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Today's biofuels require large amounts of energy in the production process for the conversion from biomass into fuels with conventional properties. To reduce the amounts of energy needed, future fuels derived from biomass will have a molecular structure which is more similar to the respective feedstock. Butyl levulinate can be gained easily from levulinic acid which is produced by acid hydrolysis of cellulose. Thus, the Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of this biofuel compound, as a candidate for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. Previous investigations identified most desirable fuel properties like a reduced cetane number, an increased amount of oxygen content and a low boiling temperature for compression ignition engine conditions.

Fuels derived from biomass will most likely contain oxygen due to the high amount of hydrogen needed to remove oxygen in the production process. Today, alcohol fuels (e. g. ethanol) are well understood for spark ignition engines. The Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of alcohol fuels as candidates for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. The soot formation and oxidation process when using alcohol fuels in diesel engines is not yet sufficiently understood. Depending on the chain length, alcohol fuels vary in cetane number and boiling temperature. Decanol possesses a diesel-like cetane number and a boiling point in the range of the diesel boiling curve. Thus, decanol was selected as an alcohol representative to investigate the influence of the oxygen content of an alcohol on the combustion performance.

Homogeneous charge compression ignition (HCCI) is a part load, low-temperature combustion process which operates at lean mixtures and produces ultra-low NOX emissions. As opposed to SI engines that use a spark to control combustion timing, HCCI combustion is enabled by compression induced autoignition which is characterized by rapid global and spatial combustion yielding fuel efficiency benefits. This process is highly dependent on the in-cylinder state, including pressure, temperature and trapped mass. The absence of a direct combustion control proves to be a major challenge and results in unstable engine operation especially at the limits of the narrow operation range. In recent studies, direct water injection is used in HCCI combustion to stabilize combustion and increase the operation range. This paper outlines the thermodynamic influence and evaluation of the potential of water injection for HCCI combustion.