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Technical Paper

Exhaust-Gas Reforming of Hydrocarbon Fuels

1993-04-01
931096
This paper presents the findings of theoretical and practical studies of an exhaust-gas reforming process, as applied to hydrocarbon fuels. It is shown that hydrogen-containing gaseous reformed fuels can be produced by the interaction of hot combustion products and an n-heptane feedstock in a small-scale catalytic reforming reactor. Predicted and observed reformed fuel chemical compositions were found to correlate well at the lower reactor space velocities tested, where chemical equilibrium conditions can be closely approached. Under these conditions, respective hydrogen and carbon monoxide yields of around 32 and 20 volume per cent were obtained. Under certain conditions, it was found that carbon solids were deposited on the reforming catalyst. Measures taken to avoid this problem included changes in the reforming oxidant to fuel ratio, and the addition of excess steam to the oxidant composition.
Technical Paper

Understanding the Role of Filtered EGR on PM Emissions

2011-08-30
2011-01-2080
In earlier work we have shown that engine operation with oxygenated fuels (e.g., biodiesel) reduces the particulate matter (PM) emissions and extends the engine tolerance to exhaust gas recirculation (EGR) before it reaches smoke limited conditions. The same result has also been reported when high cetane number fuels such as gas-to-liquid (GTL) are used. A likely mechanism for engine-out particulate growth is the reintroduction of particle nuclei into the cylinder through EGR. These recirculated PM particles serve as sites for further condensation and accumulation promoting larger and greater number of particles. In order to further our understanding of EGR influence on total PM production, a diesel particulate filter (DPF) was integrated into the EGR loop. A PM reduction of approximately 50% (soot) was achieved with diesel fuel through filtered EGR, whilst still maintaining a significant NOX reduction.
Technical Paper

Microkinetic Modelling for Propane Oxidation in Channel Flows of a Silver-Based Automotive Catalytic Converter

2011-08-30
2011-01-2094
Computational Fluid Dynamics (CFD) is used to simulate chemical reactions and transport phenomena occurring in a single channel of a honeycomb-type automotive catalytic converter under lean burn combustion. Microkinetic analysis is adopted to develop a detailed elementary reaction mechanism for propane oxidation on a silver catalyst. Activation energies are calculated based on the theory of the Unity Bond Index-Quadratic Exponential Potential (UBI-QEP) method. The order-of-magnitude of the pre-exponential factors is obtained from Transition State Theory (TST). Sensitivity analysis is applied to identify the important elementary steps and refine the pre-exponential factors of these reactions. These pre-exponential factors depend on inlet temperatures and propane concentration; therefore optimised pre-exponential factors are written in polynomial forms. The results of numerical simulations are validated by comparison with experimental data.
Technical Paper

CFD Analysis of Air Intake System with Negative Pressure on Intake Grill

2008-06-23
2008-01-1643
The objective of the current research was to predict and analyze the flow through the grill of air intake system which is positioned behind the front wheel arch of vehicle. Most of the vehicle used today locates the grill of air intake at the front side so to acquire benefit of ram effect. In some cases, however, the grill is located behind the vehicle to improve wading performance. The geometry of air intake system of Land Rover Freelander was used in the modelling approach. The study was focused on different flow speeds on the grill at high load operation where the air speed at the grill side is high and creates negative pressure. The CFD results are validated against experimental data of steady flow test bench.
Technical Paper

Effect of Intake Valves Timings on In-Cylinder Charge Characteristics in a DI Engine Cylinder with Negative Valve Overlapping

2008-04-14
2008-01-1347
This paper presents a computational investigation of the in-cylinder charge characteristics within a motored 4-valve direct injection HCCI engine cylinder with applied negative valve overlapping. Non-typical intake valve strategy was investigated; whereby the pair of intake valves was assumed to follow the same low-lift short-duration valve-lift profile but actuated at different timings. The phase of intake-valve-opening relative to that of exhaust-valve-closing was optimized in terms of pumping losses. The flow fields generated with such an intake valve strategy were compared to those produced in the same engine cylinder but with typical early and late intake-valve-timing. The computational results of such an approach showed modifications in the in-cylinder swirl and tumble motions during the intake and compression strokes.
Technical Paper

Fabrication of Alumina Composite Microengine Parts using Softlithography

2009-04-20
2009-01-0118
In this work, a detailed process for manufacturing 3D alumina composite microengine pistons is presented. A novel moulding process is developed for shaping alumina composites into accurate micrometer-sized parts with a combination of softlithography micromoulding techniques and colloidal ceramic powder process. Ultrathick SU-8 UV-lithography is used for making master moulds followed by mirror duplication of PDMS softmoulds. A preceramic coating resin (PCR) was used as the binder instead of the traditionally organic binders and the PCR turns into an additive to the composite after the sintering process. The sedimentation of Al2O3/acetone suspensions has been characterized with varying poly vinyl pyrrolidone (PVP) as a dispersant. Optimized PCR and curing conditions have been investigated in the soft moulding process, and prove successful in achieving dense and uniform microcomponents.
Technical Paper

Performance, Emissions and Exhaust-Gas Reforming of an Emulsified Fuel: A Comparative Study with Conventional Diesel Fuel

2009-06-15
2009-01-1809
The fuel reforming technology has been extensively investigated as a way to produce hydrogen on-board a vehicle that can be utilized in internal combustion engines, fuel cells and aftertreatment technologies. Maximization of H2 production in the reforming process can be achieved when there is optimized water (steam) addition for the different reforming temperatures. A way to increase the already available water quantity on-board a vehicle (i.e. exhaust gas water content) is by using emulsified fuel (e.g. water-diesel blend). This study presents the effect of an emulsified diesel fuel (a blend of water and diesel fuel with an organic surfactant to make the mixture stable) on combustion in conjunction with exhaust gas assisted fuel reforming on a compression ignition engine. No engine modification was required to carry out these tests. The emulsified diesel fuel consisted of about 80% (mass basis) of conventional ultra low sulphur diesel (ULSD) fuel and fixed water content.
Technical Paper

Engine Performance and Emissions from Dual Fuelled Engine with In-Cylinder Injected Diesel Fuels and In-Port Injected Bioethanol

2009-06-15
2009-01-1853
Biofuels development and specification are currently driven by the engine (mainly gasoline- and diesel-type) technology, existing fossil fuel specification and availability of feedstock. The ability to use biofuels with conventional fuels without jeopardising the standard fuel specifications is a very effective means for the implementation of these fuels. In this work the effect of dual fuelling with in-cylinder injected ULSD fuel or synthetic second generation biofuels (a Gas-To-Liquid GTL fuel as a surrogate of these biofuels as its composition, specifications and production process are very similar to second generation biofuels) and with inlet port injected bioethanol on the engine performance and emissions were investigated. The introduction of anhydrous bioethanol improved the NOx and smoke emissions, but increased total hydrocarbons and carbon monoxide.
Technical Paper

Effect of Fuel Temperature on Performance and Emissions of a Common Rail Diesel Engine Operating with Rapeseed Methyl Ester (RME)

2009-06-15
2009-01-1896
The paper presents analysis of performance and emission characteristics of a common rail diesel engine operating with RME, with and without EGR. In both cases, the RME fuel was pre-heated in a heat exchanger to control its temperature before being pumped to the common rail. The studied parameters include the in-cylinder pressure history, rate of heat release, mass fraction burned, and exhaust emissions. The results show that when the fuel temperature increases and the engine is operated without EGR, the brake specific fuel consumption (bsfc) decreases, engine efficiency increases and NOx emission slightly decreases. However, when EGR is used while fuel temperature is increased, the bsfc and engine efficiency is independent of fuel temperature while NOx slightly increases.
Technical Paper

Particulate Emissions from a Gasoline Homogeneous Charge Compression Ignition Engine

2007-04-16
2007-01-0209
Particulate Emissions from Homogeneous Charge Compression Ignition (HCCI) combustion are routinely assumed to be negligible. It is shown here that this is not the case when HCCI combustion is implemented in a direct injection gasoline engine. The conditions needed to sustain HCCI operation were realized using the negative valve overlap method for trapping high levels of residual exhaust gases in the cylinder. Measurements of emitted particle number concentration and electrical mobility diameter were made with a Cambustion DMS500 over the HCCI operating range possible with this hardware. Emissions of oxides of nitrogen, carbon monoxide and unburned hydrocarbons were also measured. These data are presented and compared with similar measurements made under conventional spark ignition (SI) operation in the same engine. Under both SI and HCCI operation, a significant accumulation mode was detected with particle equivalent diameters between 80 and 100 nm.
Technical Paper

GDI Engine Performance and Emissions with Reformed Exhaust Gas Recirculation (REGR)

2013-04-08
2013-01-0537
Exhaust Gas Fuel Reforming has potential to be used for on-board generation of hydrogen rich gas, reformate, and to act as an energy recovery system allowing the capture of waste exhaust heat. High exhaust gas temperature drives endothermic reforming reactions that convert hydrocarbon fuel into gaseous fuel when combined with exhaust gas over a catalyst - the result is an increase in overall fuel energy that is proportional to waste energy capture. The paper demonstrates how the combustion of reformate in a direct injection gasoline (GDI) engine via Reformed Exhaust Gas Recirculation (REGR) can be beneficial to engine performance and emissions. Bottled reformate was inducted into a single cylinder GDI engine at a range of engine loads to compare REGR to conventional EGR. The reformate composition was selected to approximate reformate produced by exhaust gas fuel reforming at typical gasoline engine exhaust temperatures.
Technical Paper

A 1D Analysis into the Effect of Variable Valve Timing on HCCI Engine Parameters

2008-10-06
2008-01-2459
The effects of variable intake-valve-timing on the gas exchange process and performance of a 4-valve direct-injection HCCI engine were computationally investigated using a 1D gas dynamics engine cycle simulation code. A non-typical strategy to actuate the pair of intake valves was examined; whereby each valve was assumed to be actuated independently at different timing. Using such an intake valves strategy, the obtained results showed a considerable improvement of the engine parameters such as load and charging efficiency as compared with the typical identical intake valve pair timings case. Additional benefits of minimizing pumping losses and improving the fuel economy were demonstrated with the use of the non-simultaneous actuation of the intake valve pair having the opening timing of the early intake valve coupled with a symmetric degree of crank angle for the timing of exhaust valve closing.
Technical Paper

Activity of Prototype Catalysts on Exhaust Emissions from Biodiesel Fuelled Engines

2008-10-06
2008-01-2514
A prototype catalyst has been developed and integrated within the aftertreatment exhaust system to control the HC, CO, PM and NOx emissions from diesel exhaust gas. The catalyst activity in removing HC and nano-particles was examined with exhaust gas from a diesel engine operating on biodiesel - Rapeseed Methyl Ester (RME). The tests were carried out at steady-state conditions for short periods of time, thus catalyst tolerance to sulphur was not examined. The prototype catalyst reduced the amount of hydrocarbons (HC) and the total PM. The quantity of particulate with electrical mobility diameter in nucleation mode size < 10nm, was significantly reduced over the catalyst. Moreover, it was observed that the use of EGR (20% vol.) for the biodiesel fuelled engine significantly increases the particle concentration in the accumulation mode with simultaneous reduction in the particle concentration in the nuclei mode.
Technical Paper

Split-Injection Strategies under Full-Load Using DMF, A New Biofuel Candidate, Compared to Ethanol in a GDI Engine

2012-04-16
2012-01-0403
It is well known that direct injection (DI) is a technology enabler for stratified combustion in spark-ignition (SI) engines. At full load or wide-open throttle (WOT), partial charge stratification can suppress knock, enabling greater spark advance and increased torque. Such split-injection or double-pulse injection strategies are employed when using gasoline in DI (GDI). However, as the use of biofuels is set to increase, is this mode still beneficial? In the current study, the authors attempt to answer this question using two gasoline-alternative biofuels: firstly, ethanol; the widely used gasoline-alternative biofuel and secondly, 2,5-dimethylfuran (DMF); the new biofuel candidate. These results have been benchmarked against gasoline in a single-cylinder, spray-guided DISI research engine at WOT (λ = 1 and 1500 rpm). Firstly, single-pulse start of injection (SOI) timing sweeps were conducted with each fuel to find the highest volumetric efficiency and IMEP.
Technical Paper

Combustion and Emission Characteristics of a PPCI Engine Fuelled with Dieseline

2012-04-16
2012-01-1138
In this paper blends of diesel and gasoline (dieseline) fuelled Partially Premixed Compression Ignition (PPCI) combustion and the comparison to conventional diesel combustion is investigated. The tests are carried out using a light duty four cylinder Euro IV diesel engine. The engine condition is maintained at 1800 rpm, 52 Nm (equivalent IMEP around 4.3 bar). Different injection timings and different amounts of EGR are used to achieve the PPCI combustion. The results show that compared to the conventional diesel combustion, the smoke and NOx emissions can be reduced by more than 95% simultaneously with dieseline fuelled PPCI combustion. The particle number total concentration can be reduced by 90% as well as the mean diameter (from 54 nm for conventional diesel to 16 nm for G50 fuelled PPCI). The penalty is a slightly increased noise level and lower indicated efficiency, which is decreased from 40% to 38.5%.
Technical Paper

An Optical Study of DMF and Ethanol Combustion Under Dual-Injection Strategy

2012-04-16
2012-01-1237
The new fuel, 2, 5-dimenthylfuran, known as DMF, captured worldwide attention since the discovery of its new production method. As a potential bio-fuel, DMF is competitive to gasoline in many areas, such as energy density, combustion efficiency and emissions. However, little work has been performed on its unconventional combustion mode. In this work, high speed imaging and thermal investigation are carried out to study DMF and gasoline dual-injection on a single cylinder, direct injection spark ignition optical engine. This dual-injection strategy combines direct injection (DI) and port fuel injection (PFI) simultaneously which means two different fuels can blend in the cylinder with any ratio. It provides a flexible way to use bio-fuels with gasoline. DMF DI with gasoline PFI and ethanol DI with gasoline PFI are studied under different injection proportions (by volume) and IMEPs.
Technical Paper

Improving Cold Start and Transient Performance of Automotive Diesel Engine at Low Ambient Temperatures

2016-04-05
2016-01-0826
Ambient temperature has significant impact on engine start ability and cold start emissions from diesel engines. These cold start emissions are accounted for substantial amount of the overall regulatory driving cycle emissions like NEDC or FTP. It is likely to implement the low temperature emissions tests for diesel vehicles, which is currently applicable only for gasoline vehicles. This paper investigates the potential of the intake heating strategy on reducing the driving cycle emissions from the latest generation of turbocharged common rail direct injection diesel engines at low ambient temperature conditions. For this investigation an air heater was installed upstream of the intake manifold and New European Driving Cycle (NEDC) tests were conducted at -7°C ambient temperature conditions for the different intake air temperatures. Intake air heating reduced the cranking time and improved the fuel economy at low ambient temperatures.
Technical Paper

A Thermally Efficient DOC Configuration to Improve CO and THC Conversion Efficiency

2013-04-08
2013-01-1582
The purpose of this study is to improve the carbon monoxide (CO) and total hydrocarbons (THC) conversion efficiency of a diesel oxidation catalyst (DOC) by enhancing the monolith thermal behaviour through modification of the substrate cell density and wall thickness. The optimisation is based on catalyst properties (light off performance, conversion efficiency, pressure drop and mechanical durability). These properties were first estimated using theoretical equations derived from literature in order to select commercially available substrates for further modelling studies. The thermal behaviour and conversion efficiency of the selected catalysts under diesel exhaust gas conditions were numerically studied using data from an EU5 diesel engine operating a New European Driving Cycle (NEDC). This simulation was carried out on a commercial exhaust aftertreatment modelling program, AXISUITE. The predictions were compared to a reference coated 400/4 catalyst.
Technical Paper

Investigation on the Self-Stabilization Feature of HCCI Combustion

2014-10-13
2014-01-2663
The combustion timing, work output and in-cylinder peak pressure for HCCI engines often converge to a stable equilibrium point, which implies that the HCCI combustion may have a self-stabilization feature. It is thought that this behavior is due to the competing residual-induced heating and dilution of the reactant gas. As one of the most important features of HCCI combustion, the self-stabilization behavior can give great guidance to people for designing controller for HCCI engine control. The self-stabilization features of HCCI combustion had been observed by many researchers and mentioned in some publications. However, there is no report to experimentally analyze this phenomenon individually. Due to the fuel injection normally ending during the NVO process and the spark plug is turned off for HCCI engines, there is no direct control approach between the Intake Valve Close (IVC) and the start of combustion.
Technical Paper

Experimental Study of Multiple Premixed Compression Ignition Engine Fueled with Heavy Naphtha for High Efficiency and Low Emissions

2014-10-13
2014-01-2678
A study of Multiple Premixed Compression Ignition (MPCI) with heavy naphtha is performed on a light-duty single cylinder diesel engine. The engine is operated at a speed of 1600rpm with the net indicated mean effective pressure (IMEP) from 0.5MPa to 0.9MPa. Commercial diesel is also tested with the single injection for reference. The combustion and emissions characteristics of the heavy naphtha are investigated by sweeping the first (−200 ∼ −20 deg ATDC) and the second injection timing (−5 ∼ 15 deg ATDC) with an injection split ratio of 50/50. The results show that compared with diesel combustion, the naphtha MPCI can reduce NOx, soot emissions and particle number simultaneously while maintaining or achieving even higher indicated thermal efficiency. A low pressure rise rate can be achieved due to the two-stage combustion character of the MPCI mode but with the penalty of high HC and CO emissions, especially at 0.5MPa IMEP.
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