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Corrosion tendency is one of the major inhibitors for increased use of magnesium alloys in automotive structural applications. Moreover, systematic or standardized methods for evaluation of both general and galvanic corrosion of magnesium alloys, either as individual components or eventually as entire subassemblies, remains elusive, and receives little attention from professional and standardization bodies. This work reports outcomes from an effort underway within the U.S. Automotive Materials Partnership - ‘USAMP’ (Chrysler, Ford and GM) directed toward enabling technologies and knowledge base for the design and fabrication of magnesium-intensive subassemblies intended for automotive “front end” applications. In particular, subassemblies consisting of three different grades of magnesium (die cast, sheet and extrusion) and receiving a typical corrosion protective coating were subjected to cyclic corrosion tests as employed by each OEM in the consortium.

An electrochemical testing protocol for assessing the intrinsic corrosion-resistance of creep-resistant magnesium alloys in aqueous environments, and effects of passivating surface films anticipated to develop in the presence of engine coolants is under development. This work reports progress in assessing the relative corrosion resistance of the base metals (AMC-SC1, MRI-202S, MRI-230D, AM50 and 99.98% Mg) in a common test environment, based on a near-neutral pH buffered saline solution, found to yield particularly stable values for the open-circuit or corrosion potential. This approach was found to provide a platform for the eventual assessment of the durability of certain passivating layers expected to develop during exposure of the magnesium alloys to aqueous coolants.

This study utilized Rutherford Backscattering Spectroscopy (RBS) and Auger Electron Spectroscopy (AES) to determine the thickness and composition of corrosion films formed on magnesium alloys exposed to experimental engine coolants intended for use with creep-resistant magnesium alloy engine blocks. Knowledge on the nature of the film formed may produce a better understanding of corrosion inhibition and protection requirements for these materials. This paper will first briefly review the RBS and AES techniques as applied to the characterization of surface films on metals. It will then present results from experiments conducted with pure magnesium and two different magnesium alloys in two engine coolants.

This study reports the performance of three different automotive magnesium substrate materials (AM60B diecastings, AZ31-H24 sheet, and AM30 extrusions), each bonded to a common aluminum reference material with two different toughened adhesives. The magnesium substrates were pretreated with six different commercial pretreatments both with and without a final fused-powder polymeric topcoat. These samples were then evaluated by comparing initial lap-shear strength to the lap-shear strength after cyclic-corrosion testing. Additionally, use of a scribe through the polymer primer permitted assessment of: 1) distance of corrosion undercutting from the scribe (filiform), and 2) percent corrosion over the area of the coupon. The results showed that the performance of each magnesium pretreatment varied on cast AM60B, sheet AZ31-H24, and extruded AM30 substrates.

General corrosion protection of sheet materials such as steel used in automobile construction has reached a high level of performance, due primarily to the incorporation of mill-applied treatments such as electrogalvanizing, galvannealing and other coil-coating processes developed over the last half century. While such treatments have greatly extended the corrosion resistance of steel and its various body constructs, attention is now focused on aspects of the manufacturing process wherein these intended protections are compromised by such features as weldments, joins, cut edges and extreme metal deformations such as hems. A novel metal deposition process, based on high-velocity impact fusion of solid metal particles, has been used to extend the corrosion resistance of base steel and pre-galvanized sheet, by selectively placing highly controlled depositions of zinc and other sacrificial materials in close proximity to critical manufacturing details.