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In order to clarify the diesel fuel spray characteristics inside the cylinder, we developed two novel techniques, which are preparation of same level of temperature and pressure ambient as inside cylinder and quantitative measurement of vapor concentration. The first one utilizes combustion-type constant-volume chamber (inner volume 110cc), which allows 5 MPa and 873K by igniting the pre-mixture (n-pentane and air) with two spark plugs. In the second technique, TMPD vapor concentration is measured by using Laser Induced Exciplex Fluorescence method (LIEF). The concentration is compensated by investigation of the influence of ambient pressure (from 3 to 5 MPa) and temperature (from 550 to 900 K) on TMPD fluorescence intensity. By using two techniques, we investigated the influence of nozzle hole diameter, injection pressure and ambient condition on spray characteristics.

In a Diesel engine with a Diesel particulate filter (DPF) system, high-sulfur fuel causes white smoke containing odorous and harmful pollutants during DPF regeneration. This study investigates the conditions and mechanisms of sulfur-related white smoke generation. Engine and vehicle tests found that sulfur compounds emitted from the engine accumulated on the catalysts in the DPF system and were emitted as white smoke during DPF regeneration. The white smoke was observed when the catalyst temperature was more than 450°C, under conditions such as the early stage of DPF regeneration. Model gas tests were conducted to clarify the mechanism of the white smoke. It was found that SO2 emitted from the engine was oxidized to SO3 on the catalyst, which was then mainly absorbed on the oxidation catalyst support (Al2O3). Then, the absorbed SO3 was desorbed and converted into white smoke.