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The effects of secondary air on the exhaust oxidation of particulate matters (PM) have been assessed in a direct-injection-spark-ignition engine under fuel rich fast idle condition (1200 rpm; 2 bar NIMEP). Substantial oxidation of the unburned feed gas species (CO and HC) and significant reduction of both the particulate number (up to ∼80%) and volume (up to ∼90%) have been observed. The PM oxidation is attributed to the reactions between the PM and the radicals generated in the oxidation of the feed gas unburned species. This hypothesis is supported by the observation that the reduction in PM volume is proportional to the amount of heat release in the secondary oxidation.

The first 3 cycles in the cold crank-start process at 20°C are studied in a GDI engine. The focus is on the dependence of the HC and PM/PN emissions of each cycle on the injection strategy and combustion phasing of the current and previous cycles. The PM/PN emissions per cycle decrease by more than an order of magnitude as the crank-start progresses from the 1st to the 3rd cycle, while the HC emissions stay relatively constant. The wall heat transfer, as controlled by the combustion phasing, during the previous cycles has a more significant influence on the mixture formation process for the current cycle than the amount of residual fuel. The results show that the rise in HC emissions caused by the injection spray interacting with the intake valves and piston crown is reduced as the cranking process progresses. Combustion phasing retard significantly reduces the PM emission. The HC emissions, however, are relatively not sensitive to combustion phasing in the range of interest.

This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

Particulate emissions from a production gasoline direct injection spark ignition engine were studied under a typical cold-fast-idle condition (1200 rpm, 2 bar NIMEP). The particle number (PN) density in the 22 to 365 nm range was measured as a function of the injection timing with single pulse injection and with split injection. Very low PN emissions were observed when injection took place in the mid intake stroke because of the fast fuel evaporation and mixing processes which were facilitated by the high turbulent kinetic energy created by the intake charge motion. Under these conditions, substantial liquid fuel film formation on the combustion chamber surfaces was avoided. PN emissions increased when injection took place in the compression stroke, and increased substantially when the fuel spray hit the piston.

The impact of the operating strategy on emissions from the first combustion cycle during cranking was studied quantitatively in a production gasoline direct injection engine. A single injection early in the compression cycle after IVC gives the best tradeoff between HC, particulate mass (PM) and number (PN) emissions and net indicated effective pressure (NIMEP). Retarding the spark timing, it does not materially affect the HC emissions, but lowers the PM/PN emissions substantially. Increasing the injection pressure (at constant fuel mass) increases the NIMEP but also the PM/PN emissions.

A research program designed to measure the contribution from fuel absorption in the thin layer of oil, lubricating the cylinder liner, to the total and speciated HC emissions from a spark ignition engine has been performed. The logic of the experiment design was to test the oil layer mechanism via variations in the oil layer thickness (through the lubricant formulations), solubility of the fuel components in the lubricants, and variations in the crankcase gas phase HC concentration (through crankcase purging). A set of preliminary experiments were carried out to determine the solubility and diffusivity of the fuel components in the individual lubricants. Engine tests showed similar HC emissions among the tested lubricants. No consistent increase was observed with oil viscosity (oil film thickness), contrary to what would be expected if fuel-oil absorption was contributing significantly to engine-out HC. Similarly, no effect of crankcase purging could be observed.

The effects of the directed port flow produced by a Charge-Motion-Control-Valve (CMCV) on mixture preparation in a Port-Fuel-Injection engine were assessed under conditions typical of fast idle in a cold start process. The port fuel was found to comprise two components: a “valve” puddle (at the vicinity of the valve) that built up quickly, and that was mainly responsible for the delivery of the fuel to the cylinder charge; a “port” puddle located significantly upstream. The latter was mainly created by the reverse back flow process and built up slowly. Although the fuel amounts in these two components were roughly the same, the latter did not significantly interact with the fuel transport to the cylinder charge. The CMCV only weakly affected the purging or filling time of the valve puddle, hence the dynamics of the fuel delivery process was not materially affected.

Knock in a HCCI engine was examined by comparing subjective evaluation, recorded sound radiation from the engine, and cylinder pressure. Because HCCI combustion involved simultaneous heat release in a spatially large region, substantial oscillations were often found in the pressure signal. The time development of the audible signal within a knock cycle was different from that of the pressure trace. Thus the audible signal was not the attenuated transmission of the cylinder pressure oscillation but the sound radiation from the engine structure vibration excited by the initial few cycles of pressure oscillation. A practical knock limited maximum load point for the specific 2.3 L I4 engine under test (and arguably for engines of similar size and geometry) was defined at when the maximum rate of cycle-averaged pressure rise reached 5 MPa/ms.

The loss mechanisms associated with engine downsizing, boosting and compression ratio change are assessed. Of interest are the extents of friction loss, pumping loss, and crevice loss. The latter does not scale proportionally with engine size. These losses are deconstructed via a cycle simulation model which encompasses a friction model and a crevice loss model for engine displacement of 300 to 500 cc per cylinder. Boost pressure is adjusted to yield constant torque. The compression ratio is varied from 8 to 20. Under part load, moderate speed condition (1600 rpm; 13.4 Nm/cylinder brake torque), the pumping work reduces significantly with downsizing while the work loss associated with the crevice volume increases. At full load (1600 rpm; 43.6 Nm/cylinder brake torque), the pumping work is less significant. The crevice loss (normalized to the fuel energy) is essentially the same as in the part load case. The sensitivities of the respective loss terms to downsizing are reported.

This paper describes the development of a spark ignition engine operating in a stratified-EGR mode at part load. The concept is to reduce the pumping loss with high levels of EGR while maintaining stable combustion via charge stratification. Since the engine operates stoichiometrically, the ability to control NOx emissions by the three-way catalyst is retained. The configuration of introducing the stoichiometric fresh mixture to the center portion of the combustion chamber with the EGR gas on the two sides is visualized in a transparent engine using planar laser-induced fluorescence (PLIF) and Mie scattering. Visualization results showed that the stratification between air/fuel mixture and EGR gas was relatively well established during the intake stroke. There was, however, significant mixing in the late part of the compression stroke.

The residual gas fraction prior to ignition at the vicinity of the spark plug in a single cylinder, two-valve spark ignition engine was measured with a fast-response flame ionization hydrocarbon detector. The technique in using such an instrument is reported. The measurements were made as a function of the intake manifold pressure, engine speed and intake/exhaust valve-overlap duration. Both the mean level of the residual fraction and the statistics of the cycle-to-cycle variations were obtained.

This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.

To understand the effects of crevices on the engine-out hydrocarbon emissions, a series of engine experiments was carried out with different piston crevice volumes and with simulated head gasket crevices. The engine-out HC level was found to be modestly sensitive to the piston crevice size in both the warmed-up and the cold engines, but more sensitive to the crevice volume in the head gasket region. A substantial decrease in HC in the cold-to-warm-up engine transition was observed and is attributed mostly to the change in port oxidation.

A method for determining the flame contour based on the flame arrival time at the fiber optic (FO) spark plug and at the head gasket ionization probe (IP) locations has been developed. The experimental data were generated in a single-cylinder Ricardo Hydra spark-ignition engine. The head gasket IP, constructed from a double-sided copper-clad circuit board, detects the flame arrival time at eight equally spaced locations at the top of the cylinder liner. Three other IP's were also installed in the cylinder head to provide additional intermediate data on flame location and arrival time. The FO spark plug consists of a standard spark plug with eight symmetrically spaced optical fibers located in the ground casing of the plug. The cylinder pressure was recorded simultaneously with the eleven IP signals and the eight optical signals using a high-speed PC-based data acquisition system.

The effect of engine operating parameters (speed, spark timing, and fuel-air equivalence ratio [Φ]) on hydrocarbon (HC) oxidation within the cylinder and exhaust system is examined using propane or isooctane fuel. Quench gas (CO2) is introduced at two locations in the exhaust system (exhaust valve or port exit) to stop the oxidation process. Increasing the speed from 1500 to 2500 RPM at MBT spark timing decreases the total, cylinder-exit HC emissions by ∼50% while oxidation in the exhaust system remains at 40% for both fuels. For propane fuel at 1500 rpm, increasing Φ from 0.9 (fuel lean) to 1.1 (fuel rich) reduces oxidation in the exhaust system from 42% to 26%; at 2500 RPM, exhaust system oxidation decreases from 40% to approximately 0% for Φ = 0.9 and 1.1, respectively. Retarded spark increases oxidation in the cylinder and exhaust system for both fuels. Decreases in total HC emissions are accompanied by increased olefinic content and atmospheric reactivity.

A reciprocating test apparatus was constructed in which the friction of a single piston ring against a liner segment was measured. The lubrication oil film thickness was also measured simultaneously at the mid stroke of the ring travel using a laser fluorescence technique. The apparatus development and operation are described. Results are presented from a test matrix consisting of five different lubrication oils of viscosity (at 30°C) ranging from 49 to 357 cP; at three mean piston speeds of 0.45, 0.89 and 1.34 m/s; and at three ring normal loading of 1.4, 2.9 and 5.7 MPa. At mid stroke, the oil film thickness under the ring was ∼0.5 to 4 μm; the frictional coefficient was ∼0.02 to 0.1. The frictional coefficient for all the lubricants tested increased with normal load, and decreased with piston velocity. Both mixed and hydrodynamic lubrication regimes were observed. The friction behaviors were consistent with the Stribeck diagram.

The fuel effects on throttle transients in PFI spark ignition engines were assessed through experiments with simultaneous step change of the throttle position from part load to WOT and increment of the injected fuel amount. The test matrix consisted of various gasoline/methanol blends from pure gasoline to pure methanol, coolant temperatures at 40C (for cold engine condition) and 80C (for warm engine), and different levels of fuel enrichment at the WOT condition. The x-τ model was used to interpret the engine GIMEP response in the transient. Using the model, a procedure was developed to calculate the parameters of the transient from the data. These parameters were systematically regressed against the fuel distillation points, the increment in injected fuel mass in the transient, and the enthalpy required to evaporate the fuel increment as the explanatory variables.

A strategy to facilitate the mixture preparation process in PFI engines is to delay the Intake Valve Opening (IVO) by shifting the cam phasing so that the cylinder pressure is sub-atmospheric when the valve opens. The physics of the effect are discussed in terms of the pressure differential between the manifold and the cylinder, and the resulting flow and charge temperature history. The effect was evaluated by measuring the equivalence ratio of the trapped charge and the exhaust HC emissions in the first cycle of cranking in a 2.4L engine. When the IVO timing was changed from 18° BTDC to 21° ATDC, the in-cylinder fuel equivalence ratio increased by approximately 10%. This increase was attributed mainly to the enrichment of the charge by displacing the leaner mixture at the top of the cylinder in the period between BDC and IVC. The exhaust HC, however, increased by 40%. No conclusive explanation was established for this increase in HC emissions.

The fuel property effects on first cycle mixture preparation were assessed by measuring the in-cylinder fuel equivalence ratio (Φ) with a Fast Flame Ionization Detector (FFID) using four different fuels. The Engine Coolant Temperature (ECT) was varied between -6°C and 80°C. The Φ values increased with both ECT and amount of injected fuel mass. The delivery fraction (fraction of the injected fuel that went into the combustible charge), however, increased with ECT but decreased with increase in injected fuel. The minimum required injected mass to produce a combustible mixture increased sharply with decrease in ECT below 20°C. There was, however, no single fuel parameter that would correlate with the measurements over the entire temperature range. Instead, the minimum required injected mass correlated to different distillation points on the ASTM distillation curve; e.g. at ECT of -6°C, it correlated to T20; at 40°C, it correlated to T50.