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Three-way catalyst equipped stoichiometric natural gas vehicles have proven to be an effective alternative fuel strategy that has shown superior low NOx benefits in comparison to diesels equipped with SCR. However, recent studies have shown the TWC activity to contribute to high levels of tailpipe ammonia emissions. Although a non-regulated pollutant, ammonia is a potent pre-cursor to ambient secondary PM formation. Ammonia (NH3) is an inevitable catalytic byproduct of TWCduring that results also corresponds to lowest NOx emissions. The main objective of the study is to develop a passive SCR based NH3 reduction strategy that results in an overall reduction of NH3 as well as NOx emissions from a stoichiometric spark ignited natural gas engine. The study investigated the characteristics of Fe-based and Cu-based zeolite SCR catalysts in storage, and desorption of ammonia at high exhaust temperature conditions, that are typical of stoichiometric natural gas engines.

This paper discusses the design and qualification of a High Temperature Sampling System (HTSS), capable of stripping the volatile fraction from a sample flow stream in order to provide for quantification of total, solid and volatile particulate matter (PM) on a near real-time basis. The sampling system, which incorporates a heated diesel oxidation catalyst, is designed for temperatures up to 450°C. The design accounts for molecular diffusion of volatile compounds, solid particles diffusion and reaction kinetics inside one channel of the oxidation catalyst. An overall solid particle loss study in the sampling was performed, and numerical results were compared with experimental data gathered at the West Virginia University Engine and Emissions Research Laboratory (EERL) and West Virginia University's Transportable Heavy-Duty Vehicle Emissions Testing Laboratory (THDVETL).

Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.

As a part of the 1996 FutureCar Challenge competition, West Virginia University converted a 1996 Chevrolet Lumina to a series hybrid electric vehicle. This technical report summarizes the modifications made to the vehicle during 1997, the second year of the competition, and details the present state of development of this second-generation hybrid electric vehicle. In particular, the vehicle's powertrain configuration, component selection, control strategy for all modes of operation, emissions control strategies, vehicle structure and design modifications, and suspension design and modifications are all detailed. Also discussed, are the operational use of this vehicle and its intended market. The projected performance of the vehicle, obtained from computer simulations, is discussed in the light of results obtained from testing during 1996 and 1997.

Until a proper fueling infrastructure is established, vehicles powered by natural gas must have bi-fuel capability in order to avoid a limited vehicle range. Although bi-fuel conversions of existing gasoline engines have existed for a number of years, these engines do not fully exploit the combustion and knock properties of both fuels. Much of the power loss resulting from operation of an existing gasoline engine on compressed natural gas (CNG) can be recovered by increasing the compression ratio, thereby exploiting the high knock resistance of natural gas. However, gasoline operation at elevated compression ratios results in severe engine knock. The use of variable intake valve timing in conjunction with ignition timing modulation and electronically controlled exhaust gas recirculation (EGR) was investigated as a means of controlling knock when operating a bi-fuel engine on gasoline at elevated compression ratios.

Dedicated natural gas engines suffer the disadvantages of limited vehicle range and relatively few refueling stations. A vehicle capable of operating on either gasoline or natural gas allows alternative fuel usage without sacrificing vehicle range and mobility. However, the bi-fuel engine must be made to provide equal performance on both fuels. Although bi-fuel conversions have existed for a number of years, historically natural gas performance is degraded relative to gasoline due to reduced volumetric efficiency and lower power density of CNG. Much of the performance losses associated with CNG can be overcome by increasing the compression ratio. However, in a bi-fuel application, high compression ratios can result in severe engine knock during gasoline operation. Variable intake valve timing, increased exhaust gas recirculation and retarded ignition timing were explored as a means of controlling knock during gasoline operation of a bi-fuel engine.

New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these vehicles was for street collection and transporting the collected refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines.

Reduced emissions, improved fuel economy, and improved performance are a priority for manufacturers of internal combustion engines. However, these three goals are normally interrelated and difficult to optimize simultaneously. Studying the experimental heat release provides a useful tool for combustion optimization. Heavy-duty diesel engines are inherently transient, even during steady state operation engine controls can vary due to exhaust gas recirculation (EGR) or aftertreatment requirements. This paper examines the heat release and the derived combustion characteristics during steady state and transient operation for a 1992 DDC series 60 engine and a 2004 Cummins ISM 370 engine. In-cylinder pressure was collected during repeat steady state SET and the heavy-duty transient FTP test cycles.

West Virginia University evaluated diesel oxidation catalysts (DOC) and lean-NOX catalysts as part of Diesel Emissions Control-Sulfur Effects (DECSE) project. In order to perform thermal aging of the DOC and lean-NOX catalysts simultaneously and economically, each catalyst was sized to accommodate half of the engine exhaust flow. Simultaneous catalyst aging was then achieved by splitting the engine exhaust into two streams such that approximately half of the total exhaust flowed through the DOC and half through the lean-NOX catalyst. This necessitated splitting the engine exhaust into two streams during emissions measurements. Throttling valves installed in each branch of the split exhaust were adjusted so that approximately half the engine exhaust passed though the active catalyst under evaluation and into a full flow dilution tunnel for emissions measurement.

The aim of this investigation was to improve understanding and quantify the impact of exhaust gas recirculation (EGR) as an emissions control measure onto cyclic variability of a small-bore, single-cylinder, diesel-fueled compression-ignition (CI) power generation unit. Of special interest were how cycle-to-cycle variations of the CI engine affect steady-state voltage deviations and frequency bandwidths. Furthermore, the study strived to elucidate the impact of EGR addition onto combustion parameters, as well as gaseous and particle phase emissions along with fuel consumption. The power generation unit was operated over five discrete steady-state test modes, representative of nominal 0, 25, 50, 75, and 100% engine load (i.e. 0-484kPa BMEP), by absorbing electrical power via a resistive load bank. The engine was equipped with a passive EGR system that directly connected the exhaust and intake runners through a small passage.

With continuously increasing concern for the emissions from two-stroke engines including regulated hydrocarbon (HC) and oxides of nitrogen (NOx) emissions, non-road engines are implementing proven technologies from the on-road market. For example, four stroke diesel generators now include additional internal exhaust gas recirculation (EGR) via an intake/exhaust valve passage. EGR can offer benefits of reduced HC, NOx, and may even improve combustion stability and fuel efficiency. In addition, there is particular interest in use of natural gas as fuel for home power generation. This paper examines exhaust throttling applied to the Helmholtz resonator of a two-stroke, port injected, natural gas engine. The 34 cc engine was air cooled and operated at wide-open throttle (WOT) conditions at an engine speed of 5400 RPM with fueling adjusted to achieve maximum brake torque. Exhaust throttling served as a method to decrease the effective diameter of the outlet of the convergent cone.

Among the key technologies currently being used for reducing emissions of oxides of nitrogen, Exhaust Gas Recirculation (EGR) has been found to be very effective for light duty diesel engines. However, EGR results in a sharp increase in particulate matter emissions in heavy-duty diesel engines. The presence of increased levels of particulate matter in the engine has led to increased wear of engine parts such as cylinder liners, piston rings, valve train system and bearings. A statistically designed experiment was developed to examine the effects of soot contaminated engine oil on wear of engine components. A three-body wear machine was designed and developed to simulate and estimate the extent of wear. The three oil properties studied were phosphorous level, dispersant level and sulfonate substrate level. The above three variables were formulated at two levels: High (1) and Low (-1). This resulted in a 23 matrix (8 oil blends).

Lean-burn natural gas engines offer attractively low particulate matter emissions and enjoy higher efficiencies than their stoichiometric counterparts. However, even though oxides of nitrogen emissions can be reduced through operation at lambda ratios of greater than 1.3, catalysts cannot reduce the oxides of nitrogen emissions in the oxidizing exhaust environment. Exhaust Gas Recirculation (EGR) offers the potential to reduce engine out oxides of nitrogen emissions by reducing the flame temperature and oxygen partial pressure that encourages their formation during the combustion process. A comparative study involving a change in the nature of primary diluent (air replaced by EGR) in the intake of a Hercules, 3.7 liter, lean-burn natural gas engine has been undertaken in this research. The Hercules engine was equipped with a General Motors electronically controlled EGR valve for low EGR rates, and a slide valve, constructed in house, for high EGR rates.

Six 2001 International Class 6 trucks participated in a project to determine the impact of gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (DPFs) on emissions and operations from December 2003 through August 2004. The vehicles operated in Southern California and were nominally identical. Three vehicles operated “as-is” on California Air Resources Board (CARB) specification diesel fuel and no emission control devices. Three vehicles were retrofit with Johnson Matthey CCRT® (Catalyzed Continuously Regenerating Technology) filters and fueled with Shell GTL Fuel. Two rounds of emissions tests were conducted on a chassis dynamometer over the City Suburban Heavy Vehicle Route (CSHVR) and the New York City Bus (NYCB) cycle. The CARB-fueled vehicles served as the baseline, while the GTL-fueled vehicles were tested with and without the CCRT filters. Results from the first round of testing have been reported previously (see 2004-01-2959).

Increasingly stringent oxides of nitrogen (NOx) and particulate matter (PM) regulations worldwide have prompted considerable activity in developing emission control technology to reduce the emissions of these two constituents from heavy-duty diesel engines. NOx has come under particular scrutiny by regulators in the US and in Europe with the promulgation of very stringent regulation by both the US Environmental Protection Agency (EPA) and the European Union (EU). In response, heavy-duty engine manufacturers are considering Selective Catalytic Reduction (SCR) as a potential NOx reduction option. While SCR performance has been well established through engine dynamometer evaluation under laboratory conditions, there exists little data characterizing SCR performance under real-world operating conditions over time. This project evaluated the field performance of ten SCR units installed on heavy-duty Class 8 highway and refuse trucks.

A fleet of six 2001 International Class 6 trucks operating in southern California was selected for an operability and emissions study using gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (CDPF). Three vehicles were fueled with CARB specification diesel fuel and no emission control devices (current technology), and three vehicles were fueled with GTL fuel and retrofit with Johnson Matthey's CCRT™ diesel particulate filter. No engine modifications were made. Bench scale fuel-engine compatibility testing showed the GTL fuel had cold flow properties suitable for year-round use in southern California and was additized to meet current lubricity standards. Bench scale elastomer compatibility testing returned results similar to those of CARB specification diesel fuel. The GTL fuel met or exceeded ASTM D975 fuel properties. Researchers used a chassis dynamometer to test emissions over the City Suburban Heavy Vehicle Route (CSHVR) and New York City Bus (NYCB) cycles.

Due to tightening emission legislations, both within the US and Europe, including concerns regarding greenhouse gases, next-generation combustion strategies for internal combustion diesel engines that simultaneously reduce exhaust emissions while improving thermal efficiency have drawn increasing attention during recent years. In-cylinder combustion temperature plays a critical role in the formation of pollutants as well as in thermal efficiency of the propulsion system. One way to minimize both soot and NOx emissions is to limit the in-cylinder temperature during the combustion process by means of high levels of dilution via exhaust gas recirculation (EGR) combined with flexible fuel injection strategies. However, fuel chemistry plays a significant role in the ignition delay; hence, influencing the overall combustion characteristics and the resulting emissions.

Heavy-duty diesel (HDD) engines are the primary propulsion source for most heavy-duty vehicle freight movement and have been equipped with an array of aftertreatment devices to comply with more stringent emissions regulations. In light of concerns about the transportation sector's influence on climate change, legislators are introducing requirements calling for significant reductions in fuel consumption and thereby, greenhouse gas (GHG) emission over the coming decades. Advanced engine concepts and technologies will be needed to boost engine efficiencies. However, increasing the engine's efficiency may result in a reduction in thermal energy of the exhaust gas, thus contributing to lower exhaust temperature, potentially affecting aftertreatment activity, and consequently rate of regulated pollutants. This study investigates the possible utilization of waste heat recovered from a HDD engine as a means to offset fuel penalty incurred during thermal management of SCR system.

Most transient heavy duty diesel emissions data in the USA have been acquired using the Federal Test Procedure (FTP), a heavy-duty diesel engine transient test schedule described in the US Code of Federal Regulations. The FTP includes both urban and freeway operation and does not provide data separated by driving mode (such as rural, urban, freeway). Recently, a four-mode engine test schedule was created for use in the Advanced Collaborative Emission Study (ACES), and was demonstrated on a 2004 engine equipped with cooled Exhaust Gas Recirculation (EGR). In the present work, the authors examined emissions using these ACES modes (Creep, Cruise, Transient and High-speed Cruise) and the FTP from a Detroit Diesel Corporation (DDC) Series 60 1992 12.7 liter pre-EGR engine. The engine emissions were measured using full exhaust dilution, continuous measurement of gaseous species, and filter-based Particulate Matter (PM) measurement.