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Three-way catalyst equipped stoichiometric natural gas vehicles have proven to be an effective alternative fuel strategy that has shown superior low NOx benefits in comparison to diesels equipped with SCR. However, recent studies have shown the TWC activity to contribute to high levels of tailpipe ammonia emissions. Although a non-regulated pollutant, ammonia is a potent pre-cursor to ambient secondary PM formation. Ammonia (NH3) is an inevitable catalytic byproduct of TWCduring that results also corresponds to lowest NOx emissions. The main objective of the study is to develop a passive SCR based NH3 reduction strategy that results in an overall reduction of NH3 as well as NOx emissions from a stoichiometric spark ignited natural gas engine. The study investigated the characteristics of Fe-based and Cu-based zeolite SCR catalysts in storage, and desorption of ammonia at high exhaust temperature conditions, that are typical of stoichiometric natural gas engines.

The temporary deactivation of the selective catalytic reduction (SCR) device due to malfunction requires the engine control to engage multiple engine-out calibrations. Further, it is expected that emitted particles will be different in composition, size and morphology when an engine, which meets the 2010 particulate matter (PM) gravimetric limits, is programmed with multiple maps. This study investigated the correlation between SCR-out/engine-out PM emissions from an 11-liter Volvo engine. Measurement of PM concentrations and size distributions were conducted under steady state and transient cycles. Ion Chromatograph analysis on gravimetric filters at the SCR-out has revealed the presence of sulfates. Two different PM size-distributions were generated over a single engine test mode in the accumulation mode region with the aid of a design of experiment (DOE) tool. The SCR-out PM size distributions were found to correlate with the two engine-out distributions.

For engine operations involving low load conditions for an extended amount of time, the exhaust temperature may be lower than that necessary to initiate the urea hydrolyzation. This would necessitate that the controller interrupt the urea supply to prevent catalyst fouling by products of ammonia decomposition. Therefore, it is necessary for the engine controller to have multiple calibrations available in regions of engine operation where the aftertreatment does not perform well, so that optimal exhaust conditions are guaranteed during the wide variety of engine operations. In this study the test engine was equipped with a catalyzed diesel particulate filter (DPF) and a selective catalytic reduction system (SCR), and programmed with two different engine calibrations, namely the low-NOx and the low fuel consumption (low-FC).

Dual primary full-flow dilution tunnels represent an integral part of a heavy-duty transportable emissions measurement laboratory designed and constructed to comply with US Code of Federal Regulations (CFR) 40 Part 1065 requirements. Few data exist to characterize the evolution of particulate matter (PM) in full scale dilution tunnels, particularly at very low PM mass levels. Size distributions of ultra-fine particles in diesel exhaust from a naturally aspirated, 2.4 liter, 40 kW ISUZU C240 diesel engine equipped with a diesel particulate filter (DPF) were studied in one set of standard primary and secondary dilution tunnels with varied dilution ratios. Particle size distribution data, during steady-state engine operation, were collected using a Cambustion DMS500 Fast Particulate Spectrometer. Measurements were made at four positions that spanned the tunnel cross section after the mixing orifice plate for the primary dilution tunnel and at the outlet of the secondary dilution tunnel.

West Virginia University (WVU) is a participant in EcoCAR - The NeXt Challenge, an Advanced Vehicle Technology Competition sponsored by the U.S. Department of Energy, and General Motors Corporation. During the first year of the competition, the goal of the WVU EcoEvolution Team was to design a novel hybrid-electric powertrain for a 2009 Saturn Vue to increase pump-to-wheels fuel economy, reduce criteria tailpipe emissions and well-to-wheels greenhouse gas emissions (GHG) while maintaining or improving performance and utility. To this end, WVU designed a 2-Mode split-parallel diesel-electric hybrid system. Key elements of the hybrid powertrain include a General Motors 1.3L SDE Turbo Diesel engine, a General Motors Corporation 2-Mode electrically variable transmission (EVT) and an A123 Systems Lithium-Ion battery system. The engine will be fueled on a blend of 20% soy-derived biodiesel and 80% petroleum-derived ultra-low sulfur diesel fuel (B20).

Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

Emissions from 10 refuse trucks equipped with Caterpillar C-10 engines were measured on West Virginia University's (WVU) Transportable Emissions Laboratory in Riverside, California. The engines all used a commercially available Dual-Fuel™ natural gas (DFNG) system supplied by Clean Air Partners Inc. (CAP), and some were also equipped with catalyzed particulate filters (CPFs), also from CAP. The DFNG system introduces natural gas with the intake air and then ignites the gas with a small injection of diesel fuel directly into the cylinder to initiate combustion. Emissions were measured over a modified version of a test cycle (the William H. Martin cycle) previously developed by WVU. The cycle attempts to duplicate a typical curbside refuse collection truck and includes three modes: highway-to-landfill delivery, curbside collection, and compaction. Emissions were compared to similar trucks that used Caterpillar C-10 diesels equipped with Engelhard's DPX catalyzed particulate filters.

Selective Catalytic Reduction (SCR), using urea injection, is being examined as a method for substantial reduction of oxides of nitrogen (NOx) for diesel engines, but the urea injection rates must be controlled to match the NOx production which may need to be predicted during open loop control. Unfortunately NOx is usually measured in the laboratory using a full-scale dilution tunnel and chemiluminescent analyzer, which cause delay and diffusion (in time) of the true manifold NOx concentration. Similarly, delay and diffusion of measurements of all emissions cause the task of creating instantaneous emissions models for vehicle simulations more difficult. Data were obtained to relate injections of carbon dioxide (CO2) into a tunnel with analyzer measurements. The analyzer response was found to match a gamma distribution of the input pulse, so that the analyzer output could be modeled from the tunnel CO2 input.

A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

West Virginia University redesigned a 2002 Ford Explorer and created a diesel electric hybrid vehicle to satisfy the goals of the 2002 FutureTruck competition. These goals were to demonstrate a 25% improvement in fuel economy, to reduce greenhouse gas emissions, to achieve California ULEV emissions, to demonstrate 1/8-mile acceleration of 11.5 seconds or less, and to maintain vehicular comforts and performance. West Virginia University's 2002 hybrid sport utility vehicle (SUV), the Exclaim!, meets or exceeds these goals. Using a post-transmission parallel configuration, WVU integrated a 2.5L Detroit Diesel Corporation engine along with a Unique Mobility 75kW electric motor to replace the stock drivetrain. With an emphasis on maintaining performance, WVU strived to improve areas where SUVs have traditionally performed poorly: fuel economy and emissions. Using regenerative braking, fuel economy has been significantly improved.

Diesel Particulate Filters (DPFs) are well assessed exhaust aftertreatment devices currently equipping almost every modern diesel engine to comply with the most stringent emission standards. However, an accurate estimation of soot content (loading) is critical to managing the regeneration of DPFs in order to attain optimal behavior of the whole engine-after-treatment assembly, and minimize fuel consumption. Real-time models can be used to address challenges posed by advanced control systems, such as the integration of the DPF with the engine or other critical aftertreatment components or to develop model-based OBD sensors. One of the major hurdles in such applications is the accurate estimation of engine Particulate Matter (PM) emissions as a function of time. Such data would be required as input data for any kind of accurate models. The most accurate way consists of employing soot sensors to gather the real transient soot emissions signal, which will serve as an input to the model.

In order to comply with stringent 2010 US-Environmental Protection Agency (EPA) on-road, Heavy-Duty Diesel (HDD) emissions regulations, the Selective Catalytic Reduction (SCR) aftertreatment system has been judged by a multitude of engine manufacturers as the primary technology for mitigating emissions of oxides of nitrogen (NOx). As virtually stand-alone aftertreatment systems, SCR technology further represents a very flexible and efficient solution for retrofitting legacy diesel engines as the most straightforward means of cost-effective compliance attainment. However, the addition of a reducing agent injection system as well as the inherent operation limitations of the SCR system due to required catalyst bed temperatures introduce new, unique problems, most notably that of ammonia (NH₃) slip.

Diesel particulate filters (DPFs) are recognized as the most efficient technology for particulate matter (PM) reduction, with filtration efficiencies in excess of 90%. Design guidelines for DPFs typically are: high removal efficiency, low pressure drop, high durability and capacity to resist high temperature excursions during regeneration events. The collected mass inside the trap needs to be periodically oxidized to regenerate the DPF. Thus, an in-depth understanding of filtration and regeneration mechanisms, together with the ability of predicting actual DPF conditions, could play a key role in optimizing the duration and number of regeneration events in case of active DPFs. Thus, the correct estimation of soot loading during operation is imperative for effectively controlling the whole engine-DPF assembly and simultaneously avoidingany system failure due to a malfunctioning DPF. A viable way to solve this problem is to use DPF models.

The study was aimed at assessing in-use emissions of a USEPA 2010 emissions-compliant heavy-duty diesel vehicle powered by a model year (MY) 2011 engine using West Virginia University's Transportable Emissions Measurement System (TEMS). The TEMS houses full-scale CVS dilution tunnel and laboratory-grade emissions measurement systems, which are compliant with the Code of Federal Regulation (CFR), Title 40, Part 1065 [1] emissions measurement specifications. One of the specific objectives of the study, and the key topic of this paper, is the quantification of greenhouse gas (GHG) emissions (CO2, N2O and CH4) along with ammonia (NH3) and regulated emissions during real-world operation of a long-haul heavy-duty vehicle, equipped with a diesel particulate filter (DPF) and urea based selective catalytic reduction (SCR) aftertreatment system for PM and NOx reduction, respectively.

Stringent emission regulations have forced drastic technological improvements in diesel after treatment systems, particularly in reducing Particulate Matter (PM) emissions. Those improvements generally regard the use of Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF) and lately also the use of Selective Catalyst Reduction (SCR) systems along with improved engine control strategies for reduction of NOx emissions from these engines. Studies that have led to these technological advancements were made in controlled laboratory environment and are not representative of real world emissions from these engines or vehicles. In addition, formation and evolution of PM from these engines are extremely sensitive to overall changes in the dilution process.

With continuously increasing concern for the emissions from two-stroke engines including regulated hydrocarbon (HC) and oxides of nitrogen (NOx) emissions, non-road engines are implementing proven technologies from the on-road market. For example, four stroke diesel generators now include additional internal exhaust gas recirculation (EGR) via an intake/exhaust valve passage. EGR can offer benefits of reduced HC, NOx, and may even improve combustion stability and fuel efficiency. In addition, there is particular interest in use of natural gas as fuel for home power generation. This paper examines exhaust throttling applied to the Helmholtz resonator of a two-stroke, port injected, natural gas engine. The 34 cc engine was air cooled and operated at wide-open throttle (WOT) conditions at an engine speed of 5400 RPM with fueling adjusted to achieve maximum brake torque. Exhaust throttling served as a method to decrease the effective diameter of the outlet of the convergent cone.

Regulated gaseous and particulate emissions were obtained from in-use vehicles, two trucks and two buses, operated on the Transportable Heavy Duty Engine Emissions Testing Laboratory. Presented here is the data on transient emissions from a refuse truck with a Cummins LTA10-260 engine, a GMC tractor with a CAT 3176 engine and two buses with Detroit Diesel 6V-92TA engines (one with a particulate trap and the other without) when tested on different fuels. The reported study on in-use heavy duty vehicles is part of an on-going program aimed at establishing a database on the exhaust emissions from vehicles tested on a chassis dynamometer under conditions that represent the ‘real-world’ situations. The paper also discusses, briefly, the entire testing laboratory. The Transportable Laboratory can be effectively used in testing programs, such as recall, deterioration and emission factors.

Increasingly stringent oxides of nitrogen (NOx) and particulate matter (PM) regulations worldwide have prompted considerable activity in developing emission control technology to reduce the emissions of these two constituents from heavy-duty diesel engines. NOx has come under particular scrutiny by regulators in the US and in Europe with the promulgation of very stringent regulation by both the US Environmental Protection Agency (EPA) and the European Union (EU). In response, heavy-duty engine manufacturers are considering Selective Catalytic Reduction (SCR) as a potential NOx reduction option. While SCR performance has been well established through engine dynamometer evaluation under laboratory conditions, there exists little data characterizing SCR performance under real-world operating conditions over time. This project evaluated the field performance of ten SCR units installed on heavy-duty Class 8 highway and refuse trucks.

A fleet of six 2001 International Class 6 trucks operating in southern California was selected for an operability and emissions study using gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (CDPF). Three vehicles were fueled with CARB specification diesel fuel and no emission control devices (current technology), and three vehicles were fueled with GTL fuel and retrofit with Johnson Matthey's CCRT™ diesel particulate filter. No engine modifications were made. Bench scale fuel-engine compatibility testing showed the GTL fuel had cold flow properties suitable for year-round use in southern California and was additized to meet current lubricity standards. Bench scale elastomer compatibility testing returned results similar to those of CARB specification diesel fuel. The GTL fuel met or exceeded ASTM D975 fuel properties. Researchers used a chassis dynamometer to test emissions over the City Suburban Heavy Vehicle Route (CSHVR) and New York City Bus (NYCB) cycles.

Specific aspects of a study aimed at developing a microwave assisted regeneration system for diesel particulate traps are discussed. Results from thermal and microwave characteristic studies carried out in the initial phase of the study are reported. The critical parameters that need to be optimized, for achieving controlled regeneration, are microwave preheating time period, regenerative air supply, regenerative air temperature, and soot deposition. Using a 1000 W magnetron, power measurements were made to select the best waveguide configuration for optimized transmission. A six cylinder naturally aspirated, indirect injection diesel engine was retrofitted with a customized exhaust system that included a Corning EX80 (5.66″ × 6.00″) type ceramic particulate trap. An automated exhaust bypass system enabled trap loading and subsequent regeneration with a customized microwave regeneration system. The paper discusses the salient details of both on-line and off-line regeneration setups.