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Some papers on the combustion in a diesel engine have been already presented to discuss the effect of the additive called ADOIL TAC. A bottom view DI diesel engine driven at 980rpm with no load was used in the experiment presented here, in order to make clear this effect. JIS second class light diesel fuel oil was injected through a hole nozzle at the normal test run. The additive was intermixed 0.01 vol. % in this fuel oil, in the experiments to compare with the normal combustion. The flame was taken by direct high-speed photography. Profiles of flame temperature and KL were detected on the film by image processing, applying the two-color method. Soot was visualized by high-speed laser shadowgraphy, and the heat release rate was calculated using the cylinder pressure diagram. Discussion on the effect of the additive on the combustion phenomena was made by using all the data.

Fuel design concept has been proposed for low emission and combustion control in engine systems. In this concept, the multicomponent fuels, which are mixed with a high volatility fuel (gasoline or gaseous fuel components) and a low volatility fuel (gas oil or fuel oil components), are used for artificial control of fuel properties. In addition, these multicomponent fuels can easily lead to flash boiling which promote atomization and vaporization in the spray process. In order to understand atomization and vaporization process of multicomponent fuels in detail, the model for flash boiling spray of multicomponent fuel have been constructed and implemented into KIVA3V rel.2. This model considers the detailed physical properties and evaporation process of multicomponent fuel and the bubble nucleation, growth and disruption in a nozzle orifice and injected fuel droplets.

Ignition, combustion and emissions characteristics of dual-component fuel spray were examined for ranges of injection timing and intake-air oxygen concentration. Fuels used were binary mixtures of gasoline-like component i-octane (cetane number 12, boiling point 372 K) and diesel fuel-like component n-tridecane (cetane number 88, boiling point 510 K). Mass fraction of i-octane was also changed as the experimental variable. The experimental study was carried out in a single cylinder compression ignition engine equipped with a common-rail injection system and an exhaust gas recirculation system. The results demonstrated that the increase of the i-octane mass fraction with optimizations of injection timing and intake oxygen concentration reduced pressure rise rate and soot and NOx emissions without deterioration of indicated thermal efficiency.

CNG is one of the future fuel for a CI engine. Recently, the general tendency is the use of the high pressure injection system over 100 MPa in a CI engine for the near future severe regulation. Combustion phenomenon in a CI engine with such injection system is like a transient gas diffusion flame. The flow in a gas diffusion flame was investigated by the particle image velocimetry on its 2-D images, the relative soot concentration, the temperature and the relative CO2 concentration was detected in the experiments. And the model of transient gas diffusion flame was constructed by use of experimental data.

Authors propose the reformulation technique of physical properties of Biodiesel Fuel (BDF) by mixing lower boiling point fuels. In this study, waste cooking oil methyl ester (B100), which have been produced in Kyoto city, is used in behalf of BDF. N-Heptane (C7H16) and n-Dodecane (C12H26) are used as low and medium boiling point fuel. Mixed fuel of BDF with lower boiling point fuels have lighter quality as compared with neat BDF. This result is based on the chemical-thermo dynamical liquid-vapor equilibrium theory. This paper describes fundamental spray and combustion characteristics of mixed fuel of B100 with lower boiling point fuels as well as the reformulation technique. By mixing lower boiling point fuel, lighter quality fuels can be refined. Thus, mixed fuels have higher volatility and lower viscosity. Therefore, vaporization of mixed fuel spray is promoted and liquid phase penetration of mixed fuel shortens as compared with that of neat BDF.

It is thought that the synthetic gas, including hydrogen and carbon monoxide, has a potential to be an alternative fuel for internal combustion engines, because a heating value of the synthetic gas is higher than one of hydrogen or natural gas. A purpose of this study is to acquire stable auto-ignition and combustion of the synthetic gas which is supposed to be applied into a direct-injection compression ignition engine. In this study, the effects of ambient gas temperatures and oxygen concentrations on auto-ignition characteristics of the synthetic gas with changing percentage of hydrogen (H2) or carbon monoxide (CO) concentrations in the synthetic gas. An electronically-controlled, hydraulically-actuated gas injector was used to control a precise injection timing and period of gaseous fuels, and the experiments were conducted in an optically accessible, constant-volume combustion chamber under simulated quiescent diesel engine conditions.

A transient gas jet and its flame are the most fundamental phenomena of a transient spray and its flame breaking out in a CI engine and an SI engine with the direct injection system. In the case of CNG and LNG engines, the fuel itself is just gaseous state. The 2-LIF technique was applied to the transient gas jet to obtain the mixing process between the surroundings and it, and the simultaneous application of LII and LIS techniques were applied to the transient gas jet flame to obtain the soot formation process.

This paper describes the results of on-board measurement of engine performance and emissions in diesel vehicle operated with bio-diesel fuels. Here, two waste-cooking oils were investigated. One fuel is a waste-cooking oil methyl esters. This fuel is actually applied to a garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is a fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. Then, these 3 bio-diesel fuels were applied to the on-board experiments and the results were compared with gas oil operation case.

The Flame structure and combustion characteristics for two waste-cooking oils were investigated in detail. One fuel is the waste-cooking oil methyl esters. This fuel is actually applied to the garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is the fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. In the experiments, the used fuels were gas oil, i-BDF, B100 and B20. Spray characteristics and basic combustion properties were measured inside a rapid compression and an expansion machine (RCEM).

Flash-boiling occurs when a fuel is injected to a combustion chamber where the ambient pressure is lower than the saturation pressure of the fuel. It has been known that flashing is a favorable mechanism for atomizing liquid fuels. On the other hand, alternative fuels, such as gaseous fuels and oxygenated fuels, are used to achieve low exhaust emissions in recent years. In general, most of these alternative fuels have high volatility and flash-boiling takes place easily in fuel spray, when they are injected into the combustion chamber of an internal combustion engine under high pressure. In addition, fuel design concept the multicomponent fuel with high and low volatility fuels has been proposed in the previous study in order to control the spray and combustion processes in internal combustion engine. It is found that the multicomponent fuel produce flash-boiling with an increase in the initial fuel temperature.

It is expected that the analysis of the evaporation process for multicomponent fuels such as actual fuels like gasoline and diesel gas oil could be performed to assess more accurately the mixture preparation field inside the cylinder of D.I.S.I engines and diesel engines. In this paper, we suggested the importance of this multicomponent fuel consideration relating to the mixture formation and combustion characteristics from the basis of their own fuel physical and chemical properties. Then, we introduce a treatment for the phase change of a multicomponent solution through the formation of two-phase regions with the basis of chemical-thermodymical liquid-vapor equilibrium. Next, we analyze the distillation properties of a multicomponent fuel as well as the evaporation process of a multicomponent single droplet by use of the chemical-thermodymical analysis.

This paper confirms a structure for the soot formation process inside a burning diesel jet plume of oxygenated fuels. An explanation of how the soot formation process changes by the use of oxygenated fuel in comparison with that for using a conventional diesel fuel, and why oxygenated fuel drastically suppresses the soot formation has been derived from the chemical kinetic analysis. A detailed chemical kinetic mechanism, which is combined with various proposed chemical kinetic models including normal paraffinic hydrocarbon oxidation, oxygenated hydrocarbon oxidation, and poly-aromatic hydrocarbon (PAH) formation, was developed in present study. The calculated results are presented to elucidate the influence of fuel mixture composition and fuel structure, especially relating to oxygenated fuels, on PAH formation. The analysis also provides a new insight into the initial soot formation process in terms of the temperature range of PAH formation.

This work presents the ignition delay time characteristics of oxygenated fuel sprays under simulated diesel engine conditions. A constant volume combustion vessel is used for the experiments. The fuels used in the experiments were three oxygenated fuels: diethylene glycol dibutyl ether, diethylene glycol diethyl ether, and diethylene glycol dimethyl ether. JIS 2nd class gas oil was used as the reference fuel. The ambient gas temperature and oxygen concentration were ranging from 700 to 1100K and from 21 to 9%, respectively. The results show that the ignition delay of each oxygenated fuel tested in this experiments exhibits shorter than that of gas oil fuel for the wide range of ambient gas conditions. Also, NTC (negative temperature coefficient) behavior which appears under shock tube experiment for homogenous fuel-air mixture was observed on low ambient gas oxygen concentration for each fuel. And at the condition, the ignition behavior exhibits two-stage phase.

This paper provides new insights on the mechanism of the smokeless diesel combustion with oxygenated fuels, based on a combination of soot kinetic modeling and optical diagnostics. The chemical effects of fuel compositions, including aromatics - paraffins blend, neat oxygenated fuels and oxygenate additives, on sooting equivalence ratio ‘ϕ’ - temperature ‘T’ dependence were numerically examined using a detailed soot kinetic model. To better understand the physical factors affecting soot formation in oxygenated fuel sprays, the effects of injection pressure and ambient gas temperature on the flame lift-off length and relative soot concentration in oxygenated fuel jets were experimentally investigated. The computational results show that the leaner mixture side of soot formation peninsula on the ϕ - T map, rather than the lower temperature one, should be utilized to suppress the formation of PAHs and ultra-fine particles together with the large reduction in particulate mass.

In this study, a rapid compression and expansion machine(RCEM) with a pancake combustion chamber was designed to investigate fundamentally on the knocking phenomena in spark ignition(S.I) engines. This RCEM is intended to simulate combustion in an actual engine. The homogeneous pre-mixture of n-pentane and air was charged into a quiescent atmosphere of the chamber. Then, the combustion field become simpler in this machine than it in a real S.I. engine. Also, the combustion phenomena, that is a cylinder pressure history, the behavior of flame propagation and so on, with high reproducibility are realized in this machine. The phenomena caught in this experiment were so-called low speed knocking. And, this knocking characteristics such as a knock intensity and a knock mass fraction were revealed by the cylinder pressure analysis varying the charge pressure and the equivalence ratio of the mixture, a compression ratio and an ignition timing.

In this study, it is purpose to make clear the effect of cavitation phenomenon on the spray atomization. In this report, the cavitation phenomenon inside the nozzle hole was visualized and the pressure measurements along the wall of the nozzle hole were carried out by use of 25-times enlarged acrylic nozzle. For the representatives of regular gasoline, single and two-component fuels were used as a test fuel. In addition, various cavitating flow patterns same as experimental conditions were simulated by use of Barotropic model incorporated in commercial code of Star-CD scheme, and compared with experimental results.

Methyl butanoate (MB) and methyl decanoate (MD) are surrogates for biodiesel fuels. According to computational results with their detailed reaction mechanisms, MB and MD indicate shorter ignition delays than long alkanes such as n-heptane and n-dodecane do at an initial temperature over 1000 K. The high ignitability of these methyl esters was computationally analyzed by means of contribution matrices proposed by some of the authors. Due to the high acidity of an α-H atom in a carbonyl compound, hydroperoxy radicals are generated out of the equilibrium between forward and backward reactions of O₂ addition to methyl ester radicals by the internal transfer of an α-H atom in the initial stage of an ignition process. Some of the hydroperoxy methyl ester radicals can generate OH to activate initial reactions. MB has an efficient CH₃O formation path via CH₃ generated by the β-scission of an MB radical which has a radical site on the α-C atom to the carbonyl group.

In the direct injection spark ignition gasoline engine (D-4), thin fan-shaped high-dispersion, high-penetration and high-atomization spray formed by the slit nozzle generates a stratified mixture cloud without depending on a strong intake air motion, subsequently realizing stable stratified charge combustion. To improve fuel economy further in actual traffic, the region of stratified charge combustion in torque-engine speed map must be expanded by improving spray characteristics. Since the fuel flow inside the nozzle has a large effect on the spray characteristics, it was clarified this effect by visual analysis of the fuel flow inside the nozzle using an enlarged acrylic slit nozzle of 10 magnifications. Consequently, it was found that vortices are generated frequently within a sac even in the case of steady state conditions. The effect on the spray characteristics is corresponding to the vortex scale.

One of the most effective means of improving the thermal efficiency and the specific fuel consumption in spark ignition engines is the increase of the compression ratio. However, there is a limit to it because of the generation of knocking combustion due to the rise of temperature and pressure in the unburnt mixture. Also in turbo charged spark ignition engines, the ignition timing cannot be advanced until MBT in order to avoid the knocking phenomena. Generally speaking, it is very difficult to investigate the phenomena in an actual engine, because there are many restriction and the phenomena are too complex and too fast. According-ly, it is advantageous to reveal the phenomena fundamentally, including the autoignition process of the end-gas by using simplified model equipment. Therefore, a rapid compression and expansion machine (RCEM) with a pan-cake combustion chamber was designed and developed for the experiments presented here.

A transient gas jet seems to be a model of a diesel spray because it has no vaporization process. Recently, CNG is utilized in a diesel engine. In the case of diesel engine, sprays or jets have the free state in some cases, and they are impinging surely on the piston surface in the other cases. The 2-D image of acetylene gas with tracer particles was taken by high-speed photography. In both jets, the outer shape was measured on the images and the characteristics of the internal flow was obtained by particle image velocimetry. Then, the physical models of these jets were constructed by use of experimental results.