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Journal Article

Development and Demonstration of LNT+SCR System for Passenger Car Diesel Applications

2014-04-01
2014-01-1537
The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.
Technical Paper

Catalytic NOx Reduction in Net Oxidizing Exhaust Gas

1990-02-01
900496
Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.
Technical Paper

A PDF-Based Model for Full Cycle Simulation of Direct Injected Engines

2008-06-23
2008-01-1606
In one-dimensional engine simulation programs the simulation of engine performance is mostly done by parameter fitting in order to match simulations with experimental data. The extensive fitting procedure is especially needed for emissions formation - CO, HC, NO, soot - simulations. An alternative to this approach is, to calculate the emissions based on detailed kinetic models. This however demands that the in-cylinder combustion-flow interaction can be modeled accurately, and that the CPU time needed for the model is still acceptable. PDF based stochastic reactor models offer one possible solution. They usually introduce only one (time dependent) parameter - the mixing time - to model the influence of flow on the chemistry. They offer the prediction of the heat release, together with all emission formation, if the optimum mixing time is given.
Technical Paper

Benefits of GTL Fuel in Vehicles Equipped with Diesel Particulate Filters

2009-06-15
2009-01-1934
Synthetic fuels are expected to play an important role for future mobility, because they can be introduced seamlessly alongside conventional fuels without the need for new infrastructure. Thus, understanding the interaction of GTL fuels with modern engines, and aftertreatment systems, is important. The current study investigates potential benefits of GTL fuel in respect of diesel particulate filters (DPF). Experiments were conducted on a Euro 4 TDI engine, comparing the DPF response to two different fuels, normal diesel and GTL fuel. The investigation focused on the accumulation and regeneration behavior of the DPF. Results indicated that GTL fuel reduced particulate formation to such an extent that the regeneration cycle was significantly elongated, by ∼70% compared with conventional diesel. Thus, the engine could operate for this increased time before the DPF reached maximum load and regeneration was needed.
Technical Paper

Simulation Based Analysis of Test Results

2010-04-12
2010-01-1013
The use of a newly developed approach results in a highly accurate three dimensional analysis of the occupant movement. The central point of the new method is the calculation of precise body-trajectories by fitting standard sensor-measurements to video analysis data. With the new method the accuracy of the calculated trajectories is better than 5 to 10 millimeters. These body trajectories then form the basis for a new multi-body based numerical method, which allows the three dimensional reconstruction of the dummy kinematics. In addition, forces and moments acting on every single body are determined. In principle, the body movement is reconstructed by prescribing external forces and moments to every single body requiring that it follows the measured trajectory. The newly developed approach provides additional accurate information for the development engineers. For example the motion of dummy body parts not tracked by video analysis can be determined.
Technical Paper

Development of Vehicle Exhaust Flow Measurement Calibration Device

2004-03-08
2004-01-1436
Vehicle exhaust flow is difficult to measure accurately and with high precision due to the highly transient nature of the cyclic events which are dependent on engine combustion parameters, varying exhaust gas compositions, pulsation effects, temperature and pressure. Bag mini-diluter (BMD) is becoming one of the few technologies chosen for SULEV and PZEV exhaust emission measurement and certification. A central part of the BMD system is an accurate and reliable exhaust flow measurement which is essential for proportional bag fill. A new device has been developed to accurately and reliably calibrate exhaust flow measurement equipments such as the E-Flow. The calibration device uses two different size laminar flow elements (LFE), a 40 CFM (1.13 m3/min) LFE for low end calibration and a 400 CFM (11.32 m3/min) LFE for higher flows. A blower is used to push flow through a main flow path, which then divides into two flow pathways, one for each of the two LFE's.
Technical Paper

Bag Mini-Diluter System Diagnostics

2004-03-08
2004-01-1438
Automakers in the United States have started using bag mini-diluters (BMD) for developing, testing and certifying vehicles, to meet PZEV and SULEV regulation requirements. The BMD system which is a new technology developed by AIGER, is being used as an alternative to the traditional CFV/CVS system for accurate ultra low-level emission measurement. BMD system has shown to have considerable advantage over CFV/CVS system, especially at ULEV/SULEV emission levels. This paper details modifications and diagnostic checks conducted with the existing BMD system at the DaimlerChrysler Tech Center emissions facility, Auburn Hills, Michigan. This paper also discusses possible scenarios where the BMD system at DaimlerChrysler could give erroneous results due to system setup, optimization issues and equipment limitations.
Technical Paper

New ways of fluid flow control in automobiles: Experience with exhaust gas aftertreatmetn control

2000-06-12
2000-05-0299
Flow control by fluidic devices - without moving parts - offers advantages of reliability and low cost. As an example of their automobile application based on authors'' long-time experience the paper describes a fluidic valve for switching exhaust gas flow in a NOx absorber into a by-pass during regeneration phase. The unique feature here is the fluidic valve being of monostable and of axisymmetric design, integrated into the absorber body. After development in aerodynamic laboratory, the final design was tested on engine test stand and finally in a car. This proved that the performance under high temperature and pulsation existing in exhaust systems is reliable and promising. Fluidic valves require, however, close matching with aerodynamic load. To optimize the exhaust system layout for the whole load-speed range and reaching minimum counter- pressure, both the components of exhaust system and control strategy have to be properly adopted.
Technical Paper

Overall Results: Phase I Ad Hoc Diesel Fuel Test Program

2001-03-05
2001-01-0151
The future of diesel-engine-powered passenger cars and light-duty vehicles in the United States depends on their ability to meet Federal Tier 2 and California LEV2 tailpipe emission standards. The experimental purpose of this work was to examine the potential role of fuels; specifically, to determine the sensitivity of engine-out NOx and particulate matter (PM) to gross changes in fuel formulation. The fuels studied were a market-average California baseline fuel and three advanced low sulfur fuels (<2 ppm). The advanced fuels were a low-sulfur-highly-hydrocracked diesel (LSHC), a neat (100%) Fischer-Tropsch (FT100) and 15% DMM (dimethoxy methane) blended into LSHC (DMM15). The fuels were tested on modern, turbocharged, common-rail, direct-injection diesel engines at DaimlerChrysler, Ford and General Motors. The engines were tested at five speed/load conditions with injection timing set to minimize fuel consumption.
Technical Paper

Oxygenates screening for AdvancedPetroleum-Based Diesel Fuels: Part 2. The Effect of Oxygenate Blending Compounds on Exhaust Emissions

2001-09-24
2001-01-3632
Adding oxygenates to diesel fuel has shown the potential for reducing particulate (PM) emissions in the exhaust. The objective of this study was to select the most promising oxygenate compounds as blending components in diesel fuel for advanced engine testing. A fuel matrix was designed to consider the effect of molecular structure and boiling point on the ability of oxygenates to reduce engine-out exhaust emissions from a modern diesel engine. Nine test fuels including a low-sulfur (∼1 ppm), low-aromatic hydrocracked base fuel and 8 oxygenate-base fuel blends were utilized. All oxygenated fuels were formulated to contain 7% wt. of oxygen. A DaimlerChrysler OM611 CIDI engine for light-duty vehicles was controlled with a SwRI Rapid Prototyping Electronic Control System. The base fuel was evaluated in four speed-load modes and oxygenated blends only in one mode. Each operating mode and fuel combination was run in triplicate.
Technical Paper

Driver out-of-position injuries mitigation and advanced restraint features development

2001-06-04
2001-06-0069
Airbag-related out-of-position (OOP) injuries in automotive crash accident have drawn great attention by public in recent years. In the interim-final rule of Federal Motor Vehicle Safety Standards that NHTSA issued in May 2000, OOP static test becomes a mandatory requirement of new regulation and will be phased in starting from year 2003. Due to the complexities and constraints of vehicle design, such as extreme vehicle styling and packaging as well as multiple safety requirements, it is a great challenge for both restraint safety suppliers and automobile manufacturers work together to come up with proper designs to meet requirements of new regulation and provide additional protection for both in-position and OOP occupants at various vehicle crash scenarios. In this paper, the technique of developing advanced restraint system and mitigating the OOP injuries is described.
Technical Paper

A Study of the Thermochemical Conditions in the Exhaust Manifold Using Secondary Air in a 2.0 L Engine

2002-05-06
2002-01-1676
The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.
Technical Paper

Compatibility: Causes, Constraints, Improvements and Evaluation Proposal

2002-03-04
2002-01-1023
Accident studies conducted during the last twenty-five years clearly show that car to car head-on collision is a major impact configuration to take into account in order to improve safety on the roads. With new self protection ratings all cars offer equivalent behaviour against a fixed obstacle. So, in the future, the main progress will have to be made in car to car compatibility. Recent studies have shown the feasibility of designing compatible cars for both structure behaviour and occupant protection. However, some requirements on front unit design could make this aim more difficult to achieve. We suggest developping a more comprehensive approach in order to better take into account all the constraints.
Technical Paper

An Impact Pulse-Restraint Energy Relationship and Its Applications

2003-03-03
2003-01-0505
This paper presents an energy relationship between vehicle impact pulses and restraint systems and applies the relationship to formulations of response factors for linear and nonlinear restraints. It also applies the relationship to derive optimal impact pulses that minimize occupant response for linear and nonlinear restraints. The relationship offers a new viewpoint to impact pulse optimization and simplifies the process mathematically. In addition, the effects of different vehicle impact pulses on the occupant responses with nonlinear restraints are studied. Finally, concepts of equivalent pulses and equal intensity pulses are presented for nonlinear restraints.
Technical Paper

Engine-Independent Exhaust Gas Aftertreatment Using a Burner Heated Catalyst

2006-10-16
2006-01-3401
Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.
Technical Paper

OOP Response of THOR and Hybrid-III 50th% ATDs

2006-04-03
2006-01-0065
The responses of the THOR and the Hybrid-III ATDs to head and neck loading due to a deploying air bag were investigated. Matched pair tests were conducted to compare the responses of the two ATDs under similar loading conditions. The two 50th percentile male ATDs, in the driver as well as the passenger positions, were placed close to the air bag systems, in order to enhance the interaction between the deploying air bag and the chin-neck-jaw regions of the ATDs. Although both ATDs nominally meet the same calibration corridors, they differ significantly in their kinematic and dynamic responses to interaction with a deploying air bag. The difference between the structural designs of the Hybrid-III's and the THOR's neck appears to result in significant differences in the manner in which the loads applied on the head are resisted.
Technical Paper

Evaluation of Advanced Diesel Oxidation Catalyst Concepts: Part 2

2006-04-03
2006-01-0032
The development of diesel powered passenger cars is driven by the enhanced emission legislation. To fulfill the future emission limits there is a need for advanced aftertreatment devices. A comprehensive study was carried out focusing on the improvement of the DOC as one part of these systems, concerning high HC/CO conversion rates, low temperature light-off behaviour and high temperature aging stability, respectively. The first part of this study was published in [1]. Further evaluations using a high temperature DPF aging were carried out for the introduced systems. Again the substrate geometry and the catalytic coating were varied. The results from engine as well as vehicle tests show advantages in a highly systematic context by changing either geometrical or chemical factors. These results enable further improvement for the design of the exhaust system to pass the demanding emission legislation for high performance diesel powered passenger cars.
Technical Paper

Improving Direct Vehicle Exhaust Flow Measurement

2005-04-11
2005-01-0686
Measuring vehicle exhaust volumetric flow rate accurately and precisely is critical in calculating the correct vehicle modal and bag mini-diluter exhaust emission constituent masses. It is also instrumental in engine calibration practices. Currently, DaimlerChrysler's Emission and Certification Lab in Auburn Hills, Michigan utilizes constant volume sampling bag systems to certify vehicles but the automotive technological trend is heading toward the bag mini-diluter for greater precision at low emission levels. The bag mini-diluters, as well as the modal sampling system, used extensively in vehicle development testing, rely on exhaust flow rate measurement by means of a direct vehicle exhaust flow meter named E-Flow. The E-Flow has few limitations such as flow profile instability at low idle flow rates and reaction to resonating pressure waves in the exhaust system.
Technical Paper

Interaction Between Gasoline Properties and Engine Management System and Effects on 3-Way Catalyst Efficiency

1997-10-01
972839
The EPEFE study (European Programme on Emissions, Fuels and Engine Technologies), /1/ and other programmes have identified an increase in tailpipe NOx emissions with reduced gasoline aromatics content for modern 3-way controlled catalyst vehicles. This effect occurs with fully warmed-up catalyst under closed-loop operation. In order to understand the reasons for this effect VW and Shell have mechanistically investigated the effects of fuel properties on EMS (engine management system) and catalyst performance. Fuels with independent variation of oxygen, aromatics and mid-range volatility were tested in different VW engines. λ was monitored using sensors located both pre and post catalyst. The results confirmed that reducing gasoline aromatics content reduced engine-out emissions but increased tailpipe NOx emissions. It could be shown that differences in H/C ratio led to differences in the hydrogen content of engine-out emissions which affected the reading of the λ sensor.
Technical Paper

Development of Wireless Message for Vehicle-to-Infrastructure Safety Applications

2018-04-03
2018-01-0027
This paper summarizes the development of a wireless message from infrastructure-to-vehicle (I2V) for safety applications based on Dedicated Short-Range Communications (DSRC) under a cooperative agreement between the Crash Avoidance Metrics Partners LLC (CAMP) and the Federal Highway Administration (FHWA). During the development of the Curve Speed Warning (CSW) and Reduced Speed Zone Warning with Lane Closure (RSZW/LC) safety applications [1], the Basic Information Message (BIM) was developed to wirelessly transmit infrastructure-centric information. The Traveler Information Message (TIM) structure, as described in the SAE J2735, provides a mechanism for the infrastructure to issue and display in-vehicle signage of various types of advisory and road sign information. This approach, though effective in communicating traffic advisories, is limited by the type of information that can be broadcast from infrastructures.
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