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There is a possibility that trace contaminants in the Shuttle Orbiter cabin atmosphere may chemically react with amine beads found in the Regenerative Carbon Dioxide Removal System and degrade system performance. Two contaminant compounds were exposed to the amine beads, and performance changes were measured. Acetone was tested because it is sometimes found in small but appreciable quantities in the cabin, and it has chemical properties that make it a potential poison. Halon 1301 was tested because it is the fire extinguishant, and a discharge of a Halon canister would trigger high concentrations in the cabin. Acetone was shown to be weakly and reversibly adsorbed. It does not poison the bed, and the RCRS was shown to remove small quantities of acetone. Halon was shown to be inert to the amine. It does not poison the RCRS, and is not removed by the RCRS.

Recent efforts have been pursued to establish the usefulness of Space Shuttle Orbiter lithium hydroxide (LiOH) canisters beyond their certified two-year shelf life, at which time they are currently considered “expired.” A stockpile of Orbiter LiOH canisters are stowed on the International Space Station (ISS) as a backup system for maintaining ISS carbon dioxide Canisters with older (CO2) control. Canister with older pack dates must routinely be replaced with newly packed canisters off-loaded from the Orbiter Middeck. Since conservation of upmass is critical for every mission, the minimization of canister swap-out rate is paramount. LiOH samples from canisters with expired dates that had been returned from the ISS were tested for CO2 removal performance at the NASA Johnson Space Center (JSC) Crew and Thermal Systems Division (CTSD). Through this test series and subsequent analysis, performance degradation was established.