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Biodiesel has been widely accepted as an alternative for fossil-derived diesel fuel for use in compression ignition (CI) engines. Poor oxidative stability and cold flow properties restrict the use of biodiesel beyond current B20 blend levels (20% biodiesel in 80% ULSD) for vehicle applications. Maintaining the properties of B20 as specified by ASTM D7476-08 is important because, once out of spec, B20 may cause injector coke formation, fuel filter plugging, increased exhaust emissions, and overall loss of engine performance. While the properties of fresh B20 may be within the specifications, under engine operating and longer storage conditions B20 could deteriorate. In a diesel engine, the fuel that goes to the injector and does not enter the cylinder is recycled back to the fuel tank. The re-circulated fuel returns to the fuel tank at an elevate temperature, which can cause thermal oxidation.

The use of butanol as an alternative biofuel blend component for conventional diesel fuel has been under extensive investigation. However, some fuel properties such as cetane number and lubricity fall below the accepted values as described by the ASTM D 975 diesel specifications. Blending 10% butanol with #2 ULSD decreases the cetane number by 7% (from 41.6 to 39.0). At higher butanol blend levels, i.e., 20% v/v, the cetane number decrease cannot be compensated for; even with the addition of a 2000 ppm level commercial cetane improver. The decreased cetane number, or in other words, increased ignition delay, can be attributed to the increased blend level of low cetane butanol as well as the critical physical properties for better atomization of fuels during auto ignition such as viscosity. The kinematic viscosity dropped sharply with increasing butanol blend level up to 25 % v/v, then increased with further increase of butanol blend level.

Fuel quality has a significant influence on the combustion engine operation. In recent years the increasing concerns about environmental protection, energy saving, energy security and the requirements of protecting fuel injection and aftertreatment systems have been major driving forces for the Chinese fuel specification evolution. The major property changes in the evolution of Chinese national gasoline and diesel standards are introduced and the reasons behind these changes are analyzed in this paper. The gasoline fuel development from State I to State VI-B involved a decrease of sulfur, manganese, olefins, aromatics and benzene content. The diesel fuel quality improvement from State I to State VI included achieving low sulfur fuels and a cetane number (CN) increase. Provincial fuel standards, stricter than corresponding national standards, were implemented in economically developed areas in the past.

The Department of Defense (DOD) has adopted the use of JP-8 under the “single battlefield fuel” policy. Fuel properties of JP-8 which are different from ULSD include cetane number, density, heating value and compressibility (Bulk modulus). While JP8 has advantages compared to ULSD, related to storage, combustion and lower soot emissions, its use cause a drop in the peak power in some military diesel engines. The engines that has loss in power use the Hydraulically actuated Electronic Unit Injection (HEUI) fuel system. The paper explains in details the operation of HEUI including fuel delivery into the injector and its compression to the high injection pressure before its delivery in the combustion chamber. The effect of fuel compressibility on the volume of the fuel that is injected into the combustion chamber is explained in details.

The combustion characteristics and soot emissions of three types of fuels were studied in a high pressure and temperature vessel. In order to achieve better volatility, proper cetane number and high oxygen content, the newly designed WDEP fuel was proposed and investigated. It is composed of wide distillation fuel (WD), PODE3-6 mixture (PODEn) and ethanol. For comparison, the test on WD and the mixture of PODEn-ethanol (EP) are also conducted. OH* chemiluminescence during the combustion was measured and instantaneous PLII was also applied to reveal the soot distribution. Abel transformation was adopted to calculate the total soot of axisymmetric flame. The results show that WDEP has similar ignition delays and flame lift-off lengths to those of WD at 870-920 K. But the initial ignition locations of WDEP flame in different cycles were more concentrated, particularly under the condition of low oxygen atmosphere.

Combustion visualizations were carried out in a constant volume vessel to study the partially premixed combustion of a gasoline-like fuel using high speed imaging. The test fuel (G80H20) is composed by volume 80% commercial gasoline and 20% n-heptane. The effects of ambient gas composition, ambient temperature and injection pressure on G80H20 combustion characteristics were analyzed. Meanwhile, a comparison of the EGR effect on combustion process between G80H20 and diesel was made. Four ambient gas conditions that represent the in-cylinder gas compositions of a heavy-duty diesel engine with EGR ratios of 0%, 20%, 40% and 60% were used to simulate EGR conditions. Variables also include two ambient temperature (910K and 870K) and two injection pressure (20 MPa and 50 MPa) conditions.

Polyoxymethylene Dimethyl Ether (PODEn) is a promising green additive to diesel fuel, owing to the unique chemical structure (CH3O[CH2O]nCH3, n≥2) and high cetane number. Together with the general wide-distillation fuel (WDF), which has an attractive potential to reduce the cost of production of vehicle fuel, the oxygenated WDF with PODEn can help achieve a high efficiency and low emissions of soot, NOx, HC, and CO simultaneously. In this paper, the first detailed reaction mechanism (225 species, 1082 reactions) which can describe the ignition characteristics of PODE1 and PODE3 at low temperature was developed.

The effects of different biodiesel blends on engine-out emissions under various transient conditions were investigated in this study using fast response diagnostic equipment. The experimental work was conducted on a modern 3.0 L, V6 high pressure common rail diesel engine fuelled with mineral diesel (B0) and three different blends of rapeseed methyl esters (RME) (B30, B60, B100 by volume) without any modifications of engine parameters. DMS500, Fast FID and Fast CLD were used to measure particulate matter (PM), total hydrocarbon (THC) and nitrogen monoxide (NO) respectively. The tests were conducted during a 12 seconds period with two tests in which load and speed were changed simultaneously and one test with only load changing. The results show that as biodiesel blend ratio increased, total particle number (PN) and THC were decreased whereas NO was increased for all the three transient conditions.

Several mechanisms are discussed to understand the particulate matter (PM) characterization in a high speed, direct injection, single cylinder diesel engine using low sulfur diesel fuel. This includes their formation, size distribution and number density. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios, therefore covering both conventional and low temperature combustion regimes. A micro dilution tunnel was used to immediately dilute a small part of the exhaust gases by hot air. A Scanning Mobility Particle Sizer (SMPS) was used to measure the particulate size distribution and number density. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the root cause of PM characterization and their relationship with the combustion process under different operating conditions.

Several mechanisms are discussed to understand the formation of both regulated and unregulated emissions in a high speed, direct injection, single cylinder diesel engine using low sulphur diesel fuel. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios. The regulated emissions were measured by the standard emission equipment. Unregulated emissions such as aldehydes and ketones were measured by high pressure liquid chromatography and hydrocarbon speciation by gas chromatography. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the sources of different emission species and their relationship with the combustion process under the different operating conditions. Special attention is given to the low temperature combustion (LTC) regime which is known to reduce both NOx and soot. However the HC, CO and unregulated emissions increased at a higher rate.

This paper presents an experimental investigation conducted to determine the parameters that control the behavior of autoignition in a small-bore, single-cylinder, optically-accessible diesel engine. Depending on operating conditions, three types of autoignition are observed: a single ignition, a two-stage process where a low temperature heat release (LTHR) or cool flame precedes the main premixed combustion, and a two-stage process where the LTHR or cool flame is separated from the main heat release by an apparent negative temperature coefficient (NTC) region. Experiments were conducted using commercial grade low-sulfur diesel fuel with a common-rail injection system. An intensified CCD camera was used for ultraviolet imaging and spectroscopy of chemiluminescent autoignition reactions under various operating conditions including fuel injection pressures, engine temperatures and equivalence ratios.

The focus of this study is to determine the effect of using B-20 (a blend of 20% soybean methyl ester biodiesel and 80% ultra low sulfur diesel fuel) on the combustion process, performance and exhaust emissions in a High Speed Direct Injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated under simulated turbocharged conditions with 3-bar indicated mean effective pressure and 1500 rpm engine speed. The experiments covered a wide range of injection pressures and EGR rates. The rate of heat release trace has been analyzed in details to determine the effect of the properties of biodiesel on auto ignition and combustion processes and their impact on engine out emissions. The results and the conclusions are supported by a statistical analysis of data that provides a quantitative significance of the effects of the two fuels on engine out emissions.

As diesel emission regulations continue to increase, the use of exhaust aftertreatment systems containing, for example the diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) will become necessary in order to meet these stringent emission requirements. The addition of a DOC and DPF in conjunction with utilizing biodiesel fuels requires extensive research to study the implications that biodiesel blends have on emissions as well as to examine the effect on aftertreatment devices. The proceeding work discusses results from a 2006 VM Motori four-cylinder 2.8L direct injection diesel engine coupled with a diesel oxidation catalyst and catalyzed diesel particulate filter. Tests were done using ultra low sulfur diesel fuel blended with 20% choice white grease biodiesel fuel to evaluate the effects of biodiesel emission products on the performance and effectiveness of the aftertreatment devices and the effect of low temperature combustion modes.

Results of Computational Fluid Dynamic (CFD) analyses of different diesel fuel injector nozzle configurations using a commercial CFD code are presented here. The emphasis of this study is on comparing cavitation models available in the commercial code with respect to their mathematical approach. One of the models is a simple single-phase model based on the Barotropic equation of state, while the other model is a two-phase model based on the bubble dynamic considerations. Results are compared for various 3-D diesel injector nozzles using the two cavitation-modeling approaches. Simulation results are observed to substantiate some of the experimentally established facts like; nozzle efficiency improvements by using techniques like rounded orifice inlets and conical orifices. Also, simulation results agree well with the experimental results. Spray characteristics are predicted based on a primary breakup model.

Precise control of fuel delivery and injection pressure is essential in modern DI diesel engines. Electronically controlled high-pressure injection systems provide features required by modern diesel engines such as precise injection quantity, flexible injection timing, flexible rate of injection with multiple injections and high injection pressures. A comprehensive experimental and numerical investigation has been performed to determine the influence of operating parameters and critical injector design parameters on the dynamic performance of advanced high-pressure electronically controlled diesel injection systems. The injection systems compared in this study are the High Pressure Common Rail (HPCR) and the Hydraulic Electronic Unit Injector (HEUI). Experiments are carried out using a Bosch type injection-rate meter. Needle lift, injection-rate/rate shape, and injection pressure are measured.

An experimental setup using rapid compression machine to provide excellent optical access to visualize simulated high-speed small-bore direct injection diesel engine combustion processes is described. Typical combustion visualization results of diesel spray combustion under different EGR, swirl, and injection pressure and nozzle conditions are presented. Different swirl intensities are achieved using an air nozzle with variable orientations and a check valve to connect the compression chamber and the combustion chamber. Different EGR ratios are achieved by pre-injection of diesel fuel prior to the main observation sequence. Clear visualization of the high-pressure fuel injection, ignition, combustion and spray/wall/swirl interactions is obtained. The injection system is a high-pressure common-rail system with either a VCO or a mini-sac nozzle. High-speed movies up to 35,000 frame-per-second are taken using a framing drum camera to record the combustion events.

SASOL IPK is a low cetane number synthetic fuel formed from coal by the Fischer-Tropsch process which can be used as an extender to JP8, currently used in military ground vehicles. This paper presents two surrogates developed considering the following criteria: (a) availability of kinetic combustion models for each component, (b) smallest number of components to reduce computation time and cost, (c) matching the following properties of target fuel DCN, distillation curve, density, LHV, MW and H/C ratio. The autoignition and combustion characteristics of the surrogates were validated in IQT according to ASTM D6890-10a. Surrogate formulation strategy involves an equation to calculate DCN of the surrogate mixture from the DCN of each component. The linear equation commonly used for such calculations was modified to include a multiplier, based on regression analysis, for each component to produces DCN values that agree well with the measured DCN in the IQT.

Numerical simulations of diesel reacting jets in a simulated engine environment were carried out to study the effect of oxygen concentration on the ignition delay time and lift-off length dynamics. A recently developed mechanism, direct integration of chemistry, and well established Lagrangian-Eulerian spray model were utilized for 3-D turbulent spray combustion simulation under engine like conditions. The simulations are able to provide a time-history of chemical species including formaldehyde CH2O intermediates and hydroxide OH radicals to facilitate development of auto-ignition and lift off length numerical diagnostics. A range of important operating points including variations in the oxygen concentration, rail pressure, and injection duration were examined. The purpose of conducting the parametric studies is to investigate the consistency of the results and provide a more comprehensive analysis than a single point condition.

The superior fuel economy of direct injection internal combustion engines (diesel and gasoline) is related to use of a high compression ratio to auto-ignite the fuel and the overall lean combustible mixture. Two of the major problems in diesel engine emissions are the NOx and soot emissions, which are caused by the heterogeneity of the charge and the properties of the diesel fuel. Conventional Direct Injection Spark Ignition Gasoline engines don't have these problems because of the fuel properties particularly its volatility. However, its efficiency and specific power output are limited by the knock, knock produced preignition and the sporadic preignition phenomenon. The Gasoline Direct Injection Compression Ignition (GDICI) engine combines the superior features of the two engines by increasing the compression ratio and use of gasoline as a fuel.

The present study helps to understand the local combustion characteristics of PREmixed Mixture Ignition in the End-gas Region (PREMIER) combustion mode while using increasing amount of natural gas as a diesel substitute in conventional CI engine. In order to reduce NOx emission and diesel fuel consumption micro-pilot diesel injection in premixed natural gas-air mixture is a promising technique. New strategy has been employed to simulate dual fuel combustion which uses well established combustion models. Main focus of the simulation is at detection of an end gas ignition, and creating an unified modeling approach for dual fuel combustion. In this study G-equation flame propagation model is used with detailed chemistry in order to detect end-gas ignition in overall low temperature combustion. This combustion simulation model is validated using comparison with experimental data for dual fuel engine.