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The performance of a commercial Cu-zeolite SCR catalyst after differing degrees of hydrothermal aging (aged for 72 hours at 500, 700 and 800°C with 10% moisture balanced with air) was studied by spatially resolving different key reactions using gas-phase FTIR measurements. Gases were sampled along a channel at different positions and analyzed using FTIR, which overcomes the interference of water and nitrogen on ammonia concentration detection encountered in standard mass spectrometer-based spatial resolution measurements. The NO:NO₂ concentration ratio was changed so that the standard (NO:NO₂ = 1:0), fast (NO:NO₂ = 1:1) and NO₂ (NO:NO₂ = 0:1) SCR reactions could be investigated as a function of the catalyst's hydrothermal aging extent. In addition, the effects of hydrothermal aging on the activity of NH₃ and NO oxidation were also investigated. Hydrothermal aging had little effect on NO oxidation activity.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

A so-called damage percolation model is coupled with Gurson-based finite element (FE) approach in order to accommodate the high strain gradients and localized ductile damage. In doing so, void coalescence and final failure are suppressed in Gurson-based FE modeling while a measured second phase particle field is mapped onto the most damaged mesh area so that percolation modeling can be performed to capture ductile fracture in real sheet forming operations. It is revealed that void nucleation within particle clusters dominates ductile fracture in aluminum alloy sheet forming. Coalescence among several particle clusters triggered final failure of materials. A stretch flange forming is simulated with the coupled modeling.

This work outlines the evaluation of static and dynamic dent resistance of medium scale structural assemblies fabricated using AA6111 and AA5754. The assemblies fabricated attempt to mimic common automotive hood designs allowing for a parametric study of the support spacing, sheet thickness and panel curvature. Closure panels of AA6111, of two thicknesses (0.8, and 0.9mm), are bonded to re-usable inner panels fabricated using AA5754 to form the structural assemblies tested. While normal practice would use the same alloy for both the inner and the outer, in the current work, AA5754 was adopted for ease of welding. Numerical simulations were performed using LS DYNA. A comparison of experimental and numerically simulated results is presented. The study attempts to establish an understanding of the relationship between structural support conditions and resulting dent depths for both static and dynamic loading conditions.

The present work investigates weld failure modes during formability tests of multi-gauge aluminum Tailor Welded Blanks (TWBs). The limiting dome height test is used to evaluate formability of TWBs. Three gauge combinations utilizing aluminum alloy 5754 sheets are considered (2 to 1 mm, 1.6 to 1 mm and 2 to 1.6 mm). Three weld orientations have been considered: transverse, longitudinal and 45°. Interaction of several factors determines the type of failure that occurs in a TWB specimen. These factors are weld orientation, morphology and distribution of weld defects, and the magnitude of constraint imposed by the thicker sheet to the thin sheet. The last factor depends on the difference in thickness of the sheet pair and is usually expressed in terms of gauge ratio. In general TWBs show two different types of fracture: weld failure and failure of the thin aluminum sheet. Only the former will be discussed in this paper.

Plane strain tension is the critical stress state for sheet metal forming because it represents the extremum of the yield function and minima of the forming limit curve and fracture locus. Despite its important role, the stress response in plane strain deformation is routinely overlooked in the calibration of anisotropic plasticity models due to challenges and uncertainty in its characterization. Plane strain tension test specimens used for constitutive characterization typically employ large gage width-to-thickness ratios to promote a homogeneous plane strain stress state. Unfortunately, the specimens are limited to small strain levels due to fracture initiating at the edges in uniaxial tension. In contrast, notched plane strain tension coupons designed for fracture characterization have become common in the automotive industry to calibrate stress-state dependent fracture models. These coupons have significant stress and strain gradients across the gage width to avoid edge fracture.

Battery packs of electric vehicles are typically composed of lithium-ion batteries with aluminum and copper acting as cell terminals. These terminals are joined together in series by means of connector tabs to produce sufficient power and energy output. Such critical electrical and structural cell terminal connections involve several challenges when joining thin, highly reflective and dissimilar materials with widely differing thermo-mechanical properties. This may involve potential deformation during the joining process and the formation of brittle intermetallic compounds that reduce conductivity and deteriorate mechanical properties. Among various joining techniques, laser welding has demonstrated significant advantages, including the capability to produce joints with low electrical contact resistance and high mechanical strength, along with high precision required for delicate materials like aluminum and copper.