Search Results

The use of catalyzed diesel particulate filter (CDPF) systems in light duty diesel (LDD) vehicles is becoming increasingly common. The primary functions of the system are to remove carbon monoxide (CO) and hydrocarbons (HC) from the vehicle exhaust stream, while simultaneously reducing the level of particulate matter (PM) emissions to ambient background levels. These systems can comprise either a separate diesel oxidation catalyst (DOC) and a downstream CDPF, or a single unit CDPF with the DOC functions incorporated within the CDPF. The single CDPF unit provides higher regeneration efficiency as it is located nearer to the engine and also cost benefits, as only a single unit is required compared to the alternative separate DOC and CDPF arrangement. A model describing the performance of the single unit CDPF for emissions control has been developed, with particular emphasis on achieving predictions of the CO and HC emissions over transient vehicle drive cycles.

Diesel Particulate Filters (DPF) are widely used to meet 2007 and beyond EPA Particulate Matter (PM) emissions requirements. During the soot loading process, soot is collected inside a porous wall and eventually forms a soot cake layer on the surface of the DPF inlet channel walls. A densely packaged soot layer and reduced pore size due to Particulate Matter (PM) deposition will reduce overall DPF wall permeability which results in increasing pressure drop across the DPF substrate. A regeneration process needs to be enacted to burn out all the soot collected inside the DPF. Soot mass is not always evenly distributed as the distribution is affected by the flow and temperature distribution at the DPF inlet. As a result, the heat release which is determined by the burn rate is locally dependent. High temperature gradients are often found inside DPF substrate as a result of these locally dependent burn rates.

The upcoming Euro VI emission legislation for Heavy Duty Diesel engines can be complied with by using a combination of a wall flow DPF and a UREA SCR-system. This paper describes investigations of NOx and PM reduction by a combination of SCR-catalyst and an (uncoated) Diesel particulate filter (DPF), performed on a fully transient heavy-duty test bench. Soot loading and passive regeneration of the DPF for different configurations of both components and active regeneration by fuel injection into the exhaust gas line were investigated. The impact of DPF on SCR-catalyst as well as SCR-catalyst impact on DPF was analyzed in terms of NOx-conversion and regeneration efficiency of the filter under steady-state and transient operating conditions. The NOx-conversions for the configuration SCR-catalyst in front of DPF were higher for all operating conditions than for the combination DPF in front of SCR-catalyst.

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as effective for controlling NOx emissions from diesel engines, maintaining high NOx conversion even after the extended high temperature exposure encountered in systems with active filter regenerations. As future diesel emission regulations are expected to be further reduced, packaging a large volume of SCR catalysts in diesel exhaust systems, along with DOC and particulate filter catalysts, will be challenging. One method to reduce the total volume of catalysts in diesel exhaust systems is to combine the SCR and DPF catalysts by coating SCR catalyst technology on particulate filters. In this work, engine evaluation of SCR coated filters has been conducted to determine the viability of the technology. Steady-state engine evaluations demonstrated that high NOx conversions can be achieved for SCR coated filters after high temperature oven aging.

Selective Catalytic Reduction (SCR) catalysts have been designed to reduce NOx with the assistance of an ammonia-based reductant. Diesel Particulate Filters (DPF) have been designed to trap and eventually oxidize particulate matter (PM). Combining the SCR function within the wall of a high porosity particulate filter substrate has the potential to reduce the overall complexity of the aftertreatment system while maintaining the required NOx and PM performance. The concept, termed Selective Catalytic Reduction Filter (SCRF) was studied using a synthetic gas bench to determine the NOx conversion robustness from soot, coke, and hydrocarbon deposition. Soot deposition, coke derived from propylene exposure, and coke derived from diesel fuel exposure negatively affected the NOx conversion. The type of soot and/or coke responsible for the inhibited NOx conversion did not contribute to the SCRF backpressure.

Honda has succeeded in developing the new fuel cell (FC) vehicle designed into a dynamic, full-cabin sedan, the FCX Clarity, originating from the new V Flow FC platform. The key technology is V Flow FC Stack, featuring V Flow cell structure in which the fuel gases run from top to bottom vertically through the wave flow-channels. According to this unique structure, the fuel cell stack sits longitudinally along the center tunnel, and a Vertebral layout has emerged. The Vertebral layout results in Volume efficient package and low-floor platform. The V Flow FC stack has achieved a high output of 100kW and improved the output density with 50% by volume and 67% by mass, compared to the previous 2005 model. The V Flow cell structure utilizes gravity for water drainage and reduces the channel depth creating thinner cells. The wave-shaped vertical gas flow channel provides horizontal and more efficient coolant flow distribution allowing the reduction of the number of cooling layer.

This paper reports an active heat sink (AHS) that allows high-density electronic components to operate at a stable temperature over a broad range of ambient conditions. AHS receives heat at high flux and transfers it at reduced flux to environment, coolant fluid (e.g., air or engine coolant), or structures. Temperature of the heat load can be controlled electronically. Target applications for AHS include thermal management of the new class of high-power electronics being developed for electric hybrid vehicles. AHS also enables precise control over junction temperature (and, thus, light color) of high-power light-emitting diodes (LED) used for solid-state headlights and allows for compact air-cooled heat sinks. Depending on the configuration, AHS thermal resistance can be as low as 0.1 degC/W. AHS physics, engineering design, and performance simulations are presented.

The Space Suit Water Membrane Evaporator (SWME) is a baseline heat rejection technology that was selected to develop the Constellation Program lunar suit. The Hollow Fiber (HoFi) SWME is being considered for service in the Constellation Space Suit Element Portable Life Support Subsystem to provide cooling to the thermal loop via water evaporation to the vacuum of space. Previous work [1] described the test methodology and planning that are entailed in comparing the test performance of three commercially available HoFi materials as alternatives to the sheet membrane prototype for SWME: (1) porous hydrophobic polypropylene, (2) porous hydrophobic polysulfone, and (3) ion exchange through nonporous hydrophilic-modified Nafion®.

The Mars Science Laboratory (MSL) mission to land a large rover on Mars is being prepared for Launch in 2011. A Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) on the rover provides an electrical power of 110 W for use in the rover and the science payload. Unlike the solar arrays, MMRTG provides a constant electrical power during both day and night for all seasons (year around) and latitudes. The MMRTG dissipates about 2000 W of waste heat to produce the desired electrical power. One of the challenges for MSL Rover is the thermal management of the large amount of MMRTG waste heat. During operations on the surface of Mars this heat can be harnessed to maintain the rover and the science payload within their allowable limits during nights and winters without the use of electrical survival heaters. A mechanically pumped fluid loop heat rejection and recovery system (HRS) is used to pick up some of this waste heat and supply it to the rover and payload.

An advanced exhaust aftertreatment system is characterized following end-of-life catalyst aging to meet final Tier 4 off-highway emission requirements. This system consists of a fuel dosing system, mixing elements, fuel reformer, lean NOx trap (LNT), diesel particulate filter (DPF), and a selective catalytic reduction (SCR) catalyst. The fuel reformer is used to generate hydrogen (H2) and carbon monoxide (CO) from injected diesel fuel. These reductants are used to regenerate and desulfate the LNT catalyst. NOx emissions are reduced using the combination of the LNT and SCR catalysts. During LNT regeneration, ammonia (NH3) is intentionally released from the LNT and stored on the downstream SCR catalyst to further reduce NOx that passed through the LNT catalyst. This paper addresses system durability as the catalysts were aged to 500 desulfation events using an off-highway diesel engine.

A diesel particulate filter (DPF) controls and maintains a constant pressure drop across the filter by repeating the regeneration process for PM (Particulate Matter). However, the regeneration results in ash accumulation on the DPF. Although this ash accumulation is very slow, it eventually causes increased pressure drop which affects the product life of the DPF. Metal elements in the lubricant additives in the engine oil are the source of the ash. Since ash is an oxidized substance, the amount of ash produced depends on such factors as the amount of oil consumed in the engine and the kinds of lubricant additives contained in engine oil. According to the reference literature [1-3], ash accumulates on a DPF differently depending on use of either a passive regeneration system or an active regeneration system. With the passive regeneration system, ash accumulates uniformly on the filter wall while ash accumulates near the outlet of the filter with the active regeneration system.

The commercial turbofan trend of increasing bypass ratio and decreasing fan pressure ratio has seen its latest market entry in Pratt & Whitney's PurePower™ product line, which will power regional aircraft for the Bombardier and Mitsubishi corporations, starting in 2013. The high-bypass-ratio, low-fan-pressure-ratio trend, which is aimed at diminishing noise while increasing propulsive efficiency, combines with contemporary business factors including the escalating cost of testing and limited availability of simulated altitude test sites to pose formidable challenges for engine certification and performance validation. Most fundamentally, high bypass ratio and low fan pressure ratio drive increased gross-to-net thrust ratio and decreased fan temperature rise, magnifying by a factor of two or more the sensitivity of in-flight thrust and low spool efficiency to errors of measurement and assumption, i.e., physical modeling.

This paper reports on a field test with 23 Volvo D12C non-exhaust gas recirculation diesel engines using the Diesel Particulate Filter (DPF), Selective Catalytic Reduction (SCR), and urea system with Ultra-Low-Sulfur-Diesel (ULSD). This combination will be used to meet the on-highway emission standards for U.S. 2010, Japan 2010, and Europe 2013. Because of future widespread use of DPF-SCR, this study reports on our field experience with this system, and focuses on enhancing our understanding of the incombustible materials which are collected in the DPF with API CJ-4 and API CI-4 PLUS oils. The average weight of incombustibles was lower in the trucks using API CJ-4 oils at 1.0% sulfated ash, than in those using API CI-4 PLUS oils at 1.4% sulfated ash. The difference in weight between the two groups was highly significant. Further, the weight of the incombustibles per kilometer substantially decreased with each subsequent cleaning within a truck.

The volatile organic compounds (VOC) from diesel engines, including formaldehyde and benzene, are concerned and remain as unregulated harmful substances. The substances are positively correlated with THC emissions, but the VOC and aldehyde compounds at light load or idling conditions are more significant than THC. When coolant temperatures are low at light loads, there are notable increases in formaldehyde and acetaldehyde, and with lower coolant temperatures the increase in aldehydes is more significant than the increase in THC. When using ultra high EGR so that the intake oxygen content decreases below 10%, formaldehyde, acetaldehyde, benzene, and 1,3-butadiene increase significantly while smokeless and ultra low Nox combustion is possible.

Diesel engine ash emissions are composed of the non-combustible portions of diesel particulate matter derived mainly from lube oil, and over time can degrade diesel particulate filter performance. This paper presents results from a high temperature oxidation method (HTOM) used to estimate ash emissions, and engine oil consumption in real-time. Atomized lubrication oil and diesel engine exhaust were used to evaluate the HTOM performance. Atomized fresh and used lube oil experiments showed that the HTOM reached stable particle size distributions and concentrations at temperatures above 700°C. The HTOM produced very similar number and volume weighted particle size distributions for both types of lube oils. The particle number size distribution was unimodal, with a geometric mean diameter of about 23 nm. The volume size distribution had a geometric volume mean diameter of about 65 nm.

The paper will discuss the design and development of heavy-duty diesel engines to meet the US EPA 2010 on-highway standards - 0.2 g/HP-hr NOx and 0.01 g/HP-hr particulate matter (PM). In meeting these standards a combination of in-cylinder control and aftertreatment control for both NOx and particulate has been used. For NOx control, a combination of cooled exhaust gas recirculation (EGR) and selective catalytic reduction (SCR) is used. The SCR catalyst uses copper zeolite to achieve high levels of NOx conversion efficiency with minimal ammonia slip and unparalleled thermal durability. For particulate control, a diesel particulate filter (DPF) with upstream oxidation catalyst (DOC) is used. While the DPF may be actively regenerated when required, it operates predominantly with passive regeneration - enabled by the high NOx levels between the engine and the DPF, associated with high efficiency SCR systems and NO₂ production across the DOC.

Diesel exhaust aftertreatment systems are required for meeting both EPA 2010 and final Tier 4 emission regulations while meeting the stringent packaging constraints of the vehicle. The aftertreatment system for this study consists of a fuel dosing system, mixing elements, fuel reformer, lean NOx trap (LNT), diesel particulate filter (DPF), and a selective catalytic reduction (SCR) catalyst. The fuel reformer is used to generate hydrogen (H₂) and carbon monoxide (CO) from injected diesel fuel. These reductants are used to regenerate and desulfate the LNT catalyst. NOx emissions are reduced using the combination of the LNT and SCR catalysts. During LNT regeneration, ammonia (NH₃) is intentionally released from the LNT and stored on the downstream SCR catalyst to further reduce NOx that passed through the LNT catalyst. This paper addresses system packaging and exhaust flow optimization for heavy-duty line-haul and severe service applications.

Biodiesel-blended fuel is increasingly becoming available for diesel engines. Due to seasonal and economic factors, biodiesel available in filling stations can be sourced from varying feedstocks. Moreover, biodiesel may not contain the minimum oxidative stability required by the time it is used by the automotive consumer. With fuel dilution of engine oil accelerated by post-injection of fuel for regeneration of diesel particulate filters, it is necessary to investigate whether different biodiesel feedstocks or stabilities can affect engine oil properties. In this work, SAE 15W-40 CJ-4 is diluted with B20 fuel, where the B20 was prepared with soy methyl ester (SME) B100 with high Rancimat oxidative stability, SME B100 with low oxidative stability, and lard methyl ester (LME). The oils were then subjected to laboratory aging simulating severe drive cycles. At intermediate aging times, samples were obtained and additional B20 was added to simulate on-going fuel dilution.

In cold climatic regions (25°C below zero) thermal comfort inside vehicle cabin plays a vital role for safety of driver and crew members. This comfortable and safe environment can be achieved either by utilizing available heat of engine coolant in conjunction with optimized in cab air circulation or by deploying more costly options such as auxiliary heaters, e.g., Fuel Fired, Positive Temperature Coefficient heaters. The typical vehicle cabin heating system effectiveness depends on optimized warm/hot air discharge through instrument panel and foot vents, air directivity to occupant's chest and foot zones and overall air flow distribution inside the vehicle cabin. On engine side it depends on engine coolant warm up and flow rate, coolant pipe routing, coolant leakage through engine thermostat and heater core construction and capacity.

A 2005 prototype diesel aftertreatment system consisting of diesel oxidation catalysts (DOC), Cu/zeolite Selective Catalytic Reduction (SCR) catalyst, and Catalyzed Diesel Particulate Filter (CDPF) was aged to an equivalent of 120k mi on an engine dynamometer using an aging cycle that incorporated both city and highway driving modes. The program demonstrated durable reduction in particulate matter (PM) and nitrogen oxides (NOx) emissions to federal Tier 2 levels on a 6000 lbs light-duty truck application. Very low sulfur diesel fuel (∼15 ppm) enabled lower PM emissions, reduced the fuel penalty associated with the emission control system, and improved long-term system durability. A total of 643 filter regenerations occurred during the aging that raised the entire catalyst system to high temperatures on a regular basis. After testing the aged system on a 6000 lbs light-duty diesel truck, a post mortem analysis was completed on core samples taken from the DOC, SCR catalyst, and filter.