Search Results

Four of these Particulate Reduction Systems (PMS) were tested on a passenger car and one of them on a HDV. Expectation of the research team was that they would reach at least a PM-reduction of 30% under all realistic operating conditions. The standard German filter test procedure for PMS was performed but moreover, the response to various operating conditions was tested including worst case situations. Besides the legislated CO, NOx and PM exhaust-gas emissions, also the particle count and NO2 were measured. The best filtration efficiency with one PMS was indeed 63%. However, under critical but realistic conditions filtration of 3 of 4 PMS was measured substantially lower than the expected 30 %, depending on operating conditions and prior history, and could even completely fail. Scatter between repeated cycles was very large and results were not reproducible. Even worse, with all 4 PMS deposited soot, stored in these systems during light load operation was intermittently blown-off.

Increasing concern, about the health risk due to solid aerosols from engine combustion, has provoked more stringent imission limits, for soot particles in the range of pulmonary intrusion, at critical work-places (e.g. tunnel sites, see Table 1). Within the scope of the joint European project VERT, these emissions were characterized and their effective curtailment through exhaust gas after-treatment investigated. Diesel engines, irrespective of design and operating point, emit solid particulates in the range of 100 nm, at concentrations above 10 million particulates per cm3. Engine tests showed that a drastic curtailment of pulmonary intruding particulates seems not feasible by further development of the engine combustion, nor by reformulation of fuels, nor by deployment of oxidation catalytic converters. Particulate traps, however, can curtail the total solid particulate count, in the fine particulate range 15-500 nm, by more than two orders of magnitude.

Diesel particle filters (DPFs) efficiently eliminate soot, fuel-, and oil-ash emissions of diesel engines, but little data are available with respect to long term aging or deterioration effects of DPFs under real world operating conditions. Aging of wash coat- and catalyst-materials, catalyst poisoning, ash sintering, adsorption and long lasting storage of semi- or non-volatile substances can take place, which over time may influence filtration and conversion properties of DPFs. Herein we report to what extent DPF aging may affect particle filtration characteristics. We compared particle number concentrations (PN), and particle mass (PM) emissions after a 2000 operating hours endurance test (VFT2). Such a controlled field test is required by VERT verification procedures, which lately were published as a national standard (SNR 277205).

The project objective was to investigate the ultrafine solid particle emissions of the prevalent traffic, by performing field measurements at an urban traffic artery in Zurich/Switzerland. Subsequently, various scenarios were postulated to assess the potential of the diesel particle filters (DPF) to improve curbside air quality. Soot aerosols are known to be carcinogenic [1]. If all heavy-duty diesel vehicles were equipped with DPFs, then the number of particles emitted from the entire vehicle fleet could be reduced by 75 to 80%. For PM10, the curtailment scope is considerably lower, around 20%, because more than half of those emissions are not from the exhaust and therefore would not be filtered.

New Diesel exhaust gas aftertreatment systems, with combined DPF*) and deNOx (mostly SCR) systems represent a very important step towards zero emission Diesel fleet. These combined systems are already offered today by several suppliers for retrofitting of HD vehicles. Reliable quality standards for those quite complex systems are urgently needed to enable decisions of several authorities. The present report informs about the international network project VERT *) dePN (de-activation, de-contamination, disposal of particles and NOx), which was started in Nov. 2006 with the objective to introduce the SCR-, or combined DPF+SCR-systems in the VERT verification procedure. Examples of results for some of the investigated systems are given. These investigations included parameters, which are important for the VERT quality testing: besides the regulated gaseous emissions several unregulated components such as NH3, NO2 and N2O were measured.

Swiss EPA and European occupational health authorities have sponsored the development of a new sampling and measuring system designed to fulfil future requirements of differentiated particle analysis in field use and for certification purposes. The system suppresses the formation of condensates by applying hot dilution. Solid carbonaceous particles are distinguished from ash particles by means of two different sensors. Particles are size classified by their mobility; their active surface is measured. The measurable size ranges from less than 10 nm to 1 micrometer. The detection limit corresponds to a mass concentration of elemental carbon (EC) of about 0.1 μg/m3. The time resolution of 1 second is suitable for on-line analysis of particulate emission during all types of transient cycles, even no-load acceleration. The system includes a compact diluter with tunable dilution factor from 30 to 3000.

Particulate traps are mechanical devices for trapping soot, ash and mineral particles, to curtail emissions from Diesel engines. The filtration effectiveness of traps can be defined, independent of the pertinent engine, as a function of the particle size, space velocity and operating temperature. This method of assessment lowers cost of certifying traps for large-scale retrofitting projects [1,2]. VERT [3] is a joint project of several European environmental and occupational health agencies. The project established a trap-verification protocol that adapts industrial filtration standards [4] to include the influence of soot burden and trap regeneration phenomena. Moreover, it verifies possible catalytic effects from coating substrates and deposited catalytic active material from engine wear or fuel/ lubricant additives.

By means of catalysts, either coatings or fuel-borne, the temperature level for triggering the combustion of soot stored in particulate traps can be lowered from 600°C to 300°C, in case of CRT even to 250°C; but even that may fail, if in dense traffic application of a city-bus only 150 - 200°C are attained - similar situations of low load duty cycles exist in most other applications too. Mere passive regeneration may then not be sufficient, active support is needed. This paper presents an “active” method applicable to any Diesel engine to increase the exhaust temperature whenever required: load of Diesel engines is controlled by the fuel flow only; consequently, excess of air above stochiometric requirement is increasing from λ = 1.5 to λ = 8 with decreasing load, which is in fact the principal cause of the low temperature at light loads.

Ceramic fibers with high specific surface area and adequate high-temperature strength are commercially available for filtration of diesel particulates and in-situ hot regeneration. The manufacturing of a deep bed filtration medium, using such brittle fibers, became possible after a special knitting technique was developed which forms the loops with minimum friction and pretension. Within this structure, the fibers are very little constrained and expose their active surface almost completely. Hence, high filtration efficiencies in the range of 95% could be demonstrated with favorable back-pressure characteristics. Blow-off phenomena were never observed. Endurance testing on engines, with full-flow burner regeneration, proved the high robustness to mechanical and thermo-mechanical loading. This is one of the particular advantages of the new concept.

Ceramic fibers, in a knitted structure, offer an elastic deep-filter medium having a very high specific surface. The robustness of this trap, and its invulnerability to thermo-shock, was demonstrated during a further year of development and tests. By using new manufacturing techniques, the filtration efficiency was further improved, pressure losses reduced, and the required volume diminished. New insight was obtained regarding the employment of the fiber medium for catalysis. The filter concept permits regeneration either electrically or by fuel-additives. The layout versatility facilitates deployment on vehicular and stationary engines, in the pre-turbo position, too.

Fine pored hot gas traps have filtration efficiencies exceeding 99% of the solid particles in the diesel exhaust gas. There is a favorable trend to deploy this technology ex-factory and retrofitting on-road and off-road engines. The trap system however functions as a chemical reactor. The filter has a large effective area and the engine exhaust gas has plenty of reactants, which can promote undesirable chemical reactions that release toxic secondary emissions. These effects may be amplified when traps have catalytic influence, e.g. due to surface coatings or fuel-borne catalysts. The VERT suitability tests for particle trap systems therefore include a detailed test procedure for verifying the presence of over 200 toxic substances. These include PAH, nitro-PAH, chlorinated dioxins, furans as well as metals. The paper describes test procedures, test reporting, sample extraction and analysis.

Metallic substances, usually added to fuel as organic compounds are, as fuel additives proven to curtail particulate emissions from diesel engines and, as fuel borne catalysts (FBC), to promote regeneration of particle traps. During combustion, these substances form catalytic metal oxides and exit the combustion chamber as ultra-fine solid clusters in the mobility diameter range of 5-30 nm. Particles of this size and composition have a health impact and should not enter the respiratory air. FBC should therefore only be used together with particle traps, which can efficiently collect these metal oxide particles at all operating conditions. This and other requirements are stipulated in the VERT suitability tests for particle trap systems. The approval procedure includes a particle size-specific analysis to verify trap penetration in trace quantities.

High levels of particulate emissions from Diesel engines, in tunnel construction sites, force the aftertreatment of exhaust gases with particulate traps. Sub-micron particulates are suspected to be carcinogenic. Hence, the size distribution of particulates was compared for different particulate trap systems. The two extreme types are the ceramic monolith surface filter and the typical deep-bed filter of knitted fiber. These two types have distinctly different properties. The gravimetric evaluation of both systems show comparable efficiencies around 90%. If, instead, the particle count is evaluated: the efficiency of the surface filter drops below 70%, whereas that of the deep-bed filter increases. The spectral analysis of distinct solid particulates shows that the efficiency of the surface filter deteriorates for particles smaller than 100 nm. The toxicological consequences are disquieting.

Knitted fiber particulate traps facilitate deep-bed structures. These have excellent filtration properties, particularly for ultra-fine particulates. They are also suitable as substrate for catalytic processes. The two characteristics are: high total surface area of the filaments, and good mass transfer. These are prerequisites for intense catalytic activity. The deposited soot is uniformly distributed. Therefore, temperature peaks are avoided during regeneration. The tested coatings lower the regeneration temperature by about 200°C to burn-off temperatures below 350°C. Further improvements seem attainable. Thus, a purely passive regeneration appears feasible for most applications. The system is autonomous and cost effective. However, in extreme low load situations, e.g. city bus services, the necessary exhaust temperatures are not attained. Hence, burners or electrical heating is necessary for trap regeneration.

There is growing concern about the risk potential of Diesel particulates. This prompted two Swiss R&D projects focused on the capabilities of different soot trap concepts for filtering finest particulates. Eight different filter media, some in numerous variants, were tested on four different Diesel engines. All traps attained their gravimetric target. However, there are noticeable performance differences for finest particulates at or smaller than 50 nm. Fiber deep filters seem to be noticeably better than other filter types. If the carcinogens are mainly the finest particulates, then this criterion may become important in future trap evaluation.

Microfibers with high specific micro-surface can be knitted into two-dimensional structures with large internal porosity. Catalytically active metals can be deposited on the fibers with high dispersion by wet-impregnation, sol-gel or CVD, respectively. These microfiber knits may be used for exhaust gas treatment systems with a triple function: particle filtration, gas conversion and muffling. The total oxidation of propane on Pd and Pt coated fibers has been studied as a test reaction. Conversion temperature could be remarkably reduced compared to cellular structures. For a bimetallic (Pt-Pd) coating, the activity is independent of humidity or oxygen concentration. Thus a catalytic converter based on micro-fiber knits appears feasible. Its high mass and heat transfer prevent hot spots. And it functions as submicron filter for combustion aerosols. Integrated electric heating can also be provided in case of low gas temperatures. First tests on engines show promising results.

Diesel engines are irreplaceable in tunnel construction. The particulate emissions of present day engines are so high that the imission limits valid since 1991 cannot be attained by ventilation alone. This problem had to be solved preparatory to the large tunnel projects in Switzerland, Austria and Germany. Several retro-fitting measures were investigated both in the laboratory and in field tests, within the scope of the Project VERT. Oxidation catalytic converters, exhaust gas recirculation, and the usage of special fuels cannot be recommended. Particulate trap deployment, in different systems, was mostly successful. Particular attention was focused on the dependable filtration of finest particulates < 200 nm. The VERT proved that exhaust gas after-treatment with particulate traps is feasible, cost effective and controllable in the field. Pertinent directives are in discussion.

Vegetable oils blended to Diesel fuel are becoming popular. Economic, ecological and even political reasons are cited to decrease dependence on mineral oil and improve CO2 balance. The chemical composition of these bio fuels is different from mineral fuel, having less carbon and much more oxygen. Hence, internal combustion of Diesel + RME (Rapeseed Methyl Ester) blends was tested with particular focus on nanoparticle emissions, particle filtration characteristics and PAH-emissions. Fuel economy and emissions of bus engines were investigated in traffic, on a test-rig during standardized cycles, and on the chassis dynamometer. Fuel compositions were varied from standard EN 590 Diesel with <50 ppm sulfur to RME blends of 15, 30, and 50%. Also 100 % RME was tested on the test-rig. Emissions were compared with and without CRT traps. The PAH profiles of PM were determined. Particles were counted and analyzed for size, surface, and composition, using SMPS, PAS, DC and Coulometry.

Most particulate traps efficiently retain soot of diesel engine exhaust but the potential hazard to form secondary emissions has to be controlled. The Diesel Particle Filter (DPF) regeneration is mainly supported by metal additives or metallic coatings. Certain noble or transition metals can support the formation of toxic secondary emissions such as Dioxins, Polycyclic Aromatic Hydrocarbons (PAH), Nitro-PAH or other volatile components. Furthermore, particulate trap associated with additive metals can penetrate through the filter system or coating metals can be released from coated systems. The VERT test procedure was especially developed to assess the potential risks of a formation of secondary pollutants in the trap. The present study gives an overview to the VERT test procedure. Aspects of suitability of different fuel additives and coating metals will be discussed and examples of trap and additive induced formation of toxic secondary emissions will be presented.