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Three-way catalyst equipped stoichiometric natural gas vehicles have proven to be an effective alternative fuel strategy that has shown superior low NOx benefits in comparison to diesels equipped with SCR. However, recent studies have shown the TWC activity to contribute to high levels of tailpipe ammonia emissions. Although a non-regulated pollutant, ammonia is a potent pre-cursor to ambient secondary PM formation. Ammonia (NH3) is an inevitable catalytic byproduct of TWCduring that results also corresponds to lowest NOx emissions. The main objective of the study is to develop a passive SCR based NH3 reduction strategy that results in an overall reduction of NH3 as well as NOx emissions from a stoichiometric spark ignited natural gas engine. The study investigated the characteristics of Fe-based and Cu-based zeolite SCR catalysts in storage, and desorption of ammonia at high exhaust temperature conditions, that are typical of stoichiometric natural gas engines.

In-service 1994-2003 heavy-duty trucks were acquired by West Virginia University (WVU), equipped with the WVU Mobile Emissions Measurement System (MEMS) to measure on-road NOx, and driven on road routes near Sabraton, West Virginia, and extending up to Washington, PA to obtain real-world oxides of nitrogen (NOx) emissions data on highways and local roads. The MEMS measured 5Hz NOx, and load was obtained from the electronic control unit. Trucks were loaded to about 95% of their gross vehicle weights. Emissions in g/mi and g/bhp-hr were computed over the various road routes. In addition, some of the trucks were tested 1 to 2 years later to determine emission changes that may have occurred for these trucks. Emission results varied significantly over the different road routes due to different speeds, driving patterns, and road grades.

A work-based window method has been developed to calculate in-use brake-specific oxides of nitrogen (NOx) emissions for all engine speeds and engine loads. During an in-use test, engine speed and engine torque are read from the engine's electronic control unit, and along with time, are used to determine instantaneous engine power. Instantaneous work is calculated using this power and the time differential in the data collection. Work is then summed until the target amount of work is accumulated. The emissions levels are then calculated for that window of work. It was determined that a work window equal to the theoretical Federal Test Procedure (FTP) cycle work best provides a means of comparison to the FTP certification standard. Also, a failure criterion has been established based on the average amount of power generated in the work window and the amount of time required to achieve the target work window to determine if a particular work window is valid.

As part of the 1998 Consent Decrees concerning alternative ignition strategies between the six settling heavy-duty diesel engine manufacturers and the United States government, the engine manufacturers agreed to perform in-use emissions measurements of their engines. As part of the Consent Decrees, pre- (Phase III, pre-2000 engines) and post- (Phase IV, 2001 to 2003 engines) Consent Decree engines used in over-the-road vehicles were tested to examine the emissions of oxides of nitrogen (NOx) and carbon dioxide (CO2). A summary of the emissions of NOx and CO2 and fuel consumption from the Phase III and Phase IV engines are presented for 30 second “Not-to-Exceed” (NTE) window brake-specific values. There were approximately 700 Phase III tests and 850 Phase IV tests evaluated in this study, incorporating over 170 different heavy duty diesel engines spanning 1994 to 2003 model years. Test vehicles were operated over city, suburban, and highway routes.

Pollutants are a major issue of diesel engines, with oxides of nitrogen (NOx) and airborne total particulate matter (TPM) of primary concern. Current emission standards rely on laboratory testing using an engine dynamometer with a standard test procedure. Results are reported as an integrated value for emissions from a transient set of engine speed and load conditions over a length of time or a set of prescribed speed-load points. To be considered a valid test by the US EPA, the measured engine speed and load are compared to the prescribed engine speed and load and must be within prescribed regression limits.

Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.

Biodiesel fuels benefit both from being a renewable energy source and from decreasing in carbon monoxide (CO), total hydrocarbons (THC), and particulate matter (PM) emissions relative to petroleum diesel. The oxides of nitrogen (NOx) emissions from biodiesel blended fuels reported in the literature vary relative to baseline diesel NOx, with no NOx change or a NOx decrease found by some to an increase in NOx found by others. To explore differences in NOx, two Cummins ISM engines (1999 and 2004) were operated on 20% biodiesel blends during the heavy-duty transient FTP cycle and the steady state Supplemental Emissions Test. For the 2004 Cummins ISM engine, in-cylinder pressure data were collected during the steady state and transient tests. Three types of biodiesel fuels were used in the blends: soy, tallow (animal fat), and cottonseed. The FTP integrated emissions of the B20 blends produced a 20-35% reduction in PM and no change or up to a 4.3% increase in NOx over the neat diesel.

New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these vehicles was for street collection and transporting the collected refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines.

For engine operations involving low load conditions for an extended amount of time, the exhaust temperature may be lower than that necessary to initiate the urea hydrolyzation. This would necessitate that the controller interrupt the urea supply to prevent catalyst fouling by products of ammonia decomposition. Therefore, it is necessary for the engine controller to have multiple calibrations available in regions of engine operation where the aftertreatment does not perform well, so that optimal exhaust conditions are guaranteed during the wide variety of engine operations. In this study the test engine was equipped with a catalyzed diesel particulate filter (DPF) and a selective catalytic reduction system (SCR), and programmed with two different engine calibrations, namely the low-NOx and the low fuel consumption (low-FC).

Emissions from 10 refuse trucks equipped with Caterpillar C-10 engines were measured on West Virginia University's (WVU) Transportable Emissions Laboratory in Riverside, California. The engines all used a commercially available Dual-Fuel™ natural gas (DFNG) system supplied by Clean Air Partners Inc. (CAP), and some were also equipped with catalyzed particulate filters (CPFs), also from CAP. The DFNG system introduces natural gas with the intake air and then ignites the gas with a small injection of diesel fuel directly into the cylinder to initiate combustion. Emissions were measured over a modified version of a test cycle (the William H. Martin cycle) previously developed by WVU. The cycle attempts to duplicate a typical curbside refuse collection truck and includes three modes: highway-to-landfill delivery, curbside collection, and compaction. Emissions were compared to similar trucks that used Caterpillar C-10 diesels equipped with Engelhard's DPX catalyzed particulate filters.

A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

Cummins Westport Inc. (CWI) released for production the latest version of its C8.3G natural gas engine, the C Gas Plus, in July 2001. This engine has increased ratings for horsepower and torque, a full-authority engine controller, wide tolerance to natural gas fuel (the minimum methane number is 65), and improved diagnostics capability. The C Gas Plus also meets the California Air Resources Board optional low-NOx (2.0 g/bhp-h) emission standard for automotive and urban buses. Two pre-production C Gas Plus engines were operated in a Viking Freight fleet for 12 months as part of the U.S. Department of Energy's Fuels Utilization Program. In-use exhaust emissions, fuel economy, and fuel cost were collected and compared with similar 1997 Cummins C8.3 diesel tractors. CWI and the West Virginia University developed an ad-hoc test cycle to simulate the Viking Freight fleet duty cycle from in-service data collected with data loggers.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

Reactivity controlled compression ignition (RCCI) is a form of dual-fuel combustion that exploits the reactivity difference between two fuels to control combustion phasing. This combustion approach limits the formation of oxides of nitrogen (NOX) and soot while retaining high thermal efficiency. The research presented herein was performed to determine the influences that high reactivity (diesel) fuel properties have on RCCI combustion characteristics, exhaust emissions, fuel efficiency, and the operable load range. A 4-cylinder, 1.9 liter, light-duty compression-ignition (CI) engine was converted to run on diesel fuel (high reactivity fuel) and compressed natural gas (CNG) (low reactivity fuel). The engine was operated at 2100 revolutions per minute (RPM), and at two different loads, 3.6 bar brake mean effective pressure (BMEP) and 6 bar BMEP.

With continuously increasing concern for the emissions from two-stroke engines including regulated hydrocarbon (HC) and oxides of nitrogen (NOx) emissions, non-road engines are implementing proven technologies from the on-road market. For example, four stroke diesel generators now include additional internal exhaust gas recirculation (EGR) via an intake/exhaust valve passage. EGR can offer benefits of reduced HC, NOx, and may even improve combustion stability and fuel efficiency. In addition, there is particular interest in use of natural gas as fuel for home power generation. This paper examines exhaust throttling applied to the Helmholtz resonator of a two-stroke, port injected, natural gas engine. The 34 cc engine was air cooled and operated at wide-open throttle (WOT) conditions at an engine speed of 5400 RPM with fueling adjusted to achieve maximum brake torque. Exhaust throttling served as a method to decrease the effective diameter of the outlet of the convergent cone.

Both field research and certification data show that the lean burn natural gas powered spark ignition engines offer particulate matter (PM) reduction with respect to equivalent diesel power plants. Concerns over PM inventory make these engines attractive despite the loss of fuel economy associated with throttled operation. Early versions of the Cummins L-10 natural gas engines employed a mixer to establish air/fuel ratio. Emissions measurements by the West Virginia University Transportable Heavy Duty Emissions Testing Laboratories on Cummins L-10 powered transit buses revealed the potential to offer low emissions of PM and oxides of nitrogen, (NOx) but variations in the mixture could cause emissions of NOx, carbon monoxide and hydrocarbons to rise. This was readily corrected through mixer repair or readjustment. Newer versions of the L-10 engine employ a more sophisticated fueling scheme with feedback control from a wide range oxygen sensor.

A Saturn 1.9 liter engine has been converted for operation on either compressed natural gas or gasoline. A bi-fuel controller (BFC) that uses closed-loop control methods for both fuel delivery and spark advance has been developed. The performance and emissions during operation on each fuel have been investigated with the BFC, as well as the performance and emissions with the stock original equipment manufacturer (OEM) controller using gasoline. In-cylinder pressure was measured at a rate of 1024 points per revolution with piezoelectric pressure transducers flush-mounted in the cylinder head. The in-cylinder pressure was used in real time for ignition timing control purposes, and was stored by a data acquisition system for the investigation of engine stability and differences in the combustion properties of the fuels.

Six 2001 International Class 6 trucks participated in a project to determine the impact of gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (DPFs) on emissions and operations from December 2003 through August 2004. The vehicles operated in Southern California and were nominally identical. Three vehicles operated “as-is” on California Air Resources Board (CARB) specification diesel fuel and no emission control devices. Three vehicles were retrofit with Johnson Matthey CCRT® (Catalyzed Continuously Regenerating Technology) filters and fueled with Shell GTL Fuel. Two rounds of emissions tests were conducted on a chassis dynamometer over the City Suburban Heavy Vehicle Route (CSHVR) and the New York City Bus (NYCB) cycle. The CARB-fueled vehicles served as the baseline, while the GTL-fueled vehicles were tested with and without the CCRT filters. Results from the first round of testing have been reported previously (see 2004-01-2959).

Increasingly stringent oxides of nitrogen (NOx) and particulate matter (PM) regulations worldwide have prompted considerable activity in developing emission control technology to reduce the emissions of these two constituents from heavy-duty diesel engines. NOx has come under particular scrutiny by regulators in the US and in Europe with the promulgation of very stringent regulation by both the US Environmental Protection Agency (EPA) and the European Union (EU). In response, heavy-duty engine manufacturers are considering Selective Catalytic Reduction (SCR) as a potential NOx reduction option. While SCR performance has been well established through engine dynamometer evaluation under laboratory conditions, there exists little data characterizing SCR performance under real-world operating conditions over time. This project evaluated the field performance of ten SCR units installed on heavy-duty Class 8 highway and refuse trucks.

A fleet of six 2001 International Class 6 trucks operating in southern California was selected for an operability and emissions study using gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (CDPF). Three vehicles were fueled with CARB specification diesel fuel and no emission control devices (current technology), and three vehicles were fueled with GTL fuel and retrofit with Johnson Matthey's CCRT™ diesel particulate filter. No engine modifications were made. Bench scale fuel-engine compatibility testing showed the GTL fuel had cold flow properties suitable for year-round use in southern California and was additized to meet current lubricity standards. Bench scale elastomer compatibility testing returned results similar to those of CARB specification diesel fuel. The GTL fuel met or exceeded ASTM D975 fuel properties. Researchers used a chassis dynamometer to test emissions over the City Suburban Heavy Vehicle Route (CSHVR) and New York City Bus (NYCB) cycles.