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In the past few decades, use of energy resources in industrial and transportation sector have reached to its peak resulting in depleting resources and environment squalor. Vegetable oils, which have properties comparable to diesel fuel, are considered promising alternative fuels for unmodified diesel engines. However, high viscosity of vegetable oils is a major challenge which could be reduced by blending with alcohols. The aim of the present study was to investigate the suitability of orange peel oil and n-butanol blends as an alternative fuel for CI engine. Various blends of butanol with orange peel oil were prepared on volumetric basis and named as B10OPO90 (10% n-butanol and 90% orange peel oil), B20OPO80 (20% n-butanol and 80% orange peel oil), B30OPO70 (30% n-butanol and 70% orange peel oil) and B40OPO60 (40% n-butanol and 60% orange peel oil). All blends were found homogenous and various physico-chemical properties were evaluated in accordance to relevant standards.

Diesel engines are employed particularly in the field of heavy transportation and agriculture on account of their higher thermal efficiency and durability. As these engines, are the backbones of contemporary global transportation and accounts a 30% of world's energy consumption, which is second highest after the industrial sector. Therefore, the fossil fuel consumption becomes the prime concern. Following the global energy crisis and the increasingly stringent emission norms, the search for alternative renewable fuels has intensified. Currently, biodiesel (BD) has been identified as the most attractive and practical choice to replace fossil fuel as the main source of energy, due to the similarity in the properties with conventional diesel. However, its development and application have been hindered by the high cost of required feedstock. Therefore, in recent years, researchers have been seeking the alternative sources of non-edible oil which are economical.

The interest of using alternative fuels in diesel engines has been accelerated exponentially due to a foreseen scarcity in world petroleum reserves, increase in the prices of the conventional fossil fuels and restrictions on exhaust emissions such as greenhouse gases from internal combustion (IC) engines initiated by environmental concerns. The constant trade-off between efficiency and emissions should be in proper balance with the conventional fuels in a fuel design process for future combustors. Unlike gasoline and diesel, alcohols act as oxygenated fuels. Adding alcohols to petroleum products allows the fuel to combust properly due to the presence of oxygen, which enhances premixed combustion phase, improves the diffusive combustion phase which increases the combustion efficiency and reduces air pollution. The higher activation energy of alcohols leads to better resistance to engine knocking that allows higher compression ratios and greater engine thermal efficiencies.

Primary energy sources can be divided into non-renewable and renewable. The over-exploration of non-renewable sources for energy availability imposes considerable impacts on the environment. Reducing the use of fossil fuels would significantly reduce the carbon dioxide emissions and other pollutants produced. The future drift for sustainable production of renewable energy is cautiously thoughtful for it has been increasingly understood that first generation biofuels, majorly produced from food crops that are limited in their ability to achieve targets for biofuel production, climate change mitigation and economic growth. These concerns have increased the interest in developing second generation biofuels produced from non-edible feedstock such as microalgae, which potentially offers greatest opportunities in the longer term. Microalgae are considered a very promising feedstock for biodiesel production due to their very high yield and their no competition with food crops.