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Because of domestic production from renewable sources and their clean burning nature, alcohols, especially ethanol, have seen growing use as a blending agent and replacement for basic hydrocarbons in gasoline. The increasing use of alcohol in fuels raises questions on the safety of these fuels under certain non-operational situations. Modern vehicles use evaporative emission control systems to minimize environmental emissions of fuel. These systems must be relatively leak-free to function properly and are self-diagnosed by the vehicle On-Board Diagnostic system. When service is required, the service leak testing procedures may involve forcing test gases into the “evap” system and also exposure of the fuel vapors normally contained in the system to atmosphere. Previous work has discussed the hazards involved when performing shop leak testing activities for vehicles fuelled with conventional hydrocarbon gasoline [1, 2].

An experimental study of a glow plug engine combustion process has been performed by applying chemiluminescence imaging. The major intent was to understand what kind of combustion is present in a glow plug engine and how the combustion process behaves in a small volume and at high engine speed. To achieve this, images of natural emitted light were taken and filters were applied for isolating the formaldehyde and hydroxyl species. Images were taken in a model airplane engine, 4.11 cm3, modified for optical access. The pictures were acquired using a high speed camera capable of taking one photo every second or fourth crank angle degree, and consequently visualizing the progress of the combustion process. The images were taken with the same operating condition at two different engine speeds: 9600 and 13400 rpm. A mixture of 65% methanol, 20% nitromethane and 15% lubricant was used as fuel.

Life Cycle Value Assessment (LCVA) is a decision making tool which considers environmental, economic and/or social aspects for the entire life cycle of a product or process from “cradle-to-grave”. LCVA can be used for a wide range of public policy and business decisions with the analysis being performed at various levels of rigour. By its nature, LCVA utilizes data sets of varying qualities drawn from a wide range of sources. The uncertainties in the input data obviously lead to uncertainties in the results of the LCVA analysis. To establish confidence in an LCVA's recommendations, it is important to consider these uncertainties and incorporate an assessment of uncertainty into the LCVA process. However, the diverse nature of the data sets being used makes it difficult to rigorously establish data uncertainty levels. In addition, the complexity of most life cycle models makes it difficult to trace uncertainty through the analysis process.

Fuel choices are being made today by consumers, industry and government. One such choice is whether to use reformulated gasoline to replace regular unleaded gasoline. A second choice involves the source of crude oil, with synthetic crude oil from tar sands currently expanding its share of the Canadian supply. Decision makers usually work with the direct economic consequences of their fuel choice. However, they generally lack the knowledge to measure environmental aspects of different fuel systems. This paper uses Life Cycle Value Assessment (LCVA) to demonstrate how the life cycle environmental aspects can be compared for alternative fuel choices. LCVA is an engineering decision making tool which provides a framework for the decision maker to consider the key economic and environmental impacts for the entire life cycle of alternative products or process systems.

It has been known from multi-zone simulations that HCCI combustion can be significantly affected by temperature stratification of the in-cylinder gas. With the same combustion timing (i.e. crank angles at 50% heat release, denoted as CA50), large temperature stratification tends to prolong the combustion duration and lower down the in-cylinder pressure-rise-rate. With low pressure-rise-rate HCCI engines can be operated at high load, therefore it is of practical importance to look into more details about how temperature stratification affects the auto-ignition process. It has been realized that multi-zone simulations can not account for the effects of spatial structures of the stratified temperature field, i.e. how the size of the hot and cold spots in the temperature field could affect the auto-ignition process. This question is investigated in the present work by large eddy simulation (LES) method which is capable of resolving the in-cylinder turbulence field in space and time.

Although HCCI engines promise low NOx emissions with high efficiency, they suffer from a narrow operating range between knock and misfire because they lack a direct means of controlling combustion timing. A series of previous studies showed that reformer gas, (RG, defined as a mixture of light gases dominated by hydrogen and carbon monoxide), can be used to control combustion timing without changing mixture dilution, (λ or EGR) which control engine load. The effect of RG blending on combustion timing was found to be mainly related to the difference in auto-ignition characteristics between the RG and base fuel. The practical effectiveness of RG depends on local production using a fuel processor that consumes the same base fuel as the engine and efficiently produces high-hydrogen RG as a blending additive.

Natural gas is a challenging fuel for HCCI engines because its single-stage ignition and rapid combustion make it difficult to optimize combustion timing over a significant load range. This study investigates direct injection of a pilot quantity of high-cetane fuel near TDC as a range extension and combustion control mechanism for natural gas HCCI engines. The EGR and load range is studied in a supercharged natural gas HCCI engine equipped with external EGR, intake heating and a direct injection system for n-heptane pilot fuel. The operating range and emissions are of primary interest and are compared between both the baseline HCCI engine with variable intake temperature and the direct injected HCCI (DI-HCCI) engine with constant intake temperature. Test results show the EGR and load range at fixed intake temperature can be extended using pilot direct injection.

Life Cycle Analysis (LCA) considers the key environmental impacts for the entire life cycle of alternative products or processes in order to select the best alternative. An ideal LCA would be an expensive and time consuming process because any product or process typically involves many interacting systems and a considerable amount of data must be analysed for each system. Practical LCA methods approximate the results of an ideal analysis by setting limited analysis boundaries and by accepting some uncertainty in the data values for the systems considered. However, there is no consensus in the LCA field on the correct method of selecting boundaries or on the treatment of data set uncertainty. This paper demonstrates a new method of selecting system boundaries for LCA studies and presents a brief discussion on applying Monte Carlo Analysis to treat the uncertainty questions in LCA.

Although there seems to be a consensus regarding the low emission potential of DME, there are still different opinions about why the low NOx emissions can be obtained without negative effects on thermal efficiency. Possible explanations are: The physical properties of DME affecting the spray and the mixture formation Different shape and duration of the heat release in combination with reduced heat losses In this paper an attempt is made to increase the knowledge of DME in relation to diesel fuel with respect to heat release and NOx formation. The emphasis has been to create injection conditions as similar as possible for both fuels. For that purpose the same injection system (CR), injection pressure (270 bar), injection timing and duration have been used for the two fuels. The only differences were the diameters of the nozzle holes, which were chosen to give the same fuel energy supply, and the physical properties of the fuels.

Laser-Rayleigh imaging has been employed to measure the relative fuel concentration in the gaseous jet region of DME sprays. The measurements were performed in an optically accessible diesel truck engine equipped with a common rail injection system. A one-hole nozzle was used to guarantee that the recorded pressure history was associated with the heat release in the imaged spray. To compensate for the low compression ratio in the modified engine the inlet air was preheated. Spray development was studied for two levels of preheating, from the start of injection to the point where all fuel was consumed. The results indicate that there is a strong correlation between the amount of unburned fuel present in the cylinder and the rate of heat release at a given time. The combustion can not be described as purely premixed or purely mixing-controlled at any time, but always has an element of both. After all fuel appears to have vanished there is still an extended period of heat release.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

In this paper an online method for automatically reducing complex chemical mechanisms for simulations of combustion phenomena has been developed. The method is based on the Quasi Steady State Assumption (QSSA). In contrast to previous reduction schemes where chemical species are selected only when they are in steady state throughout the whole process, the present method allows for species to be selected at each operating point separately generating an adaptive chemical kinetics. The method is used for calculations of a natural gas fueled engine operating under Homogenous Charge Compression Ignition (HCCI) conditions. We discuss criteria for selecting steady state species and the influence of these criteria on the results such as concentration profiles and temperature.

Ion current measurements can give information useful for controlling the combustion stability in a multi-cylinder engine. Operation near the dilution limit (air or EGR) can be achieved and it can be optimized individually for the cylinders, resulting in a system with better engine stability for highly diluted mixtures. This method will also compensate for engine wear, e.g. changes in volumetric efficiency and fuel injector characteristics. Especially in a port injected engine, changes in fuel injector characteristics can lead to increased emissions and deteriorated engine performance when operating with a closed-loop lambda control system. One problem using the ion-current signal to control engine stability near the lean limit is the weak signal resulting in low signal to noise ratio. Measurements presented in this paper were made on a turbocharged 9.6 liter six cylinder natural gas engine with port injection.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

The Homogeneous Charge Compression Ignition (HCCI) is the third alternative for combustion in the Internal Combustion (IC) engines. Here, a homogeneous charge is used as in a spark ignited engine but the charge is compressed to auto-ignition as in a diesel. The characteristics of HCCI were compared to SI using a 1.6 liter single cylinder engine with compression ratio 21:1 in HCCI mode and 12:1 in SI mode. Three different fuels were used; isooctane, ethanol and natural gas. Some remarkable results were noted in the experiments: The indicated efficiency of HCCI was much better than for SI operation. Very little NOx was generated with HCCI, eliminating the need for a LeanNOx catalyst. However, HCCI generated more HC and CO than SI operation. Stable and efficient operation with HCCI could be obtained with λ=3 to λ=9 using isooctane or ethanol. Natural gas, with a higher octane number, required a richer mixture to run in HCCI mode.

Biodiesels are promising alternatives to diesel fuel since they are biodegradable, non-toxic and reduce air pollution. This study presents analytical comparisons of atomization characteristics of 3 types of biodiesels and 6 blends with Diesel No. 2. Results showed that the smallest and largest drop sizes were associated with coconut and peanut biodiesel blends, respectively. Using unblended biodiesels increases drop size by 40%, which indicates either custom nozzles should be used in such applications or blending is required to reduce surface tension and viscosity to enhance atomization. Knowledge of atomization of pure biodiesel and its blends as alternative fuels in diesel engines can lead to better design of diesel engine injectors to meet regulatory emission guidelines and engine performance.

Turbulent premixed natural gas - air flame velocities have been measured in a stationary axi-symmetric burner using LDA. The flame was stabilized by letting the flow retard toward a stagnation plate downstream of the burner exit. Turbulence was generated by letting the flow pass through a plate with drilled holes. Three different hole diameters were used, 3, 6 and 10 mm, in order to achieve different turbulent length scales. Turbulent integral length scales were measured using two-point LDA and the stretching in terms of the Karlovitz number could be estimated from these measurements. The results support previous studies indicating that stretching reduces the flame speed.

Diesel engined buses are the major means of transportation in many urban and suburban areas. Compared with other transportation systems, bus fleets are flexible, effective and low in capital cost. However, existing buses contribute to a serious air pollution problem in many cities. They also consume large amounts of diesel fuel, which is a concern for national economies where locally available natural gas could displace the more expensive petroleum-based fuel. New engine designs significantly reduce pollutants and some use alternative fuels. However, there is a huge infrastructure of existing diesel buses. Expensive new buses or bus engines will only gradually displace them, particularly in countries with weaker economies. The urgently required fuel replacement and pollution reduction benefits must be deferred into the future. These factors lead to the requirement for an economically viable, clean-burning conversion system to convert existing diesel engines to natural gas fuel.

This study describes the design and proof-of-concept testing of a system which has enabled sub-zero cold starting of a port-injected V6 engine fuelled with M100. At -30°C, the engine could reach running speed about 5s after the beginning of cranking. At a given temperature, starts were achieved using a fraction of the mixture enrichment normally required for the more volatile M85 fuels. During cold start cranking, firing is achieved using a high energy plasma jet ignition system. The achievement of stable idling following first fire is made possible through the use of an Exhaust Charged Cycle (ECC) camshaft design. The ECC camshaft promptly recirculates hot exhaust products, unburnt methanol and partial combustion products back into the cylinder to enhance combustion. The combined plasma jet/ECC system demonstrated exceptionally good combustion stability during fast idle following sub-zero cold starts.

The most economical way to convert truck and bus DI-diesel engines to natural gas operation is to replace the injector with a spark plug and modify the combustion chamber in the piston crown for spark ignition operation. The modification of the piston crown should give a geometry well suited for spark ignition operation with the original swirling inlet port. Ten different geometries were tried on a converted VOLVO TD102 engine and a remarkably large difference in the rate of combustion was noted between the chambers. To find an explanation for this difference a cycle resolved measurement of the in-cylinder mean velocity and turbulence was performed with Laser Doppler Velocimetry (LDV). The results show a high correlation between in cylinder turbulence and rate of heat release in the main part of combustion.