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The latest US emission regulations require dramatic reductions in Nitrogen Oxide (NOx) emissions from vehicular diesel engines. Selective Catalytic Reduction (SCR) is the current technology that achieves NOx reductions of up to 90%. It is typically mounted downstream of the existing after-treatment system, i.e., after the Diesel Oxidation Catalyst (DOC) and Diesel Particulate Filter (DPF). Accurate prediction of input NO₂:NO ratio is useful for control of SCR urea injection to reduce NOx output and NH₃ slippage downstream of the SCR catalyst. Most oxidation of NO to NO₂ occurs in the DOC since its main function is to oxidize emission constituents. The DOC thus determines the NO₂:NO ratio as feedgas to the SCR catalyst. The prediction of NO₂:NO ratio varies as the catalyst in the DOC ages or deteriorates due to poisoning. Thus, the DOC prediction model has to take into account the correlation of DOC conversion effectiveness and the aging of the catalyst.