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Theoretically, homogeneous charge compression engines (HCCI) are able to grant a high thermal efficiency, as well as a low NOx and particulate emissions. This ability is mainly due to the combustion process, which, contrary to both Diesel and Gasoline engine, is homogeneous in time and space within the combustion chamber. But despite these advantages, the engine operating condition is limited by the narrow boundaries of misfire at low load and knocking at high load. For that matter, one of the numerous ways of overcoming knocking is to deliberately create fuel inhomogeneities within the combustion chamber, since it has proved to lengthen combustion duration and to drastically reduce maximum pressure rise rate (PRR). Nevertheless, though the global effects of fuel inhomogeneities on PRR have been studied, we lack information that explains this phenomenon.