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Existing gasoline DI injection equipment has been modified to generate single hole pulsed gas jets. Injection experiments have been performed at combinations of 3 different pressure ratios (2 of which supercritical) respectively 3 different hole geometries (i.e. length to diameter ratios). Injection was into a pressure chamber with optical access. Injection pressures and injector hole geometry were selected to be representative of current and near-future DI natural gas engines. Each injector hole design has been characterized by measuring its discharge coefficient for different Re-levels. Transient jets produced by these injectors have been visualized using planar laser sheet Mie scattering (PLMS). For this the injected gas was seeded with small oil droplets. The corresponding flow field was measured using particle image velocimetry (PIV) laser diagnostics.

Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

Detailed chemistry and turbulence-chemistry interaction need to be properly taken into account for a realistic combustion simulation of IC engines where advanced combustion modes, multiple injections and stratified combustion involve a wide range of combustion regimes and require a proper description of several phenomena such as auto-ignition, flame stabilization, diffusive combustion and lean premixed flame propagation. To this end, different approaches are applied and the most used ones rely on the well-stirred reactor or flamelet assumption. However, well-mixed models do not describe correctly flame structure, while unsteady flamelet models cannot easily predict premixed flame propagation and triple flames. A possible alternative for them is represented by transported probability density functions (PDF) methods, which have been applied widely and effectively for modeling turbulent reacting flows under a wide range of combustion regimes.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

Methane abatement in the exhaust gas of natural gas engines is much more challenging in respect to the oxidation of other higher order hydrocarbons. Under steady state λ sweep, the methane conversion efficiency is high at exact stoichiometric, and decreases steeply under both slightly rich and slightly lean conditions. Transient lean to rich transitions can improve methane conversion at the rich side. Previous experimental work has attributed the enhanced methane conversion to activation of methane steam reforming. The steam reforming rate, however, attenuates over time and the methane conversion rate gradually converges to the low steady state values. In this work, a reactor model is established to predict steady state and transient transition characteristics of a three-way catalyst (TWC) mounted in the exhaust of a natural gas heavy-duty engine.

Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

Pursuing a sustainable energy scenario for transportation requires the blending of renewable oxygenated fuels such as alcohols into commercial hydrocarbon fuels. From a chemical kinetic perspective, this requires the accurate description of both hydrocarbon reference fuels (n-heptane, iso-octane, toluene, etc.) and oxygenated fuels chemistry. A recent systematic investigation of linear C2-C5 alcohols ignition in a rapid compression machine at p = 10-30 bar and T = 650- 900 K has extended the scarcity of fundamental data at such conditions, allowing for a revision of the low temperature chemistry for alcohol fuels in the POLIMI mechanism. Heavier alcohols such as n-butanol and n-pentanol present ignition characteristic of interest for application in HCCI engines, due to the presence of the hydroxyl moiety reducing their low temperature reactivity compared to the parent linear alkanes (i.e. higher octane number).

This paper focusses on the application of bioalcohols (ethanol and butanol) derived from seaweed in Heavy-Duty (HD) Compression Ignition (CI) combustion engines. Seaweed-based fuels do not claim land and are not in competition with the food chain. Currently, the application of high octane bioalcohols is limited to Spark Ignition (SI) engines. The Reactivity Controlled Compression Ignition (RCCI) combustion concept allows the use of these low carbon fuels in CI engines which have higher efficiencies associated with them than SI engines. This contributes to the reduction of tailpipe CO2 emissions as required by (future) legislation and reducing fuel consumption, i.e. Total-Cost-of-Ownership (TCO). Furthermore, it opens the HD transport market for these low carbon bioalcohol fuels from a novel sustainable biomass source. In this paper, both the production of seaweed-based fuels and the application of these fuels in CI engines is discussed.

Green zones are challenging problems for the thermal management systems of hybrid vehicles. This is because within the green zone the engine is turned off, and the only way to keep the aftertreatment system warm is lost. This means that there is a risk of leaving the green zone with a cold and ineffective aftertreatment system, resulting in high emissions. A thermal management strategy that heats the aftertreatment system prior to turning off the engine, in an optimal way, to reduce the NOx emissions when the engine is restarted, is developed. The strategy is also used to evaluate under what conditions pre-heating is a suitable strategy, by evaluating the performance in simulations using a model of a heavy-duty diesel powertrain and scenario designed for this purpose.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Butanol is an attractive alternative fuel by virtue of its renewable source and low sooting tendency. In this paper, three butanol isomers (n-butanol, isobutanol, and tert-butanol) were induced via port injection respectively and n-heptane was directly injected into the cylinder to investigate reactivity controlled compression ignition in a heavy-duty diesel engine. This work evaluates the potential of applying butanol as low reactivity fuel and the effects of reactivity gradient on combustion and emission characteristics. The experiments were performed from low load to medium-high load. Due to the different reactivities among the butanol isomers, the exhaust gas recirculation rate and the direct injection strategy were varied for a specific butanol isomer and testing load. Particularly, isobutanol/n-heptane can be operated with single direct injection and no exhaust gas recirculation up to medium load due to the high octane rating.

A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.

A computationally efficient engine model is developed based on an extended NO emission model and state-of-the-art soot model. The model predicts exhaust NO and soot emission for both conventional and advanced, high-EGR (up to 50 %), heavy-duty DI diesel combustion. Modeling activities have aimed at limiting the computational effort while maintaining a sound physical/chemical basis. The main inputs to the model are the fuel injection rate profile, in-cylinder pressure data and trapped in-cylinder conditions together with basic fuel spray information. Obtaining accurate values for these inputs is part of the model validation process which is thoroughly described. Modeling results are compared with single-cylinder as well as multi-cylinder heavy-duty diesel engine data. NO and soot level predictions show good agreement with measurement data for conventional and high-EGR combustion with conventional timing.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Increasing fuel prices keep bringing attention to alternative, cheaper fuels. Liquefied Petroleum Gas (LPG) has been well known for decades as an alternative fuel for spark ignition (SI) passenger cars. More recently, aftermarket LPG systems were also introduced to Heavy Duty transport vehicles. These (port fuel) systems either vaporize the liquid fuel and then mix it with intake air, or inject fuel into the engine's intake ports. While this concept offers significant fuel cost reductions, for aftermarket certification and large-scale OEM use some concerns are present. Unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions are known to be high because of premixed charge getting trapped into crevices and possibly being blown through during valve-overlap. Apart from the higher emission levels, this also limits fuel efficiency and therefore cost savings.

Partially Premixed Combustion has shown the potential of low emissions of nitrogen oxides (NOx) and soot with a simultaneous improvement in fuel efficiency. Several research groups have shown that a load range from idle to full load is possible, when using low-octane-number refinery streams, in the gasoline boiling range. As such refinery streams are not expected to be commercially available on the short term, the use of naphtha blends that are commercially available could provide a practical solution. The three blends used in this investigation have been tested in a single-cylinder engine for their emission and efficiency performance. Besides a presentation of the sensitivity to injection strategies, dilution levels and fuel pressure, emission performance is compared to legislated emission levels. Conventional diesel combustion benchmarks are used for reference to show possible improvements in indicated efficiency.

Modeling plume interaction and collapse for direct-injection gasoline sprays is important because of its impact on fuel-air mixing and engine performance. Nevertheless, the aerodynamic interaction between plumes and the complicated two-phase coupling of the evaporating spray has shown to be notoriously difficult to predict. With the availability of high-speed (100 kHz) Particle Image Velocimetry (PIV) experimental data, we compare velocity field predictions between plumes to observe the full temporal evolution leading up to plume merging and complete spray collapse. The target “Spray G” operating conditions of the Engine Combustion Network (ECN) is the focus of the work, including parametric variations in ambient gas temperature. We apply both LES and RANS spray models in different CFD platforms, outlining features of the spray that are most critical to model in order to predict the correct aerodynamics and fuel-air mixing.

Partially Premixed Combustion has shown the potential of high efficiency, emissions of nitrogen oxides (NOx) and soot below future emissions regulations, and acceptable acoustic noise. Low-octane-number gasoline fuels were shown to be most suitable for this concept, with the reactivity determining the possible load range. Other researchers have used several refinery streams, which might be produced by a refinery if they were required to do so without additional investment. Some of refinery streams are, however, not expected to be commercially available on the short term. For the present investigation, n-butanol (BuOH) has been selected as a blend component in diesel, and is used from 50 - 100%. The blends then have a reactivity range similar to the refinery streams, so single-cylinder engine tests for their emission and efficiency performance can also be used to determine their applicable load range.