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A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

As a result of recommendation from the Augustine Panel, the direction for Human Space Flight has been altered from the original plan referred to as Constellation. NASA's Human Exploration Framework Team (HEFT) proposes the use of a Shuttle Derived Heavy Lift Launch Vehicle (SDLV) and an Orion derived spacecraft (salvaged from Constellation) to support a new flexible direction for space exploration. The SDLV must be developed within an environment of a constrained budget and a preferred fast development schedule. Thus, it has been proposed to utilize existing assets from the Shuttle Program to speed development at a lower cost. These existing assets should not only include structures such as external tanks or solid rockets, but also the Flight Software which has traditionally been a ?long pole? in new development efforts. The avionics and software for the Space Shuttle was primarily developed in the 70's and considered state of the art for that time.

The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon

In this project funded by the Bayerische Forschungsstiftung two fundamental investigations had been carried out: first a new N-rich liquid ammonia precursor solution based on guanidine salts had been completely characterized and secondly a new type of side-flow reactor for the controlled catalytic decomposition of aqueous NH3 precursor to ammonia gas has been designed, applied and tested in a 3 liter passenger car diesel engine. Guanidine salts came into the focus due to the fact of a high nitrogen-content derivate of urea (figure 1). Specially guanidinium formate has shown extraordinary solubility in water (more than 6 kg per 1 liter water at room temperature) and therefore a possible high ammonia potential per liter solution compared to the classical 32.5% aqueous urea solution (AUS32) standardized in ISO 22241 and known as DEF (diesel emission fluid), ARLA32 or AdBlue®. Additionally a guanidine based formulation could be realized with high freezing stability down to almost ?30 °C (?

Topics include the effects of fuel and additives on deposit formation, intake system cleanliness, friction, wear, corrosion, and elastomer compatibility. Also covered are effects of fuel specification on drivability, on evaporative emissions, and on the relationship between emissions and drive cycle.

Abstract The current investigation studies the microstructure and high-temperature hot corrosion behavior of plasma-sprayed coatings. The composition of Fe17Cr2Ni0.18C and fly ash cenosphere powder is maintained in the 0%, 5%, 10%, and 15% ratio by weight percent, respectively. Both powder mixtures were thoroughly blended correspondingly and coated on T22 boiler steel tubings. Thermocyclic hot corrosion studies were examined in a liquid salt condition of Na2SO4—60% V2O5 for 17 cycles of 51 h at 600°C on bare and coated steels. Thermogravimetric practice was used to establish the kinetics of hot corrosion of uncoated and coated steels. As-coated samples are studied for microstructure and microhardness. X-ray diffraction (XRD), scanning electron microscopy (SEM)/energy-dispersive spectroscopy, and X-ray mapping characterization techniques have been utilized for structural analysis of the as-coated and hot-corroded samples.

Abstract Automotive-grade high-strength steels are galvanized for improved corrosion resistance. However, selective oxidation of alloying elements during annealing heat-treatment may influence the subsequent zinc (Zn) coating quality. The formation of internal and external oxides depends on the alloy composition, especially the Si/Mn ratio, and the oxygen potential of the annealing atmosphere. In this work, a dual-phase (DP) steel was intercritically annealed with varied fuel-to-air ratios in a direct-fired furnace and then galvanized in a Zn bath with 0.2 wt% Al. The type of internal and external oxides and the interfacial structures between the steel substrate, the Al-Fe-Zn inhibition layer, and the Zn coating were examined by using site-specific focused ion beam (FIB) and transmission electron microscopy (TEM).

Abstract The use of Abrasive Water Jet (AWJ) cutting technology can improve the edge stretchability in sheet metal forming. The advances in technology have allowed significant increases in working speeds and pressures, reducing the AWJ operation cost. The main objective of this work was to determine the effect of selected AWJ cutting parameters on the Hole Expansion Ratio (HER) for a DP800 (Dual-Phase) Advanced High-Strength Steel (AHSS) with s0 = 1.2 mm by using a fractional factorial design of experiments for the Hole Expansion Tests (HET). Additionally, the surface roughness and residual stresses were measured on the holes looking for a possible relation between them and the measured HER. A deep drawing quality steel DC06 with s0 = 1.0 mm was used for reference. The fracture occurrence was captured by high-speed cameras and by Acoustic Emissions (AE) in order to compare both methods.

The local equivalence ratio, Φ, was measured in fuel jets using laser-induced spontaneous Raman scattering in an optical heavy duty diesel engine. The measurements were performed at 1200 rpm and quarter load (6 bar IMEP). The objective was to study factors influencing soot formation, such as gas entrainment and lift-off position, and to find correlations with engine-out particulate matter (PM) levels. The effects of nozzle hole size, injection pressure, inlet oxygen concentration, and ambient density at TDC were studied. The position of the lift–off region was determined from OH chemiluminescence images of the flame. The liquid penetration length was measured with Mie scattering to ensure that the Raman measurement was performed in the gaseous part of the spray. The local Φ value was successfully measured inside a fuel jet. A surprisingly low correlation coefficient between engine-out PM and the local Φ in the reaction zone were observed.

Recent measurements in transient diesel jets have shown that fuel in the wake of the injection pulse mixes with ambient gases more rapidly than in a steady jet. This rapid mixing after the end of injection (EOI) can create fuel-lean regions near the fuel injector. These lean regions may not burn to completion for conditions where autoignition occurs after EOI, as is typical of low-temperature combustion (LTC) diesel engines. In this study, transient diesel jets are analyzed using a simple one-dimensional jet model. The model predicts that after EOI, a region of increased entrainment, termed the “entrainment wave,” travels downstream at twice the initial jet propagation rate. The entrainment wave increases mixing by up to a factor of three. This entrainment wave is not specific to LTC jets, but rather it is important for both conventional diesel combustion and LTC conditions.

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

The materials defined by this U.S. CAR / S.A.E Recommended Practice are low VOC water based coatings for automotive tooling and general maintenance.

The present paper describes an experimental study on the application of a Low Pressure EGR system, equipped with an high efficiency cooler, to a LD diesel engine operating with both conventional combustion and PCCI mode. The research activity is aimed to carry out an analysis of the potentiality of the cooling (with engine water at 90°C) and super-cooling (with external water at 20°C) of the low pressure EGR flow gas on the simultaneous reduction of fuel consumption and pollutant emissions. The effects were evaluated running the engine with diesel conventional combustion and PCCI mode in several engine operating points. The employed engine was a 4-cyliders LD CR diesel engine of two liters of displacement at the state of art of the current engine technology. The overall results identified benefits on both the fuel consumption and emissions with the use of a low pressure EGR system with respect to the “classical” high pressure EGR one.

The physical and optical properties viz., water absorption pattern, density, color and opacity of oil palm fiber-LLDPE composites were studied. The effect of fiber size, fiber loading and fiber treatment on the above parameters was also studied. Alkali treatment on fibers was done to reduce the hydrophilic nature of composites. It was found that the water absorption in most of the combinations followed typical fickian behavior. The rate of water absorption and swelling increased with fiber loading. However alkali treatment on fibers resulted in reduction of water absorption at higher fiber loading only and composites with higher fiber size exhibited higher water absorption. True density of oil palm fiber-LLDPE composites were in the range of 967-1177 kg m-₃, whereas the bulk density ranged from 942-1122 kg m-₃. The dielectric constant of the composite was in the range of 3.22 to 6.73.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

To meet increasingly stringent diesel exhaust emissions requirements, original equipment manufacturers (OEMs) have introduced common rail fuel injection systems that develop pressures of up to 2000 bar (30,000 psi). In addition, fuel delivery schemes have become more complicated, often involving multiple injections per cycle. Containing higher pressures and allowing for precise metering of fuel requires very tight tolerances within the injector. These changes have made injectors more sensitive to fuel particulate contamination. Recently, problems caused by internal diesel injector deposits have been widely reported. In this paper, the results of an investigation into the chemical nature and probable sources of these deposits are discussed. Using an array of techniques, internal deposits were analyzed from on a number of sticking injectors from the field and from OEM test stands in North America.

The post-flame oxidation of unburned hydrocarbons released from the ring-pack crevice was investigated for a small, air-cooled, spark-ignition utility engine. Spark timing sweeps were performed at 50, 75 and 100% load and speeds of 1800, 2400 and 3060 RPM while operating at a 12:1 air-fuel ratio, which is typical for these engines. A global HC consumption rate (GCR) was introduced based on the temporal profile of the mass released from the ring pack; the mass release after CA90 and up to the point where the remainder of the ring pack HC mass is equal to the exhaust HC level was taken as the mass oxidized, and a rate was defined based on this mass and the corresponding crank angle period over which this took place. For all conditions tested, the GCR varied with the spark timing; advanced spark timing gave higher GCR.

Organic acid degradation products and other anions in engine oil were speciated by capillary electrophoresis (CE) and liquid chromatography-mass spectrometry (LCMS) with electrospray ionization. The sample preparation procedure involved selectively extracting the acids and other water soluble salts into 0.05M aqueous potassium hydroxide. Samples of engine-aged mineral oil and synthetic engine oil contained formic acid, acetic acid, and complex mixtures of fatty acid degradation products. CE analysis of formic acid, acetic acid and selected fatty acids is proposed as a new chemical analysis method for evaluating the condition of engine oil and for studying the effects of high temperature-high load (HTHL) oxidation. Because the overall pattern of CE peaks in the electropherogram changes with oil age or condition, CE-fingerprint (i.e., pattern recognition) techniques may also be useful for evaluating an aged oil's condition or remaining service life.

Al383/SiO₂ metal matrix composites (MMC) were designed to increase the wear properties of the Al alloy. However, the soft Al matrix was subject to large plastic deformation under high normal load during lubricated sliding wear tests, causing detachment of the reinforced particles. To further increase the wear resistance of the MMC, in this research, Plasma Electrolytic Oxidation (PEO) process was used to form oxide coatings on the MMC. The hard and wear-resistant oxide coatings protected the metal matrix during the wear tests, reducing the wear rate of MMC. The effect of both oxide coating thickness and volume content of SiO₂ particles on the wear behavior of MMC was investigated. It was found that with a proper combination of the volume content of SiO₂ and coating thickness, the MMC exhibited high wear resistance and low friction coefficient.

A simulation technology has been developed to enable prediction of galvanic corrosion in chassis parts where two different materials, iron and aluminum, come into contact with each other. When polarization curves representing a corrosive environment are input, this simulation technology calculates the corrosion current to flow and outputs the volume of aluminum corrosion to be formed near the iron-aluminum interface. The simulation makes it possible to predict the depth of corrosion that may occur in automobiles in the market.