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Technical Paper

A Study of the Effect of a Catalyzed Particulate Filter on the Emissions from a Heavy-Duty Diesel Engine with EGR

2001-03-05
2001-01-0910
The effects of a catalyzed particulate filter (CPF) and Exhaust Gas Recirculation (EGR) on heavy-duty diesel engine emissions were studied in this research. EGR is used to reduce the NOx emissions but at the same time it can increase total particulate matter (TPM) emissions. CPF is technology available for retrofitting existing vehicles in the field to reduce the TPM emissions. A conventional low sulfur fuel (371 ppm S) was used in all the engine runs. Steady-state loading and regeneration experiments were performed with CPF I to determine its performance with respect to pressure drop and particulate mass characteristics at different engine operating conditions. From the dilution tunnel emission characterization results for CPF II, at Mode 11 condition (25% load - 311 Nm, 1800 rpm), the TPM, HC and vapor phase emissions (XOC) were decreased by 70%, 62% and 62% respectively downstream of the CPF II.
Technical Paper

A Computer Simulation of the Turbocharged Diesel Engine as an Enhancement of the Vehicle Engine Cooling System Simulation

1997-05-19
971804
A computer simulation of the turbocharged direct- injection diesel engine was developed to enhance the capabilities of the Vehicle Engine Cooling System Simulation (VECSS) developed at Michigan Technological University. The engine model was extensively validated against Detroit Diesel Corporation's (DDC) Series 60 engine data. In addition to the new engine model a charge-air-cooler model was developed and incorporated into the VECSS. A Freightliner truck with a Detroit Diesel's Series 60 engine, Behr McCord radiator, AlliedSignal/Garrett Automotive charge air cooler, Kysor DST variable speed fan clutch and other cooling system components was used for the study. The data were collected using the Detroit Diesel Electronic Controls (DDEC)-Electronic Control Module (ECM) and Hewlett Packard data acquisition system. The enhanced model's results were compared to the steady state TTD (top tank differential) data.
Technical Paper

A Study of the Effects of Exhaust Gas Recirculation on Heavy-Duty Diesel Engine Emissions

1998-05-04
981422
The effects of exhaust gas recirculation (EGR) on heavy-duty diesel emissions were studied at two EPA steady-state operating conditions, old EPA mode 9* (1800 RPM, 75% Load) and old EPA mode 11 (1800 RPM, 25% Load). Data were collected at the baseline, 10% and 16% EGR rates for both EPA modes. The study was conducted using a 1995 Cummins M11-330E heavy-duty diesel engine and compared to the baseline emissions from the Cummins 1988 and 1991 L10 engines. The baseline gas-, vapor- and particle-phase emissions were measured together with the particle size distributions at all modes of operation. The total particulate matter (TPM) and vapor phase (XOC) samples were analyzed for physical, chemical and biological properties. The results showed that newer engines with electronic engine controls and higher injector pressures produce TPM decreases from the 1988 to 1991 to 1995 engines with the solids decreasing more than the soluble organic fraction (SOF) of TPM.
Technical Paper

A Study of the Vapor- and Particle-Phase Sulfur Species in the Heavy-Duty Diesel Engine EGR Cooler

1998-05-04
981423
To meet future NO, heavy-duty diesel emissions standards, exhaust gas recirculation (EGR) technology is likely to be used. To improve fuel economy and further lower emissions, the recirculated exhaust gas needs to be cooled, with the possibility that cooling of the exhaust gas may form sulfuric acid condensate in the EGR cooler. This corrosive condensate can cause EGR cooler failure and consequentially result in severe damage to the engine. Both a literature review and a preliminary experimental study were conducted. In this study, a manually controlled EGR system was installed on a 1995 Cummins Ml l-330E engine which was operated at EPA mode 9* (1800 rpm and 75% load). The Goksoyr-Ross method (1)** was used to measure the particle-phase sulfate and vapor-phase H2SO4 and SO2 at the inlet and outlet locations of the EGR cooler, obtaining H2SO4 and SO2 concentrations. About 0.5% of fuel sulfur in the EGR cooler was in the particle-phase.
Technical Paper

The Effect of Fuel and Engine Design on Diesel Exhaust Particle Size Distributions

1996-02-01
960131
The objective of this research was to obtain diesel particle size distributions from a 1988 and a 1991 diesel engine using three different fuels and two exhaust control technologies (a ceramic particle trap and an oxidation catalytic converter). The particle size distributions from both engines were used to develop models to estimate the composition of the individual size particles. Nucleation theory of the H2O and H2SO4 vapor is used to predict when nuclei-mode particles will form in the dilution tunnel. Combining the theory with the experimental data, the conditions necessary in the dilution tunnel for particle formation are predicted. The paper also contains a discussion on the differences between the 1988 and 1991 engine's particle size distributions. The results indicated that nuclei mode particles (0.0075-0.046 μm) are formed in the dilution tunnel and consist of more than 80% H2O-H2SO4 particles when using the 1988 engine and 0.29 wt% sulfur fuel.
Technical Paper

A Review of Diesel Particulate Control Technology and Emissions Effects - 1992 Horning Memorial Award Lecture

1994-03-01
940233
Studies have been conducted at Michigan Technological University (MTU) for over twenty years on methods for characterizing and controlling particulate emissions from heavy-duty diesel engines and the resulting effects on regulated and unregulated emissions. During that time, control technologies have developed in response to more stringent EPA standards for diesel emissions. This paper is a review of: 1) modern emission control technologies, 2) emissions sampling and chemical, physical and biological characterization methods and 3) summary results from recent studies conducted at MTU on heavy-duty diesel engines with a trap and an oxidation catalytic converter (OCC) operated on three different fuels. Control technology developments discussed are particulate traps, catalysts, advances in engine design, the application of exhaust gas recirculation (EGR), and modifications of fuel formulations.
Technical Paper

Effects of a Ceramic Particle Trap and Copper Fuel Additive on Heavy-Duty Diesel Emissions

1994-10-01
942068
This research quantifies the effects of a copper fuel additive on the regulated [oxides of nitrogen (NOx), hydrocarbons (HC) and total particulate matter (TPM)] and unregulated emissions [soluble organic fraction (SOF), vapor phase organics (XOC), polynuclear aromatic hydrocarbons (PAH), nitro-PAH, particle size distributions and mutagenic activity] from a 1988 Cummins LTA10 diesel engine using a low sulfur fuel. The engine was operated at two steady state modes (EPA modes 9 and 11, which are 75 and 25% load at rated speed, respectively) and five additive levels (0, 15, 30, 60 and 100 ppm Cu by mass) with and without a ceramic trap. Measurements of PAH and mutagenic activity were limited to the 0, 30 and 60 ppm Cu levels. Data were also collected to assess the effect of the additive on regeneration temperature and duration. Copper species collected within the trap were identified and exhaust copper concentrations quantified.
Technical Paper

A Theoretical and Experimental Study of the Regeneration Process in a Silicon Carbide Particulate Trap Using a Copper Fuel Additive

1997-02-24
970188
The purpose of this study was to investigate the pressure drop and regeneration characteristics of a silicon carbide (SiC) wall-flow diesel particulate filter. The performance of a 25 μm mean pore size SiC dual trap system (DTS) consisting of two 12 liter traps connected in parallel in conjunction with a copper (Cu) fuel additive was evaluated. A comparison between the 25 μm DTS and a 15 μm DTS was performed, in order to show the effect of trap material mean pore size on trap loading and regeneration behavior. A 1988 Cummins LTA 10-300 diesel engine was used to evaluate the performance of the 15 and 25 μm DTS. A mathematical model was developed to better understand the thermal and catalytic oxidation of the particulate matter. For all the trap steady-state loading tests, the engine was run at EPA mode 11 for 10 hours. Raw exhaust samples were taken upstream and downstream of the trap system in order to determine the DTS filtration efficiency.
Technical Paper

The Theoretical Development of Vehicle Engine Cooling Airflow Models Using Incompressible Flow Methods

1991-02-01
910644
A one-dimensional incompressible flow model covering the mechanisms involved in the airflow through an automotive radiator-shroud-fan system with no heat transfer was developed. An analytical expression to approximate the experimentally determined fan performance characteristics was used in conjunction with an analytical approach for this simplified cooling airflow model, and the solution is discussed with illustrations. A major result of this model is a closed form equation relating the transient velocity of the air to the vehicle speed, pressure rise characteristics and speed of the fan, as well as the dimensions and resistance of the radiator. This provides a basis for calculating cooling airflow rate under various conditions. The results of the incompressible flow analysis were further compared with the computational results obtained with a previously developed one-dimensional, transient, compressible flow model.
Technical Paper

The Dimensionless Correlation of Airflow for Vehicle Engine Cooling Systems

1991-02-01
910643
An analysis of vehicle engine cooling airflow by means of a one-dimensional, transient, compressible flow model was carried out and revealed that similarity theory could be applied to investigate the variation of the airflow with ambient and operating conditions. It was recognized that for a given vehicle engine cooling system, the cooling airflow behavior could be explained using several dimensionless parameters that involve the vehicle speed, fan speed, heat transfer rate through the radiator, ambient temperature and pressure, and the system characteristic dimension. Using the flow resistance and fan characteristics measured from a prototype cooling system and the computer simulation for the one-dimensional compressible flow model, a quantitative correlation of non-dimensional mass flow rate to three dimensionless parameters for a prototype heavy-duty truck was established. The results are presented in charts, tables, and formulas.
Technical Paper

The Effect of a Ceramic Particulate Trap on the Particulate and Vapor Phase Emissions of a Heavy-Duty Diesel Engine

1991-02-01
910609
Exhaust emissions were characterized from a Cummins LTA10 heavy-duty diesel engine operated at two EPA steady-state modes with and without an uncatalyzed Corning ceramic particulate trap. The regulated emissions of nitrogen oxides (NOx), hydrocarbons (HC), and total particulate matter (TPM) and its components as well as the unregulated emissions of PAH, nitro-PAH, mutagenic activity and particle size distributions were measured. The consistently significant effects of the trap on regulated emissions included reductions of TPM and TPM-associated components. There were no changes in NOx and HC were reduced only at one operating condition. Particle size distribution measurements showed that nuclei-mode particles were formed downstream of the trap, which effectively removed accumulation-mode particles. All of the mutagenicity was direct-acting and the mutagenic activity of the XOC was approximately equivalent to that of the SOF without the trap.
Technical Paper

The Measurement and Sampling of Controlled Regeneration Emissions from a Diesel Wall-Flow Particulate Trap

1991-02-01
910606
A diesel exhaust sampling system was specially designed to measure and collect emissions from a ceramic wall-flow particulate trap during periods of controlled electric regeneration with the exhaust emissions bypassing the trap. This resulted in the regeneration emissions being independent of those produced during either baseline (no control) or trap (exhaust filtration) sampling conditions. This system provided data regarding the physical, chemical, and biological character of regeneration emissions relative to baseline and trap emissions. Selected emission levels measured continuously during the regeneration process were also used to define the particle combustion process in the trap core. Variations in hydrocarbons (HC), oxides of nitrogen (NOx), and particulate volume concentrations during the regeneration process were used to define four stages of the combustion process: preheat; combustion wave formation; combustion wave propagation; and combustion wave extinction.
Technical Paper

The Influence of Sampling Conditions on the Repeatability of Diesel Particulate and Vapor Phase Hydrocarbon and PAH Measurements

1990-02-01
900642
A study was conducted to assess the effects of controlling filter face temperatures and two differently sized collection systems on diesel total particulate matter (TPM) and vapor phase hydrocarbon levels from a diesel engine. The results were used to revise sampling protocols so that variability associated with quantitation of polynuclear aromatic hydrocarbons (PAH) is minimized. Particulate soluble organic fraction (SOF) levels (%) were compared 1) for tests where the dilute exhaust filter face temperature was held constant by varying dilution ratio (DR) to account for day to day variations in inlet air temperature to the tunnel and 2) for tests in earlier studies where the DR was held constant and the filter face temperature then varied because of varying tunnel inlet air temperature. Between date variations in %SOF were reduced by about 60% due to holding filter face temperatures constant, compared to holding DR constant.
Technical Paper

The Effects of Fuel Sulfur Concentration on Regulated and Unregulated Heavy-Duty Diesel Emissions

1993-03-01
930730
The effects of fuel sulfur concentration on heavy-duty diesel emissions have been studied at two EPA steady-state operating conditions, mode 9 (1900 RPM, 75% Load) and mode 11(1900 RPM, 25% Load). Data were obtained using one fuel at two sulfur levels (Low Sulfur, LS = 0.01 wt% S and Doped Low Sulfur DS = 0.29 wt% S). All tests were conducted using a Cummins LTA10-300 heavy-duty diesel engine. No significant changes were found for the nitrogen oxides (NOx), soluble organic fractions (SOF) and XAD-2 (a copolymer of styrene and divinylbenzene) organic component (XOC) due to the fuel sulfur level increase at either engine mode. The hydrocarbon (HC) levels were not significantly affected by sulfur at mode 9; however, at mode 11 the HC levels were reduced by 16%. The total particulate matter (TPM) levels increased by 17% at mode 11 and by 24% at mode 9 (both significantly different).
Technical Paper

A Statistical Approach to Determining the Effects of Speed, Load, Oil and Coolant Temperature on Diesel Engine Specific Fuel Consumption

1978-02-01
780971
Experimental Brake Specific Fuel Consumption (BSFC) data are presented for two engines as a function of engine speed, load, outlet coolant temperature and inlet oil temperature. The engines used in the study were the Cummins VT-903 (turbocharged) and the Caterpillar 3208, both being direct-injection and four-cycle. The data were taken for the Cat 3208 engine using a fractional factorial statistical method which reduced the total test matrix from 256 to 64 data points. The experimental data are used in the development of BSFC regression equations as a function of load, speed, outlet coolant temperature and inlet oil temperatures. A mathematical parameter for expressing quantitatively the change of BSFC per 10°F change in coolant and oil temperature is presented. It was found that an increase in the coolant and/or oil temperatures had the effect of reducing BSFC in both engines.
Technical Paper

The Development and Application of Ferrography to the Study of Diesel Engine Wear

1978-02-01
780181
This paper covers the development of Ferrographic oil analysis techniques for the study of diesel engine wear. A brief overview of the various wear analysis techniques now commonly used in laboratory and field engine wear studies is discussed. Also included in this paper is an in depth description of the Ferrographic oil analysis techniques and the various applications of the techniques to the study of engine wear. A comparison of the commonly used wear measurement methods, Ferrography, spectroscopy and the radioactive tracer methods, and their abilities to measure wear is also discussed. A direct injection, 4-cycle, turbocharged diesel engine was used in the testing and data are presented indicating the abilities of the Ferrographic oil analysis techniques to detect changes in wear rates. The effects of operating time on engine oil and the effects of the variation of oil and coolant temperatures on engine wear is presented.
Technical Paper

The Characterization of the Hydrocarbon and Sulfate Fractions of Diesel Particulate Matter

1978-02-01
780111
One of the more objectionable aspects of the use of diesel engines has been the emission of particulate matter. A literature review of combustion flames, theoretical calculations and dilution tunnel experiments have been performed to elucidate the chemical and physical processes involved in the formation of diesel particulate matter. A comparative dilution tunnel study of diluted and undiluted total particulate data provided evidence supporting calculations that indicate hydro-carbon condensation should occur in the tunnel at low exhaust temperatures. The sample collection system for the measurement of total particulate matter and soluble sulfate in particulate matter on the EPA 13 mode cycle is presented. A method to correct for hydrocarbon interferences in the EPA barium chloranilate method for the determination of sulfate in particulate matter is discussed.
Technical Paper

The Physical and Chemical Character of Diesel Particulate Emissions-Measurement Techniques and Fundamental Considerations

1978-02-01
780108
The techniques used to characterize the chemical and physical nature of particulates in diesel exhaust emissions are reviewed. The emphasis is on understanding the broader aspects of the fundamental nature of not only diesel particulates, but particulate systems in general. Consideration is given to the special nature of particulates which make them significant pollutants and to the relative place of the diesel in the formation of man-made particles. The underlying combustion processes leading to carbon and sulfur based particulates are reviewed. The important variables in steps of the combustion processes which lead to particulate formation are considered, as well as major fuel and engine factors. Collection methods are examined with examples given from current diesel dilution techniques. Probes, sampling lines, and instrumentation are considered.
Technical Paper

The Characterization of the Soluble Organic Fraction of Diesel Particulate Matter

1979-02-01
790418
This paper is concerned with the demonstration of a methodology for chemically characterizing diesel particulate organic matter (POM) emissions. The procedure begins with a Soxhlet extraction of the POM with dichloromethane to obtain a soluble organic fraction (SOF). The acidic and basic portions of the SOF are isolated by liquid-liquid extraction techniques with aqueous base and aqueous acid, respectively. The neutral portion of the extract is separated into paraffin, aromatic, transitional and oxygenated fractions by column chromatography on silica gel. Two additional fractions, the ether insoluble and hexane insoluble fractions, are also separated by the procedure. Quantitative mass data are presented on the extraction and fractionation of twelve particulate samples from the exhaust of a medium-duty diesel engine collected in a dilution tunnel at a volume dilution ratio of 8 to 1.
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