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Significant reduction in Nitrogen Oxide (NOx) emissions will be required to meet LEV III/Tier III Emissions Standards for Light Duty Diesel (LDD) passenger vehicles. As such, Original Equipment Manufacturers (OEMs) are exploring all possible aftertreatment options to find the best balance between performance, durability and cost. The primary technology adopted by OEMs in North America to achieve low NOx levels is Selective Catalytic Reduction (SCR). The critical parameters needed for SCR to work properly are: an appropriate reductant such as ammonia (NH3) provided as Diesel Exhaust Fluid (DEF), which is an aqueous urea solution 32.5% concentration in weight with water (CO(NH2)2 + H2O), optimum operating temperatures, and optimum nitrogen dioxide (NO2) to NOx ratios (NO2/NOx). The NO2/NOx ratio is most influenced by Precious Group Metals (PGM) containing catalysts upstream of the SCR catalyst.

A production calibrated GTDI 1.6L Ford Fusion was used to demonstrate low HC, CO, NOx, PM (particulate mass), and PN (particulate number) emissions using advanced catalyst technologies with newly developed high porosity substrates and coated GPFs (gasoline particulate filters). The exhaust system consisted of 1.2 liters of TWC (three way catalyst) in the close-coupled position, and 1.6L of coated GPF in the underfloor position. The catalysts were engine-aged on a dynamometer to simulate 150K miles of road aging. Results indicate that ULEV70 emissions can be achieved at ∼$40 of PGM, while also demonstrating PM tailpipe performance far below the proposed California Air Resources Board (CARB) LEV III limit of 1 mg/mi. Along with PM and PN analysis, exhaust system backpressure is also presented with various GPF designs.

Proposed LEV-III emission level will require improvements in NMOG, CO and NOx emissions as measured over FTP and US06 emission cycles. Incremental improvements in washcoat technologies, cold start calibration and catalyst system design are required to develop a cost effective solution set. New catalyst technologies demonstrated both lower HC and NOx emissions with 25% less platinum group metals (PGM). FTP and US06 emissions were measured on a 4-cylinder 2.4L application which compares a close-coupled converter and close-coupled + underfloor converter systems. A PGM placement study was performed with the close-coupled converter system employing these new catalyst technologies. Emissions results suggest that the placement of PGM is critical in minimizing emissions and PGM costs.

The nonroad Final Tier 4 US EPA emission standards require 88% reduction in NOx emission from the Interim Tier 4 standards. It is necessary to utilize aftertreatment technologies to achieve the required NOx reduction. The development of a fuel reformer, lean NOx trap (LNT) and optional selective catalytic reactor (SCR) on a John Deere 4045 nonroad engine is described in this paper. The paper discusses aftertreatment system performance, catalyst formulations and system controls of a fuel vaporizer, fuel reformer, LNT and SCR system designed to meet the nonroad Final Tier 4 emission standards. The 4045 John Deere engine was calibrated and integrated with the aftertreatment system. The system performance was characterized in an engine dynamometer performance test cell, durability test cell and on a vehicle. The catalyst performance was evaluated using aged catalysts and a detailed description of the LNT, DPF and SCR catalysts is provided.

The fuel air ratio imbalance between individual cylinders can result in poor fuel economy and severe exhaust emissions. Individual cylinder fuel air ratio control is one of the important techniques used to improve fuel economy and reduce exhaust emission. California Air Resources Board (CARB) also has required automotive manufacturers to equip with on-board diagnosis system for cylinder fuel air ratio imbalance detection starting in 2011. However, one of the most challenging tasks for the individual cylinder fuel air ratio control and cylinder imbalance diagnosis is how to retrieve the cylinder fuel air ratio information effectively at low cost. This paper presents a novel and practical signal processing based fuel air ratio estimation method for individual cylinder fuel air ratio balance control and on-board fuel air ratio imbalance diagnosis.

To meet the 2010 diesel engine emission regulations, an aftertreatment system was developed to reduce HC, CO, NOx and soot. In NOx reduction, a baseline SCR module was designed to include urea injector, mixing decomposition tube and SCR catalysts. However, it was found that the baseline decomposition tube had unacceptable urea mixing performance and severe deposit issues largely because of poor hardware design. The purpose of this article is to describe necessary development work to improve the baseline system to achieve desired mixing targets. To this end, an emissions Flow Lab and computational fluid dynamics were used as the main tools to evaluate urea mixing solutions. Given the complicated urea spray transport and limited packaging space, intensive efforts were taken to develop pre-injector pipe geometry, post-injector cone geometry, single mixer design modifications, and dual mixer design options.

Using gasoline and diesel simultaneously in a dual-fuel combustion system has shown effective benefits in terms of both brake thermal efficiency and exhaust emissions. In this study, the dual-fuel approach is applied to a light-duty spark ignition (SI) gasoline direct injection (GDI) engine. Three combustion modes are proposed based on the engine load, diesel micro-pilot (DMP) combustion at high load, SI combustion at low load, and diesel assisted spark-ignition (DASI) combustion in the transition zone. Major focus is put on the DMP mode, where the diesel fuel acts as an enhancer for ignition and combustion of the mixture of gasoline, air, and recirculated exhaust gas. Computational fluid dynamics (CFD) is used to simulate the dual-fuel combustion with the final goal of supporting the comprehensive optimization of the main engine parameters.

Flame ionization detector (FID) analyzers used in emission testing to measure total hydrocarbon emissions have been operating for the last forty years on a fuel mixture of 40% H₂ and 60% helium. These mixtures were selected based on research studies reported in the literature indicating that this particular mixed fuel combination gave the best sensitivity and relative response of the different hydrocarbons present in vehicle exhaust with respect to propane, the calibration gas. During the past few years, it was announced that there is a worldwide shortage of helium which triggered the automotive industry to look for alternatives for helium to be used in FID fuels. Helium which is produced as a byproduct from natural gas fields is non-renewable, expensive, and extremely rare on the earth. Current supply cannot keep up with demand. There are only few natural gas fields producing helium and unless new natural gas fields are found, current helium amounts will continue to dwindle.

In-line hydrocarbon (HC) traps are not widely used to reduce HC emissions due to their limited durability, high platinum group metal (PGM) concentrations, complicated processing, and insufficient hydrocarbon (HC) retention temperatures required for efficient conversion by the three-way catalyst component. New trapping materials and system architectures were developed utilizing an engine dynamometer test equipped with dual Fourier Transform Infrared (FTIR) spectrometers for tracking the adsorption and desorption of various HC species during the light-off period. Parallel laboratory reactor studies were conducted which show that the new HC trap formulations extend the traditional adsorption processes (i.e., based on physic-sorption and/or adsorption at acid sites) to chemical reaction mechanisms resulting in oligomerized, dehydro-cyclization, and partial coke formation.

Due to increased demand for improved fuel economy and reduction in CO2 emissions, active grille shutter (AGS) has been considered as one option to increase fuel economy by reducing vehicle drag resistance. An AGS system will allow airflow through the grille when demand on cooling system or air conditioning system is high. Under conditions of light load and moderate ambient temperatures and humidity, the grille does not have to be fully open. A reduction in the effective grille size opening can be achieved by either partially or fully closing the grille through a stepped speed motor actuator. When the grille opening size is reduced, under-hood airflow will decrease. Therefore, the operating points for the grille shutter should take into account the effect of temperature rise for under-hood and underbody components and the performance of the cooling and climate control systems.

To meet TierII/LEVII emissions standards, light duty diesel (LDD) vehicles require high conversion efficiencies from the Aftertreatment Systems (ATS) for the removal of both Hydrocarbon (HC) and Nitrogen Oxide (NOx) species. The most populous configuration for LDD ATS have the Selective Catalytic Reduction (SCR) catalyst positioned on the vehicle behind the close coupled Diesel Oxidation Catalyst (DOC) and Catalyzed Diesel Particulate Filter (CDPF). This SCR position may require active heating measures which rely on the DOC/CDPF to provide heat through the combustion of HC and CO in the exhaust. Although DOCs are always impacted by their aging conditions, some aging conditions are shown to be both reversible and irreversible.

Growing concerns about the environment, energy dependency, and unstable fuel prices have increased the market share of electric vehicles. This has led to an increased demand for energy efficient routing algorithms that are optimized for electric vehicles. Traditional routing algorithms are focused on finding the shortest distance or the least time route between two points. These approaches have been working well for fossil fueled vehicles. Electric vehicles, on the other hand, require different route optimization techniques. Negative edge costs, battery power and capacity limits, as well as vehicle parameters that are only available at query time, make the task of electric vehicle routing a challenging problem. In this paper, we present a simulated solution to the energy efficient routing for electric vehicles using Particle Swarm Optimization. Simulation results show improvements in the energy consumption of the electric vehicle when applied to a start-to-destination routing problem.

Gasoline Particulate Filters (GPF), are universally acknowledged as a reliable and high cost effective emission control technology for particulate mass (PM) and particulate number (PN). Bare GPFs can be modified by coating with catalytic washcoat to provide emission reduction for THC, CO and NOx while back pressure (BP) and filtration efficiency (FE) might be influenced. In this study, a four cylinder China 6B calibrated 1.6 L TGDI (turbo gasoline direct injection) vehicle was used to evaluate various catalyst combinations in the close-coupled and underfloor locations. In the close-couple 1 position (CC1), PGM loadings were varied on a 1 L TWC. Next in the close-coupled 2 position (CC2), coated and uncoated 1.4 L GPFs were evaluated. PGM loading was varied on the coated GPFs using 300/8 high porosity substrates. The uncoated GPFs used a 200/8 low porosity substrates. In the underfloor location, PGM loadings were varied on two 0.5 L TWC catalysts.

Advances in diesel engine and catalyst technologies have enabled light passenger vehicles in meeting the most stringent Tier 3/LEV III emission levels and durability requirements. The advancements in diesel aftertreatment catalyst technology have made catalysts more susceptible to low levels of impurities, typically referred to as poisons. Published studies over the last two decades, have shown a significant impact on the performance of catalysts, to the presence of sulfur and other inorganics in fuels and oils. The design of an aftertreatment system (ATS) typically sets limits for lubricant and fuel quality, specific to the geographical region and availability of certain level of regulated fuels. In this study, we investigate a real-world aged diesel vehicle which exhibited deterioration in tailpipe emissions, beyond levels targeted during engineering development.