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Due to the stringent requirements to reduce the tail pipe emissions of NOx, Selective Catalytic Reduction (SCR) systems are used to remove NOx using ammonia. When a urea solution is injected into the exhaust system, urea will undergo hydrolysis and decomposition reaction that produces ammonia. At the catalyst surface, ammonia will react with the exhaust gases to convert NOx into nitrogen, N2 and water, H2O. One of the challenging problems is to make sure the urea solution is available for the SCR system at cold start conditions. At extreme cold temperatures, the urea solution will begin to freeze at −12°C. At the start up of a vehicle under such low ambient temperatures, a heating system is used to provide the heat required for melting the frozen urea. Therefore, there will be a time lag between the vehicle start up and the availability of urea solution to the SCR system.

Automotive thermal protection is one of the key areas in the vehicle development process. Critical decisions are usually based on temperature measurement during vehicle testing. Thermocouples are most widely used to determine the temperature of each component during specific test cycle. Therefore, the reliability and accuracy of the thermocouple measurements are of significant importance to the design and release engineers. Errors associated with temperature measurements of automotive components may be caused by radiation from exhaust surfaces such as exhaust manifold, catalytic converter, muffler or exhaust pipes. Other sources of error may be caused by the effect of ambient temperature or airflow if thermocouples are not properly installed. Several errors could arise from the attachment method of the thermocouple to the component or material of interest.

During initial phases of vehicle development process, it is usually required to understand the temperature profile for all components. It is usually more effective and less costly if the thermal issues are determined and addressed before actual vehicles are built. Computational Fluid Dynamics (CFD) analysis tools are typically used for thermal management of the vehicle environment. However, for transient thermal analysis problems, running a full CFD requires solving the mass, momentum, and energy equations. This typically requires a lengthy computation time and extensive computer resources. The problem becomes more challenging when trying to conduct CFD analysis for several design iterations and for different duty cycles that may be of a transient nature. Therefore, the application of one-dimensional analysis early in the development phase can help point out the areas of prime concern.

This paper describes the development of an engineering analysis tool that assesses the life of vehicle components, after exposure to heat. As a standard engineering practice, each component or part of a component has a “long term” and a “short term” temperature goal based on the part’s material physical properties. At higher temperatures, component’s physical properties degrade at a faster rate, and the component’s useful life can be significantly reduced. The extent of degradation depends upon the duration of exposure, the magnitude of the over-temperature and rate of thermal degradation. This tool utilizes actual vehicle test data from test cells or road testing, material physical properties, and expected vehicle duty cycle to determine the expected component life. When component temperature goals are exceeded, the software calculates the total duration of time above the goal temperature.

A fundamental problem in the development of automotive thermal protection strategies is the understanding of the effect of time and temperature on vehicle components life and their performance throughout the life of the vehicle. Due to restrictions on emissions and the stringent requirements for improved fuel economy, the use of polymers and synthetic materials has been widely adopted in automotive applications. It is therefore critical to develop a process to estimate life of engineering materials based on thermal testing and material physical properties. While a series of carefully selected vehicle tests can determine components temperatures during different testing conditions, a need still exists to determine the expected component life and performance throughout the life of the vehicle. Kinetic models have been widely used, in literature, to determine the aging of polymeric and composite materials over time.