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Combination of an NOx storage and reduction catalyst (NSRC, called also lean NOx trap, LNT) and a catalyst for the selective catalytic reduction of NOx by NH₃ (NH₃-SCR) offers a potential to significantly increase the efficiency of NSRC-based exhaust gas aftertreatment systems. Under most situations the SCR catalyst is able to adsorb the NH₃ peaks generated in the NSRC during the regeneration and utilize it for additional NOx reduction in the course of the consequent lean phase. This synergy becomes more important with the aged NSRC, where generally lower NOx conversions and higher NH₃ yields in wider range of operating temperatures are observed (in comparison with the fresh or de-greened NSRC). In this paper we present global kinetic models for the NSRC (Pt/Ba/Ce/gγ-Al₂O₃ catalyst type) and NH₃-SCR (Fe-ZSM5 catalyst type).

The future emission regulation (BS V) in India is expected to create new challenges to meet the particulate matter (PM) limit for diesel cars. The upcoming emission norms will bring down the limit of PM by 80 % when compared to BS IV emission norms. The diesel particulate filter (DPF) is one of the promising technologies to achieve this emission target. The implementation of DPF system into Indian market poses challenges against fuel quality, driving cycles and warranty. Hence, it is necessary to do a detailed on-road evaluation of the DPF system with commercially available fuel under country specific drive cycles. Therefore, we conducted full vehicle durability testing with DPF system which is available in the European market to evaluate its robustness and reliability with BS III fuel (≤350ppm sulfur) & BS IV (≤50ppm sulfur) fuel under real Indian driving conditions.

A powerful and efficient turbocharger turbine benefits the engine in many aspects, such as better transient response, lower NOx emissions and better fuel economy. The turbine performance can be further improved by employing secondary flow injection through an injector over the shroud section. A secondary flow injection system can be integrated with a conventional turbine without affecting its original design parameters, including the rotor, volute, and back disk. In this study, a secondary flow injection system has been developed to fit for an asymmetric twin-scroll turbocharger turbine, which was designed for a 6-cylinder heavy-duty diesel engine, aiming at improving the vehicle’s performance at 1100 rpm under full-loading conditions. The shape of the flow injector is similar to a single-entry volute but can produce the flow angle in both circumferential and meridional directions when the flow leaves the injector and enters the shroud cavity.

A numerical model for a diesel oxidation catalyst (DOC) is presented. It is based on a spatially 1D, physical and chemically based modeling of the relevant processes within the catalytic monolith. A global reaction kinetic approach has been chosen to describe the chemical reactions. Water condensation and evaporation was also considered, in order to predict the cold start behavior. Reaction kinetic parameters have been evaluated from a series of laboratory experiments. A correlation between the kinetic parameters and the noble metal loading was developed. The model was used in combination with a SCR-Model to study the influence of changes of noble metal loading and DOC volume on the overall transient NOx performance of a DOC+DPF+SCR system.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Aerodynamic design and thermal management are some of the most important tasks when developing new concepts for the flow around tractor-trailers. Today, both experimental and numerical studies are an integral part of the aerodynamic and thermal design processes. A variety of studies have been conducted how the aerodynamic design reduces the drag coefficient for fuel efficiency as well as for the construction of radiators to provide cooling on tractor-trailers. However, only a few studies cover the combined effect of the aerodynamic and thermal design on the air temperature of the under hood flow [8, 13, 16, 17, 20]. The objective of this study is to analyze the heat transfer through forced convection for a scaled Cab-over-Engine (CoE) tractor-trailer model with under hood flow. Different design concepts are compared to provide low under hood air temperature and efficient cooling of the sub components.

The number of full electric and hybrid electric vehicles is rapidly growing [1][2][3]. The new technologies accompanying this trend are increasingly becoming a focal point of interest for rescue services. There is much uncertainty about the right techniques to free trapped occupants after an accident. The same applies to vehicle fires. Can car fires involving vehicles with a lithium ion traction battery be handled in the same way as conventional vehicle fires? Is water the right extinguishing agent? Is there a risk of explosion? There are many unanswered questions surrounding the topic of electric vehicle safety. The lack of information is a breeding ground for rumours, misinformation and superficial knowledge. Discussions on various internet platforms further this trend. Tests were conducted on three lithium ion traction batteries, which were fuel-fired until burning on their own. The batteries were then extinguished with water, a surfactant and a gelling agent.

While the market share for diesel engines for LD vehicles in Europe has grown continuously in the past years, the market share in North America is still negligible. Until now, it has been possible to fulfill the limits for nitrogen oxides (NOx) both in Europe and in North America by engine measures alone, without using an active NOx aftertreatment system. With the introduction of Tier II Bin 8 and Tier II Bin 5 emissions legislation in the US in 2007, most new diesel applications will now require NOx aftertreatment. One of the possible technologies for the reduction of nitrogen oxides in lean exhaust gas is the NOx storage catalyst which has become the generally-accepted choice for engines with gasoline direct injection systems and which is also utilized in the current diesel Bluetec I systems from Daimler. For heavier applications urea-SCR is the preferred technology to fulfill NOx legislation limits.

Diesel engines have a strong contribution to the CO2 reduction in Europe in the past years. To enable these C02 reduction potential to the US market Mercedes Benz developed the BLUETEC technology for light duty diesel engines. The BLUETEC technology contains an optimized diesel engine and combustion system, an aftertreatment system with DOC, DPF and an active SCR catalyst with AdBlue Dosing System and an enhanced ECU functionality and calibration. For fulfilling the world strongest emission limits of the US legislation there have to be solutions developed for the handling of AdBlue under cold climate below -11°C, managing the refilling event, and the onboard diagnostic. To ensure the emission stability over full useful life on high NOx conversions level, intensive testing of the catalyst technology had to be done. In addition there are self learning functionalities for adapting the dosing strategy to ensure the maximum NOx performance.

The new Sprinter targets the USA and Canada markets nationwide to reconfirm Daimlers statement for Diesel engine in vans. Consequentially, the MY2007 Sprinter follows his successful predecessor as again the first - and up to now the only - Diesel vehicle in its class now meeting even the strict EPA07 requirement in California. For the growing market in North America an unique development for the successor for the previous 5-cylinder Diesel Sprinter had been made. The new 3 liter V6 Diesel engine is based on numerous corporate wide versions from Mercedes and Chrysler Passenger cars and SUVs and has its roots also in smaller and larger Mercedes vans. Effective January 2007 the NAFTA04 requirements have been replaced by the NAFTA07 values. Meeting those led to significant changes of the latest Sprinter in European EURO4 version. Both, engine and exhaust hardware as well as the ECU-data had been modified consequentially.

Catalyzed wall-flow particulate filters are increasingly applied in diesel exhaust after-treatment for multiple purposes, including low-temperature catalytic regeneration, CO and hydrocarbon conversion, as well as exothermic heat generation during forced regeneration. In order to optimize Precious Metals usage, it may be advantageous to apply the catalytic coating non-uniformly in the DPF, a technology referred to as “catalyst zoning”. In order to simulate the behavior of such a filter, one has to consider coupled transport-reaction modeling. In this work, a previously developed model is calibrated versus experimental data obtained with full-scale catalyzed filters on the engine dynamometer. In a next step, the model is validated under a variety of operating conditions using engine experiments with zoned filters. The performance of the zoned catalyst is analyzed by examining the transient temperature and species profiles in the inlet and outlet channels.

In order to control NOx reduction with NOx storing lean NOx traps (LNT), a gas sensor downstream of the LNT is presently preferred. It is a disadvantage that no means are available to gauge directly the LNT NOx loading level and the catalyst quality. The presented novel sensor consists of interdigital electrodes that are deposited on a planar substrate. On its reverse side, a temperature sensor is applied. Both sides are covered with the original catalyst coating, allowing detecting directly electrical impedance and temperature of the coating. Such sensors were integrated in different positions of an LNT. It is shown in synthetic exhausts as well as in engine tests that in-situ measurements of the electrical impedance of the LNT coating are appropriate to determine directly the catalyst status. Hence, the local degree of NOx loading as well as the local regeneration status can be measured. Furthermore, sulfur poisoning, desulfurization, and thermal ageing can be directly seen.

Beginning in 2010, Daimler's well-known Diesel Sprinter van has to fulfill the new and clearly tighter NOx emission standards of NAFTA10 (EPA, CARB). This requires an integrated approach of further engine optimizations and the implementation of an innovative exhaust aftertreatment technology. The goal was to develop an overall concept which meets simultaneously the tightened emission standards (including OBD limits) and the increasing customer demands of more power and torque without losing the high fuel efficiency of the small and highly efficient 3-liter V6 diesel engine OM642, which already has been installed in the NAFTA07 Sprinter. In the early stages of the concept phase, the most appropriate NOx aftertreatment technology and certification form (engine or vehicle) had to be selected for this specific vehicle class in the van segment with enhanced requirements to durability, economical efficiency and specific driving behavior.

For medium- and heavy-duty diesel engines, the development of new catalyst technologies and particulate filters is necessary to fulfill increasingly stringent emission regulations. An important aspect is the durability of the after-treatment system and therefore its efficiency over lifetime. Lubrication oil additives contain components such as phosphorous or zinc to ensure engine durability. Diesel oxidation catalyst (DOC) and coated diesel particulate filter (cDPF) catalytic coatings are negatively influenced by contamination on the surface with these components (chemical ageing). The components have a negative impact on the exhaust after-treatment systems performance. Additionally the cDPF is filled with oil ash. Engine tests are conducted to analyze the effect of lubrication oil additives on after-treatment system performance. In one study, lubrication oil with increased sulfur ash content is used.

The economic challenges and environmental imperatives facing the trucking and automobile industries today all point to a pressing need to improve fuel efficiency. Due to increasing volatility of fuel supplies, prices and a growing interest in reducing greenhouse gas emissions, fuel efficiency has taken on new urgency. In the long-haul trucking industry this is especially important given the fact that fuel accounts for a significant share of fleet operating costs. To this end Daimler and NAVTEQ have developed a system to improve fuel economy and reduce CO₂ emissions through the integration of digital map data into Advanced Driver Assistance Systems or ADAS. Digital road map attributes, especially road slope have been demonstrated to enable powertrain controls to anticipate road inclination changes and use this information to predictively enhance load management optimization versus the reactive approach afforded by current technology.

In this study the numerical simulation of the flow through an alternator inside an engine compartment of a passenger car is investigated. Specifically the interaction of the flow through the alternator with the flow through the engine compartment is explored in detail. The results are compared with a corresponding numerical simulation of an alternator in a surrounding of a test facility and with a numerical simulation of the flow through an engine compartment without taking into account the internal flow through the alternator. Finally the air temperature near the alternator and also the temperature of some components inside the alternator are compared with experimental values measured during a typical load case used for the thermal protection of the passenger car.

Mercedes-Benz BlueTEC passenger cars have been on the cutting edge of clean diesel technology since 2006. These BlueTEC vehicles furthermore passed millions of kilometers in the hands of customers. SCR-equipped passenger cars already meet the most stringent exhaust emissions standards in international markets such as the USA, Europe and Japan. Diesel engines with BlueTEC technology also reduce CO₂ emissions and provide the high torque and performance associated with the diesel engine in addition to keeping exhaust emissions at the lowest possible level. Nowadays the requirements for SCR emission concepts are increasing continuously. In fact the emission legislation is getting stricter with the LEVIII emission standards in 2015. Additionally the requirements and effort for on-board diagnosis are increasing year after year. In combination with ambitious CO₂ targets all these issues constitute the further challenges of BlueTEC SCR emission concepts for worldwide markets.

Downsizing and direct injection in modern DISI engines can lead to fuel impinging on the cylinder walls. The interaction of liquid fuel and engine oil due to fuel impinging on the cylinder wall causes problems in both lubrication and combustion. To analyze this issue with temporal and spatial resolution, we developed a laser-induced fluorescence (LIF) system for simultaneous kHz-rate imaging of fuel and oil films on the cylinder wall. Engine oil was doped with traces of the laser dye pyrromethene 567, which fluoresces red after excitation by 532 nm laser radiation. Simultaneously, the liquid fuel was visualized by UV fluorescence of an aromatic “tracer” in a non-fluorescent surrogate fuel excited at 266 nm. Two combinations of fuel and tracer were investigated, iso-octane and toluene as well as a multi-component surrogate and anisole. The fluorescence from oil and fuel was spectrally separated and detected by two cameras.

Lubricant oil derived ash deposits still represent a major issue in diesel particulate filter operation in vehicles. In literature various ash deposition patterns are described. The two boundary deposition patterns are (a) wall layer and (b) filling at the back end of the inlet channels. The patterns are often associated with different regeneration methods. Continuous regeneration is supposed to result in a homogeneous ash layer, whereas periodic (active) regeneration is reported to result in back end filling. The current contribution describes the basic mechanisms associated with ash transport phenomena in particle filters. On the basis of (a) frequency of ash exposure to flow (b) ash particle structure re-entrainment and finally (c) axial ash transport the different deposition pattern can be explained. Exposure to flow accomplished by periodical soot removal, either by passive or active regeneration is the first step.

In order to reduce fuel consumption in Fuel Cell Electric Vehicles, effective distribution of power demand between Fuel Cell and Battery is required. Energy management strategies can improve fuel economy by meeting power demand efficiently. This paper explains development of various energy management strategies for Fuel Cell Electric Vehicle with Lithium Ion Battery. Drive cycles used for optimization and analysis of the strategies are New European Drive cycles (NEDC), Japanese Drive cycles (JAP1015), City Drive cycles, Highway Drive cycles (FHDS) and Federal Urban Drive cycles (FUDS). All Fuel consumption and ageing calculations are done using backward model implemented in MATLAB/SIMULINK.