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Internal combustion engines are extensively used in every field of life in today's world. Diesel engines being more efficient are preferred in the industrial and transportation sector in comparison to spark ignition engines for their higher efficiency, versatility and ruggedness. The major emissions of diesel engines are oxides of nitrogen (NOx), particulate matter (PM), carbon dioxide (CO2), carbon monoxide (CO). Among these emissions, oxides of nitrogen (NOx) and the particulate matter are the reasons of serious concern. For reduction of oxides of nitrogen (NOx) and particulate matter simultaneously, the use of Homogeneous Charge Compression Ignition (HCCI) have provided a sustainable solution in the present scenario. Further, the use of CNG in HCCI engine along with pilot diesel injection; the emissions have been decreased drastically. Homogeneous mixing of fuel and air leads to cleaner combustion and lower emissions.