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In this paper, experimental investigation on spray atomization and droplet dynamics inside a thermostatic expansion valve (TXV), a component commonly used in vehicle refrigeration system, was conducted. A needle and an orifice were copied from a commercial TXV and machined to be mounted inside a chamber with optical access so that the flow inside the TXV is simulated and visualized at the same time. The break-up and atomization of the refrigerant were documented near the downstream of the orifice under different feed conditions for two TXV with different geometry. A Phase Doppler Anemometry (PDA) system was used later to measure the size and velocity of atomized refrigerant droplets. The results showed that the droplet size variation along the radial direction is slightly decreased at near downstream and increased at farther downstream due to the coalescence.

Selective catalytic reduction (SCR) of NOx is coming into worldwide use for automotive diesel emissions control. To meet the most stringent standards, NOx conversion efficiency must exceed 80% while NH3 emissions or slip must be kept below 10-30 ppm. At such high levels of performance, non-uniformities in ammonia-to-NOx ratio (ANR) at the converter inlet can limit the achievable NOx reduction. Despite its significance, this effect is frequently ignored in 1D catalyst models. The corresponding model error is important to system integration engineers because it affects system sizing, and to control engineers because it affects both steady-state and dynamic SCR converter performance. A probability distribution function (PDF) based method is introduced to include mixture non-uniformity in a 1D, real-time catalyst model.

With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. To seek for an optimized volumetric ratio for ABE-diesel blends, the previous work in our team has experimentally investigated and analyzed the combustion features of ABE-diesel blends with different volumetric ratio (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %) in a constant volume chamber. It was found that an increased amount of acetone would lead to a significant advancement of combustion phasing whereas butanol would compensate the advancing effect. Both spray dynamic and chemistry reaction dynamic are of great importance in explaining the unique combustion characteristic of ABE-diesel blend. In this study, a semi-detailed chemical mechanism is constructed and used to model ABE-diesel spray combustion in a constant volume chamber.

Hydrogen fuel is a future energy to solve the problems of energy crisis and environmental pollution. Hydrogen internal combustion engines can combine the advantage of hydrogen without carbon pollution and the main basic structure of the traditional engines. However, the power of the port fuel injection hydrogen engines is smaller than the same volume gasoline engine because the hydrogen occupies the volume of the cylinder and reduces the air mass flow. The turbocharger can increase the power of hydrogen engines but also increase the NOx emission. Hence, a comprehensive controlling strategy to solve the contradiction of the power, BTE and NOx emission is important to improve the performance of hydrogen engines. This paper shows the controlling strategy for a four-stroke, 2.3L hydrogen engine with a turbocharger. The controlling strategy divides the operating conditions of the hydrogen engine into six parts according to the engine speeds and loads.

The combustion and emission characteristics of a diesel engine running on butanol-diesel blends were investigated in this study. The blending ratio of n-butanol to diesel was varied from 0 to 40 vol% using an increment of 10 vol%, and each blend was tested on a 2.7 L V6 common rail direction injection diesel engine equipped with an EGR system. The test was carried out under two engine loads at a constant engine speed, using various combinations of EGR ratios and injection timings. Test results indicate that n-butanol addition to engine fuel is able to substantially decrease soot emission from raw exhaust gas, while the change in NOx emissions varies depending on the n-butanol content and engine operating conditions. Increasing EGR ratio and retarding injection timing are effective approaches to reduce NOx emissions from combustion of n-butanol-diesel blends.

Biodiesel fuels and their blends with diesel are often used to reduce emissions from diesel engines. However, biodiesel has been shown to increase the NOx emissions. Operating a compression ignition engine in low-temperature combustion mode as well as using multiple injections can reduce NOx emissions. Experimental data for biodiesel are compared to those for diesel to show the effect of the biodiesel on the peak pressure, temperature, and emissions. Accurate prediction of biodiesel properties, combined with the KIVA 3V code, is used to investigate the combustion of biodiesel. The volume fraction of the cylinder that has temperatures greater than 2200 K is shown to directly affect the production of oxides of nitrogen. Biodiesel is shown to burn faster during the combustion events, though the ignition delay is often longer for biodiesel compared to diesel.

A numerical study of micro-explosion in multi-component droplets is presented. The homogeneous nucleation theory is used in describing the bubble generation process. A modified Rayleigh equation is then used to calculate the bubble growth rate. The breakup criterion is then determined by applying a linear stability analysis on the bubble-droplet system. After the explosion/breakup, the atomization characteristics, including Sauter mean radius and averaged velocity of the secondary droplets, are calculated from conservation equations. Micro-explosion can be enhanced by introducing biodiesel into the fuel blends of ethanol and tetradecane. Micro-explosion is more likely to occur at high ambient pressure. However, increasing the ambient temperature does not have a significant effect on micro-explosion. There exists an optimal composition in the liquid mixture for micro-explosion.

This paper presents the latest results for a new high efficiency clean diesel combustion system – Adaptive PCCI Combustion (a premixed charge compression ignition mixed-mode combustion) using a micro-variable circular orifice (MVCO) fuel injector. Key characteristics of the new combustion system such as low NOx and soot emissions, high fuel efficiency, increased engine torque are presented through KIVA simulation results. While early premixed charge compression ignition (PCCI) combustion reduces engine-out NOx and soot, it's limited to partial loads by known issues such as combustion control, high HC and CO, and high pressure rise rate, etc. Conventional combustion is well controlled diffusion combustion but comes with high NOx and soot. Leveraging the key merits of PCCI and conventional combustion in a practical engine is both meaningful and challenging.

The operation of a small bore high speed direct injection (HSDI) engine with a MVCO injector is simulated by the KIVA 3V code, developed by Los Alamos National Laboratory. The MVCO injector extends the range of injection timings over conventional injectors and it extra flexibility in designing injection schemes. Combustion from very early injection is observed with MVCO injections but not with conventional injection. This improves the fuel economy of the engine in terms of lower ISFC. Even better efficiency can be achieved by using biodiesel, which may be due to extra oxygen in the fuel improving the combustion process. Biodiesel sees a longer ignition delay for the initial injection. It also exhibits a faster burning rate and shorter combustion duration. Biodiesel also lowered both NOx and soot emissions. This is consistent with the general observation for soot emissions.

An optically accessible single-cylinder high-speed direct-injection (HSDI) diesel engine equipped with a Bosch common rail injection system was used to study effects of injection pressures on the in-cylinder spray and combustion processes. An injector with an injection angle of 70 degrees and European low sulfur diesel fuel (cetane number 54) were used in the work. The operating load was 2.0 bar IMEP with no EGR added in the intake. The in-cylinder pressure was measured and the heat release rate was calculated. High-speed Mie-scattering technique was employed to visualize the liquid distribution and evolution. High-speed combustion video was also captured for all the studied cases using the same frame rate. NOx emissions were measured in the exhaust pipe. The experimental results indicated that for all of the conditions the heat release rate was dominated by a premixed combustion pattern. Two-stage low temperature reaction was seen for early injection timings.

A single nozzle port fuel injector was modified to apply electrostatic charge to the fuel stream, with the intention of studying electrostatically assisted sprays in a practical, port-injected engine. The modifications were kept external to the injector and involved placing an electrode and insulating liner over the tip of the injector. The performance of the modified injector, which combined pressure driven and electrostatic atomization, was characterized in three phases: the injector sprays themselves were studied, combustion of charged fuel droplets was studied, and the injector was installed and tested on a single cylinder spark ignition engine. In the first phase, Fraunhofer diffraction measurements of droplet size, and particle image velocimetry measurements of droplet velocity were performed. The charge transferred by the sprays was measured using an electrometer, and typical forces exerted on droplets in the sprays were estimated.

HCCI/PCCI combustion concepts have been demonstrated for both high brake thermal efficiency and low engine-out emissions. However, these advanced combustion concepts still could not be fully utilized partially due to the limitations of conventional fixed spray angle nozzle designs for issues related to wall wetting for early injections. The micro-variable circular orifice (MVCO) fuel injector provides variable spray angles, variable orifice areas, and variable spray patterns. The MVCO provides optimized spray patterns to minimize combustion chamber surface-wetting, oil dilution and emissions. Designed with a concise structure, MVCO can significantly extend the operation maps of high efficiency early HCCI/PCCI combustion, and enable optimization of a dual-mode HCCI/PCCI and Accelerated Diffusion Combustion (ADC) over full engine operating maps. The MVCO variable spray pattern characteristics are analyzed with high speed photographing.

A new approach of NOx reduction in the compression-ignition engine is introduced in this work. The previous research has shown that during the combustion stage, the high temperature ignition tends to occur early at the near-stoichiometric region where the combustion temperature is high and majority of NOx is formed; Therefore, it is desirable to burn the leaner region first and then the near-stoichiometric region, which inhibits the temperature rise of the near-stoichiometric region and consequently suppresses the formation of NOx. Such inverted ignition sequence requires mixture with inverted phi-sensitivity. Fuel selection is performed based on the criteria of strong ignition T-sensitivity, negligible negative temperature coefficient (NTC) behavior, and large heat of vaporization (HoV).

Bio-butanol has been widely investigated as a promising alternative fuel. However, the main issues preventing the industrial-scale production of butanol is its relatively low production efficiency and high cost of production. Acetone-butanol-ethanol (ABE), the intermediate product in the ABE fermentation process for producing bio-butanol, has attracted a lot of interest as an alternative fuel because it not only preserves the advantages of oxygenated fuels, but also lowers the cost of fuel recovery for individual component during fermentation. If ABE could be directly used for clean combustion, the separation costs would be eliminated which save an enormous amount of time and money in the production chain of bio-butanol.

Due to the increasing consumption of fossil fuels, alternative fuels in internal combustion engines have attracted a lot of attention in recent years. Ethanol is the most common alternative fuel used in spark ignition (SI) engines due to its advantages of biodegradability, positively impacting emissions reduction as well as octane number improvement. Meanwhile, acetone is well-known as one of the industrial waste solvents for synthetic fibers and most plastic materials. In comparison to ethanol, acetone has a number of more desirable properties for being a viable alternative fuel such as its higher energy density, heating value and volatility.

The motivation of the present work was to understand the mechanism by which alcohols produce less aromatic species in their combustion process than an equal amount of hydrocarbon with similar molecular structure does. Due to its numerous advantages over short-chain alcohols, butanol has been considered very promising in soot reduction. Excluding the influence of spray, vaporization and mixing process in engine cases, an adiabatic constant-pressure reactor model was applied to investigate the effect of butanol additives on aromatic species, which are known to be soot precursors, in fuel-rich butane flames. To keep the carbon flux constant, 5% and 10% oxygen by mass of the fuel were added to butane using butanol additive, respectively. Based on the soot reduction effects proposed in literature, effects on temperature, key radical concentrations and the carbon removal from the pathway to aromatic species were considered to identify the major mechanism of reduction in aromatic species.

The performance and emission of an AVL 5402 single-cylinder engine fueled with acetone-butanol-ethanol (ABE) / diesel blends were experimentally investigated at various load conditions and injection timings. The fuels tested in the experiments were ABE10 (10% ABE, 90% diesel), ABE20 and diesel as baseline. Thermodynamics analyses of pressure traces acquired in experiments were performed to show the impact of ABE concentration to the overall combustion characteristics of the fuel mixtures. Cumulative heat release analysis showed that ABE mixtures generally retarded the overall combustion phasing, ignition delays of ABE-containing fuels were significantly extended, however, combustion rate during CA10∼CA50 were accelerated at different extent. Pressure rise rate of ABE-containing fuels further implicated that the premixed combustion were more dominant than that of diesel. Polytropic indices of both expansion and compression strokes were calculated from p-V diagram.

In order to comply with the stringent emission regulations, many researchers have been focusing on diesel-compressed natural gas (CNG) dual fuel operation in compression ignition (CI) engines. The diesel-CNG dual fuel operation mode has the potential to reduce both the soot and NOx emissions; however, the thermal efficiency is generally lower than that of the pure diesel operation, especially under the low and medium load conditions. The current experimental work investigates the potential of using diesel-1-butanol blends as the pilot fuel to improve the engine performance and emissions. Fuel blends of B0 (pure diesel), B10 (90% diesel and 10% 1-butanol by volume) and B20 (80% diesel and 20% 1-butanol) with 70% CNG substitution were compared based on an equivalent input energy at an engine speed of 1200 RPM. The results indicated that the diesel-1-butanol pilot fuel can lead to a more homogeneous mixture due to the longer ignition delay.

An experimental investigation was conducted using a Ford single-cylinder spark-ignition research engine to compare the performance and emissions of neat n-butanol fuel to that of gasoline and ethanol. Measurements of brake torque and exhaust gas temperature along with in-cylinder pressure traces were used to study the performance of the engine and measurements of emissions of unburned hydrocarbons, carbon monoxide, and nitrogen oxide ere used to compare the three fuels in terms of combustion byproducts. It was found that gasoline and butanol are closest in engine performance with butanol producing slightly less brake torque. Exhaust gas temperature and nitrogen oxide measurements show that butanol combusts at a lower peak temperature. Of particular interest were the emissions of unburned hydrocarbons which were between two and three times those of gasoline suggesting that butanol is not atomizing as effectively as gasoline and ethanol.

Performance and emissions of a common-rail production diesel engine fueled with soybean-derived biodiesel was investigated. The work was broken down into two categories. First, adjustment of injection timing and EGR ratio was investigated as a means to reduce NOx emissions to levels comparable with those obtained when using pure diesel fuel. Next, simultaneous reduction of NOx and soot emissions was investigated using high rates of EGR combined with late injection timings to approach the low-temperature combustion regime. Results from the first part of the study indicate that optimization of engine control parameters for use with biodiesel can be beneficial to performance and emissions. It was found that adjusting the engine's MAF setpoint table to reflect the difference in stoichiometric air-fuel ratio between diesel and biodiesel brought NOx emissions to comparable or lower levels.