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This study explores the use of two conventional ignition improvers, 2-ethylhexyl nitrate (EHN) and di-tert-butyl peroxide (DTBP), to enhance the autoignition of the regular gasoline in an homogeneous charge compression ignition (HCCI) engine at naturally aspirated and moderately boosted conditions (up to 180 kPa absolute) with a constant engine speed of 1200 rpm. The results showed that both EHN and DTBP are very effective for reducing the intake temperature (Tin) required for autoignition and for enhancing stability to allow a higher charge-mass fuel/air equivalence ratio (ϕm). On the other hand, the addition of these additives can also make the gasoline too reactive at some conditions, so significant exhaust gas recirculation (EGR) is required at these conditions to maintain the desired combustion phasing. Thus, there is a trade-off between improving stability and reducing the oxygen available for combustion when using ignition improvers to extend the high-load limit.