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The purposes of this study are to clarify the atomization mechanism, the change over time in droplet size distribution, and the change in spray characteristics dependent on back pressure on diesel fuel spray. Diesel spray injected into a quiescent gaseous environment under high pressure is observed by taking direct microscopic photographs varying the moment of exposure, the back pressure, and the ambient density. The results show that the mechanism of spray atomization is divided into 4 processes, and spatial distribution of breakup droplets and a droplet volume rate are assessed for the whole spray region. Total and local distributions of droplet size are expressed by empirical equations as a function of time elapsed from the moment of injection. It is confirmed that the uniformity of the distribution, Sauter mean diameter of droplets, and droplet production rate change with time. Mean droplet diameter is further described in relation to the pressure drop and the ambient density.