

2010-04-12
2010-01-0303
Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.
Journal Article

Thermal Analysis of the Exhaust Line Focused on the Cool-Down Process

2014-04-01
2014-01-0655
At the engine restart, when the temperature of the catalytic converter is low, additional fuel consumption would be required to warm up the catalyst for controlling exhaust emission.The aim of this study is to find a thermally optimal way to reduce fuel consumption for the catalyst warm up at the engine restart, by improving the thermal retention of the catalytic converter in the cool down process after the previous trip. To make analysis of the thermal flow around the catalytic converter, a 2-D thermal flow model was constructed using the thermal network method. This model simulates the following processes: 1) heat conduction between the substrate and the stainless steel case, 2) heat convection between the stainless steel case and the ambient air, 3) heat convection between the substrate and the gas inside the substrate, 4) heat generation due to chemical reactions.
Journal Article

Injection Nozzle Coking Mechanism in Common-rail Diesel Engine

2011-08-30
2011-01-1818
The hole diameter of injection nozzles in diesel engines has become smaller and the nozzle coking could potentially cause injection characteristics and emissions to deteriorate. In this research, engine tests with zinc-added fuels, deposit analyses, laboratory tests and numerical calculations were carried out to clarify the deposit formation mechanisms. In the initial phase of deposit formation, lower zinc carboxylate formed close to the nozzle hole outlet by reactions between zinc in the fuel and lower carboxylic acid in the combustion gas. In the subsequent growth phase, the main component changed to zinc carbonate close to nozzle hole inlet by reactions with CO₂ in the combustion gas. Metal components and combustion gases are essential elements in the composition of these deposits. One way of removing these deposits is to utilize cavitations inside the nozzle holes.
Journal Article

Development of an On-Board PM Sensor for the OBD System Based on an Electrochemical Polarization

2011-08-30
2011-01-2059
An on-board particulate matter (PM) sensor, consisting of a gas-permeable electrochemical cell with a porous yttria-stabilized zirconia solid oxide electrolyte, was developed to assist the on-board diagnostics (OBD) system of a vehicle. Exhaust is pumped from the anode side to the cathode side and PM deposited on the anode is instantly oxidized by the catalytic effects of the metal component of the electrode at temperatures higher than 350°C. The PM oxidation reaction occurs at the three-phase boundary between the anode, electrolyte and gas phase, and causes a slight change in the bulk average oxygen concentration, which produces electrochemical polarization by the difference in oxygen partial pressures between the anode and cathode. The developed PM sensor has a detection limit of 2 mg/m₃, at which level will enable PM detection in the OBD system according to the EURO VI regulation.
Technical Paper

HILS Application for Hybrid System Development

2007-08-05
2007-01-3469
The hybrid system has the typical advantage that it can realize various types of system control, because the system has two power units, engine and motor. On the other hand, however, constraints are increasing due to the complexity of the vehicle system. Compared to the conventional HILS construction and application, there are mainly two typical characteristics or themes for HV-HILS (i.e. HILS for hybrid vehicle control development). Firstly, HV-HILS requires full vehicle simulation environment, because the plural ECU control logic is intricately intertwined. Secondly, recent HILS system needs to run with more accurate or complicated plant models which are necessary to develop more accurate vehicle control logic.
Technical Paper

Quantitative Analysis of the Relation between Flame Structure and Turbulence in HCCI Combustion by Two-Dimensional Temperature Measurement

2008-04-14
2008-01-0061
The structure of HCCI (homogeneous charge compression ignition) combustion flames was quantitatively analyzed by measuring the two-dimensional gas temperature distribution using phosphor thermometry. It was found from the relation between a turbulent Reynolds number and Karlovitz number that, when compared with the flame propagation in an S.I. engine, HCCI combustion has a wider flame structure with respect to the turbulence scale. As a result of our experimentation for the influence of low temperature reaction (LTR) using two types of fuel, it was also confirmed that different types of fuel produce different histories of flame kernel structure.
Technical Paper

Study of High Efficiency Zero-Emission Argon Circulated Hydrogen Engine

2010-04-12
2010-01-0581
The potential of high efficiency zero-emission engines fueled by hydrogen, which is regarded as a promising form of energy for the future, is being researched. The argon circulated hydrogen engine [ 1 ] is one system theoretically capable of achieving both high efficiency and zero emissions, and its feasibility for use in vehicles has been studied. Specifically, tests were performed to verify the following issues. It was examined whether stable hydrogen combustion could be achieved under an atmosphere of argon and oxygen, which has a high specific heat ratio, and whether the substantial thermal efficiency improvement effect of the argon working gas could be achieved. An argon circulation system was also studied whereby steam, which is the combustion product of the hydrogen and oxygen emitted from the engine, is separated by condensation to enable the remaining argon to be re-used.
Technical Paper

A Measuring Technology to Analyze HC Concentration in the Air Intake System while the Engine is in Operation

2004-03-08
2004-01-0142
In order to correspond to the exhaust emissions regulations that become severe every year, more advanced engine control becomes necessary. Engine engineers are concerned about the Hydrocarbons (HCs) that flow through the air-intake ports and that are difficult to precisely control. The main sources of the HCs are, the canister purge, PCV, back-flow gas through the intake valves, and Air / Fuel ratio (A/F) may be aggravated when they flow into the combustion chambers. The influences HCs give on the A/F may also grow even greater, which is due to the increasingly stringent EVAP emission regulations, by more effective ventilation in the crankcase, and also by the growth of the VVT-operated angle and timing, respectively. In order to control the A/F more correctly, it is important to estimate the amount of HCs that are difficult to manage, and seek for suitable controls over fuel injection and so on.
Technical Paper

Development of New Concept Iridium Plug

2001-01-05
2001-01-1201
In the field of automotive gasoline engines, new products aiming at greater fuel economy and cleaner exhaust gases are under development with the aim of preventing environmental destruction. Severe ignition environments such as lean combustion, stronger charge motion, and large quantities of EGR require ever greater combustion stability. In an effort to meet these requirements, an iridium plug has been developed that achieves high ignitability and long service life through reduction of its diameter, using a highly wear-resistant iridium alloy as the center electrode.(1)(2) Recently, direct injection engines have attracted attention. In stratified combustion, a feature of the direct injection engine, the introduction of rich air-fuel mixtures in the vicinity of the plug ignition region tends to cause carbon fouling. This necessitates plug carbon fouling resistance.
Technical Paper

New Lighting System for Electronic Analog Clusters

1990-02-01
900675
The development of a high tech image analog cluster providing good readability is required by today's customer. To satisfy this trend, we have developed a highly unique analog cluster, which features very sharp white lit pointers with evenly illuminated white dials on a black acrylic face. These features are primarily achieved through two new lighting sources: 1. Pointers made from thin, lightweight Cold Cathode Discharge Tubes. This pointer creates very high brightness, regardless of temperature, by enclosing xenon gas in the tube, and was designed into a single side electrode structure. 2. Circular shape Cold Cathode Tube Installed Behind Each Dial Applique. This application creates very bright high quality illumination. In this session, we would like to introduce the construction and system of two new lighting sources for lexus, LS400. This technology provide improved readability.
Technical Paper

Development of High Performance Three-Way-Catalyst

2006-04-03
2006-01-1061
In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.
Technical Paper

Mechanism of Intake Valve Deposit Formation Part III: Effects of Gasoline Quality

1992-10-01
922265
Quality control of gasoline constituents and its effect on the Intake Valve Deposits (IVD) has become a recent issue. In this paper, the effects of gasoline and oil quality on intake valve deposits were investigated using an Intake Valve Deposit Test Bench and a Sludge Simulator. The deposit formation from the gasoline maximized at an intake valve temperature of approximately 160 °C, and the deposits formed from the engine oil were maximum at approximately 250 °C. Therefore, the contribution of the gasoline or the engine oil appears to depend on the engine conditions. The gasoline which contains MTBE or ethanol with no detergent additive slightly increases the deposition amount. The gasoline with a superior detergent significantly decreases the deposition amount even when MTBE or ethanol is blended in the gasoline. Appropriate detergent fuel additive retards the oil deterioration.
Technical Paper

High Durability of Metal Support for Automotive Catalyst

1995-02-01
950622
A metal support for use in an automotive catalyst is exposed to the severe heat cycle brought about by the intermittent flow of a high temperature exhaust gas. Accordingly, the metal support must have high beat resistance(ex. oxidation resistance) and a rigid structure. Therefore, 20% chromium-5% aluminum ferritic stainless steel(containing small quantities of rare earth metals and titanium) is used as a highly beat resistant honeycomb foil in addition to a highly mechanical durable brazing honeycomb structure. This study examined the durability of a metal honeycomb installed in a gasoline engine. Both an engine bench durability test of a manifold converter type metal support which is connected directly to the exhaust manifold of the gasoline engine and a vehicle durability test of an under the floor type metal support were carried out to evaluate oxidation damage of the metal honeycomb as well as its mechanical durability.
Technical Paper

Investigation on Oxidation Stability of Engine Oils Using Laboratory Scale Simulator

1995-10-01
952528
The purposes of this paper are to develop a new laboratory oxidation stability testing method and to clarify factors relative to the viscosity increase of engine oil. Polymerized products, obtained from the oil after a JASO M333-93 engine test, were found to consist mainly of carboxyl, nitrate and nitro compounds and to increase the oil viscosity. A good similarity between the JASO M333-93 test and the laboratory simulation test was found for the polymerized products. The products were obtained not by heating oil only in air but by heating oil while supplying a synthetic blowby gas consisting of fuel pyrolysis products, NO, SO2 and air. The laboratory test has also revealed that the viscosity increase depends on oil quality, organic Fe content and hydrocarbon composition in the fuel. Moreover, it has been found that blowby gas and organic Fe accelerate ZnDTP consumption and that aromatics concentration in the fuel correlates with the viscosity increase of oil.
Technical Paper

A Multi-Dimensional Numerical Method for Predicting Warm-Up Characteristic of Automobile Catalytic Converter Systems

1995-10-01
952413
A multi-dimensional numerical method for predicting the warm-up characteristic of automobile catalytic converter systems was developed to effectively design catalytic converter systems which achieve low tail pipe emissions with satisfactory packagebility. The features of the method are; (1) consideration of the governing phenomena such as gas flow, heat transfer, and chemical reactions (2) capability of predicting warm-up characteristic for not only the catalytic converters but also the system as a whole during emission test modes such as the USA LA-4 mode. The description of the method is presented. The experimental verifications of the method were conducted to assure the accuracy of it. The effect of design parameters such as electrically heated catalyst (EHC), high loading of noble metal and thin honeycomb wall on warm-up characteristic of the catalyst are analyzed in the paper.
Technical Paper

Numerical Analysis of Fuel Behavior in a Port-Injection Gasoline Engine

1997-02-24
970878
Three-dimensional numerical analysis of fuel liquid and mixture behavior in a port-injection gasoline engine is assessed by comparing calculations with measurements. The fuel mass distributed in the intake port and cylinder is measured using an engine with hydraulic valve and gas sampling system. The experimental results show that about half of the fuel mass per injection enters the cylinder, and the rest stays in the port. The difference of the mass fraction of injected fuel directly entering the cylinder is small between the cases of single pulse injection and serial injection. Therefore, three-dimensional calculation presupposing single pulse injection has difficulty in predicting the in-cylinder mixture formation process, although it can analyze the amount of fuel wetting the port wall. The calculations are performed for a port-injection engine, and the differences of fuel behavior with respect to swirl control valve opening and wall temperature are discussed.
Technical Paper

Fuel Effects on Particulate Emissions from D.I. Engine - Relationship among Diesel Fuel, Exhaust Gas and Particulates

1997-05-01
971605
The compositions of hydrocarbons in diesel fuel, exhaust gas and particulates were analyzed and the relationships among them were determined. It was found that the compositions of the hydrocarbons in the exhaust gas were almost the same as that of the fuel, and that the hydrocarbons in the particulates corresponded to their heavy fractions. When the engine condition was fixed, both the soluble organic fraction (SOF) and insoluble fraction ( ISF) showed positive correlation coefficients versus HC×R310, where HC denotes the hydrocarbon emission and R310 denotes the backend fraction, as measured by the fraction of fuel boiling above 310°C. On the other hand, when the engine condition was varied, ISF had negative correlation coefficients versus HC×R310, while SOF showed positive correlation coefficients.
Technical Paper

Regenration Process of Ceramic Foam Diesel-Particulate Traps

1984-10-01
841394
Periodic regeneration of the diesel particulate trap is essential to maintain the collection efficiency and exhaust gas hack pressure at acceptable levels. The objectives of this study are to describe the phenomenology of ceramic foam filter regeneration process and to present its mathematical model. Further simulation study is carried out to estimate the effects of various factors including fuel additive on the ignition and the filter bed temperature and to investigate conditions of excessive temperature which could result in filter destruction. The model is based on the assumption that the regeneration process is composed of two steps. The first step is the additional heat supply from the external energy source, and the second step is the spontaneous combustion propagation. The results from the analytical model agreed very well with the experimental results.
Technical Paper

Plasma Treatment for Painting of Polypropylene Bumper

1985-02-01
850320
The colour painting of polypropylene bumpers has required development of a new polypropylene surface treatment which provides improved adhesion of the paint film to polypropylene. According to the results of various improvement studies on the application of plasma treatment, it has been discovered that surface treatment by means of plasma of an oxygen and nitrogen gas mixture activated by microwave (2,450 MHz) provides a remarkable improvement in adhesion. Furthermore, establishing a technique to diffuse plasma effectively within the treatment chamber has enabled a uniform surface treatment of several polypropylene bumpers formed in large and complicated shapes.
Technical Paper

Toyota EC-HYMATIC – A New Full Time 4WD System for Automatic Transmission

1989-02-01
890526
Toyota has developed a new full time 4WD system, called “EC-HYMATIC” or Electronically Controlled - HYdraulic Multi-plate clutch Active Traction Intelligent Control. This system permits an automatic torque transfer, depending on driving conditions, for front and rear wheels under control of the speed difference between the two. The system developed consists of a center differential, a speed difference control clutch system employing multi-plate clutch, and a gear set for rear axle drive. The speed difference control clutch system is controlled by a unique electro-hydraulic system using a microcomputer. An extensive use of computer simulations and vehicle test and evaluation has successfully developed an appropriate control strategy for the clutch system. The new 4WD system, EC-HYMATIC, considerably improves handling characteristics, traction performance and stability of a 4WD vehicle.
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