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A methodology for simulating effect of international variations in fuel compositions on spray combustion is proposed. The methodology is validated with spray combustion experiments with real fuels from three different countries. The compositions of those fuels were analyzed through GC×GC and H-NMR. It was found that ignition delay times, flame region and flame luminosity were significantly affected by the compositional variations. For the simulation, an evaporation surrogate consisting of twenty two species, covering basic molecular types and a wide range of carbon numbers, is developed. Each species in the evaporation surrogate is then virtually converted to a reaction surrogate consisting of n-hexadecane, methylcyclohexane and 1,2,4-trimethyl benzene so that combustion reactions can be calculated with a published kinetic model. The virtual species conversion (VSC) is made so as to take over combustion-related properties of each species of evaporation surrogates.

With the global adoption of diesel common rail systems and the wide variation in composition of local commercial fuels, modern fuel injection systems must be robust against diverse fuel properties. To bridge the knowledge gap on the effects of compositional variation for real commercial fuels on spray combustion characteristics, the present work quantifies ignition and soot formation/oxidation in three unique, international diesel blends. Schlieren imaging, excited-state hydroxyl radical (OH*) chemiluminescence imaging and diffused back-illumination extinction imaging were employed to quantify vapor penetration, ignition, and soot formation and oxidation for high-pressure sprays in a constant-volume, pre-burn chamber. The three fuels were procured from Finland, Japan and Brazil and have cetane numbers of 64.1, 56.1 and 45.4, respectively.