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Fuel cells show great promise in generating electrical power for a variety of uses. In the automotive realm, one focus has been on the use of fuel cells for primary vehicle propulsion. Another emerging application is the fuel cell as the primary provider of electrical power to the vehicle, augmenting or replacing the traditional alternator, while producing higher power levels. The advantage of the fuel cell in this role is that the fuel cell operation is de-coupled from that of the engine. High power levels can be achieved independent of engine speed and power can be produced without the engine running. This paper examines the application of a fuel cell auxiliary power unit (APU) to a dual-voltage 42V/14V automotive electrical system meeting the evolving 42V PowerNet specifications. An architecture for this electrical system is presented, followed by a sizing analysis to properly match the fuel cell stack to the voltage of the PowerNet and to a 42V battery pack.