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Exhaust particulate emissions from a 4-cylinder, 2.25 liter spark ignition engine were measured and characterized. A single-stage ejector-diluter system was used to dilute and cool the exhaust sample for measurement. The particulate measurement equipment included a condensation nucleus counter and a scanning mobility particle sizer. Exhaust measurements were made both upstream and downstream of the catalytic converter using three different fuels. Unlike particulate emissions in diesel engines, spark ignition exhaust particle emissions were found to be highly unstable. Typically, a stable “baseline” concentration on the order of 105 particles/cm3 is emitted. Occasionally, however, a “spike” in the exhaust particle concentration is observed. The exhaust particle concentrations observed during these spikes can increase by as much as two orders of magnitude over the baseline concentration.

Exhaust particle number concentrations and size distributions were measured from the exhaust of a 1995 direct injection, Diesel engine. Number concentrations ranged from 1 to 7.5×107 particles/cm3. The number size distributions were bimodal and log-normal in form with a nuclei mode in the 7-15 nm diameter range and an accumulation mode in the 30-40 nm range. For nearly all operating conditions, more than 50% of the particle number, but less than 1% of the particle mass were found in the nuclei mode. Preliminary indications are that the nuclei mode particles are solid and formed from volatilization and subsequent nucleation of metallic ash from lubricating oil additives. Modern low emission engines produce low concentrations of soot agglomerates. The absence of these agglomerates to act as sites for adsorption or condensation of volatile materials makes nucleation and high number emissions more likely.