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Technical Paper

Innovative Substrate Technology for High Performance Heavy Duty Truck SCR Catalyst Systems

2007-04-16
2007-01-1577
Diesel engine emissions regulations throughout the world have changed dramatically over the last 20 years, with the most stringent phase for medium/heavy duty being implemented starting 2007 - 2010. The general perception is, that combination systems including PM reduction devices and NOx aftertreatment, likely SCR will be applied, hence significant additional emissions equipment will need to be added to a diesel engine. The consequences of this will be increased space for packaging and increased cost, to meet the demanding regulations. Traditional substrate technology, while developing extensively for gasoline engines by use of higher cell densities has limitations when applied to CI diesel engines. New developments in substrate and coating technology now enable considerable improvement in the efficiency and packaging space needed to meet certain limit values.
Technical Paper

Development of an Integrated NOx and PM Reduction Aftertreatment System: SCRi™ for Advanced Diesel Engines

2008-04-14
2008-01-1321
Diesel engine emission regulations throughout the world have progressed over the last 20 years. In the U.S. the most stringent medium/heavy duty standard will be implemented for on highway vehicles starting in 2010. Although changes to engine design will improve engine out emissions, in order to meet both PM and NOx regulations, combination systems including PM and NOx aftertreatment, are planned to be utilized. In order to achieve the required regulations, a new substrate technology has been developed using advanced “turbulent” flow characteristics, and it has been combined with a novel approach to reduce system complexity: the “SCRi™” or “SCR integrated” system. Such a system uses a continuously operating PM-Metalit with advanced “turbulent” SCR-catalysts in a unique configuration. The reduction of both PM and NOx also has to be seen in context with its effect on CO2 emissions.
Technical Paper

Continuously Regenerating Particulate Matter (PM Metalit®) in LDV & HDV Retrofit Application Experiences from the Korean Retrofit Programme

2008-06-23
2008-01-1547
Particulates in Diesel Exhaust Gas have become a major concern of Environment Protection Agencies in the recent years. The main focus was placed on the so called Nano Particles which are the most harmful to human beeings. OEMs for car, light and heavy commercial vehicle industries have been working on different technologies for a number of years to meet the stringent emission legislations. At the same time some countries have started schemes to retrofit older vehicles that are still on the road and greatly contribute to air pollution. The government of Korea took the worldwide lead and defined 3 categories of required PM reduction rates and incentives to LDV and HDV owners who are prepared to retrofit their vehicles.
Technical Paper

PM Metalit® - A Continuously Regenerating Partial Flow Particulate Filter - Concept and Experience with Korean Retrofit Programme

2008-01-09
2008-28-0008
Emission legislations for the light / medium and heavy duty vehicles are becoming more and more stringent worldwide. Tightening of NOx and Particulate Matter (PM) limits further from Euro III to Euro IV levels has provoked the need of either controlling NOx from the engine measures and use PM control after-treatment devices such as Partial Flow Filters, or, controlling PM from the engine measures and use NOx control devices such as Selective Catalytic Reduction (SCR) systems. Manufacturers have adopted different strategies, depending upon the suitability, cost factors, infrastructure development and ease of maintenance of these systems. PM Metalit®, is a partial flow filter, which captures particulates coming out of the exhaust and re-generates on a continuous basis with the help of Nitrogen Dioxide (NO2) in the exhaust.
Technical Paper

New Catalyst Preparation Procedure for OBDII-Monitoring Requirements

2001-03-05
2001-01-0933
In order to match catalyst OBDII conditions the common procedure is oven aging with air, which is not suitable for complete converter systems due to mantle corrosion. The goal was, therefore, to find an alternative procedure to ensure a defined catalyst aging that would match 1,75 times the emission standard and is also good for SULEV. The new procedure currently being developed allows the aging of metal and ceramic catalysts as well as complete catalyst systems. The paper will present the aging process, emission data of fresh and aged catalysts and the feedback to the test car OBDII system.
Technical Paper

Application Guideline to Define Catalyst Layout for Maximum Catalytic Efficiency

2001-03-05
2001-01-0929
The influence of physical parameters of the catalyst's substrate such as thermal mass, hydraulic diameter and geometric surface area on catalyst's efficiency is well known as published in numerous works. This paper will show interactions of these parameters and will provide a guideline on how to design the optimum system for a specific application, taking into account system's back pressure and system costs. Based on engine test bench results that show the influence of the physical parameters, the results for the optimized design regarding emission tests and maximum conversion rate at higher loads will be demonstrated.
Technical Paper

Study of Modern Application Strategies for Catalytic Aftertreatment Demonstrated on a Production V6 Engine

2001-03-05
2001-01-0925
A study was performed to develop optimum design strategies for a production V6 engine to maximize catalyst performance at minimum pressure loss and at minimum cost. Test results for an advanced system, designed to meet future emission limits on a production V6 vehicle, are presented based on FTP testing. The on-line pressure loss and temperature data serves to explain the functioning of the catalyst.
Technical Paper

New Approaches to Catalyst Substrate Application for Diesel Engines

2001-03-05
2001-01-0189
Nearly all real Diesel engine operation is leading to low exhaust temperatures. Standard catalyst technique remains therefore for significant time below light off. To improve the conversion behavior two approaches were made: placement of tailor fitted catalysts as close as possible to the engine exhaust port before turbocharger and usage of close coupled catalysts with the so-called hybrid design. Both measures are providing visible progress in reducing Diesel engine emissions. Tests were made with modern Diesel engines both for passenger cars and heavy duty vehicles.
Technical Paper

Next Generation Catalysts are Turbulent:Development of Support and Coating

2004-03-08
2004-01-1488
Future catalyst systems need to be highly efficient in a limited packaging space. This normally leads to a design where the flow distribution, in front of the catalyst, is not perfectly uniform. Measurements on the flow test bench show that the implementation of perforated foils for the corrugated and flat foils has the capability to distribute the flow within the channels in the radial direction so that the maximum of the given catalyst surface is of use, even under very poor uniformity indices. Therefore a remarkable reduction in back pressure is measured. Emission results demonstrate cold start improvement due to reduced heat capacity. The use of LS - structured ( Longitudinal structured ) corrugated foils creates a high turbulence level within the single channels. The substrate lights-up earlier and the maximum conversion efficiency is reached more quickly.
Technical Paper

Application of New Diesel Aftertreatment Strategies on a Production 1.9 L Common-Rail Turbocharged Engine

2002-03-04
2002-01-1313
1 An experimental study has been carried out on a production vehicle by means of roller-bench emission tests in order to optimize alternative aftertreatment systems. To this aim different comparisons between the production exhaust system and new strategies are discussed in the present paper with aid of both modal emission data and bag tailpipe figures. The present work shows the application of a alternative solution that complies with future emission legislation with regard both to HC, CO, NOx and PM without any major engine power output or fuel consumption penalty.
Technical Paper

Application of metal-supported catalysts for diesel engines

2001-09-23
2001-24-0059
Nearly all real diesel engines operations are leading to low exhaust temperatures. Standard catalyst technique remains therefore for significant time below light-off. To improve the conversion behavior two approaches were made: placement of tailor-fitted catalysts as close as possible to the engine exhaust port before turbocharger and usage of close coupled catalysts with the so-called hybrid design. Both measures are providing visible progress in reducing diesel engine emissions. Tests were made with modern diesel engines both for passenger cars and heavy-duty vehicles.
Technical Paper

Design Techniques to Improve the Performances of Metal Supported Flow-Through Particulate Traps: an Experimental and Numerical Approach

2001-09-23
2001-24-0061
Soot filtration represents a major problem for the complete exploiting of Diesel engines characteristics in terms of global efficiency and CO2 emissions. Even though the engines development in the last years let the engine performances improve, exhaust gas after treatment is still required to respect the foreseen limits for soot and NOx emissions. A flow-through particle trap has been presented with a great potential in soot removal without major penalties in terms of exhaust back pressure. The device performance is strictly connected to channel geometry. This paper deals with that relation by means of an experimental-numerical approach.
Technical Paper

Advanced Performance of Metallic Converter Systems Demonstrated on a Production V8 Engine

2002-03-04
2002-01-0347
It has been shown within the catalyst industry that the emission performance with higher cell density technology and therefore with higher specific geometric area is improved. The focus of this study was to compare the overall performance of high cell density catalysts, up to 1600cpsi, using a MY 2001 production vehicle with a 4.7ltr.V8 engine. The substrates were configured to be on the edge of the design capability. The goal was to develop cost optimized systems with similar emission and back pressure performance, which meet physical and production requirements. This paper will present the results of a preliminary computer simulation study and the final emission testing of a production vehicle. For the pre-evaluation a numerical simulation model was used to compare the light-off performance of different substrate designs in the cold start portion of the FTP test cycle.
Technical Paper

A Computational and Experimental Analysis for Optimization of Cell Shape in High Performance Catalytic Converters

2002-03-04
2002-01-0355
The effects of the internal geometry of catalytic converter channels on flow characteristics; exhaust backpressure and overall conversion efficiency have been investigated by means of both numerical simulations and experimental investigations. The numerical work has been carried out by means of a micro scale numerical tool specifically tailored for flow characteristics within converter channels. The results are discussed with aid of flow distribution patterns within the single cell and backpressure figures along the catalyst channel. The results of the numerical investigation provide information about the most efficient channel shapes. An experimental validation of the simulated results has been carried out with a production 3.6 liter, 6-cylinder engine on a dynamic test bench. Both modal and bag emission data have been measured during the FTP-Cycle.
Technical Paper

A Mixed Numerical-Experimental Analysis Procedure for Non-Blocking Metal Supported Soot Trap Design

2002-10-21
2002-01-2782
Metal based Diesel Particulate Filters (PM-TRAPs) could represent a short time solution to face with particulate (and NOx) emissions with a small influence on CO2 emission. In fact, the operation principle of the PM-TRAP, based on fluid dynamical behavior of exhaust flow in “ad hoc” shaped geometries, allows to separate the particle content of exhaust-gases but needs to be carefully assessed to optimize filter performances. In this paper a mixed numerical and experimental procedure has been developed; it allows to finely tune the design parameters which can be used to achieve pre-defined targets in terms of particulate matter and fuel consumption. By adopting the previously declared procedure, a PM-TRAP “optimal” geometry has been chosen. Its performance has been verified with respect to experimental data. Results are encouraging and suggest further development of the system.
Technical Paper

A Metal Substrate with Integrated Oxygen Sensor; Functionality and Influence on Air/Fuel Ratio Control

2003-03-03
2003-01-0818
In order to achieve ultra low emission levels with three-way catalysts, an early accurate air/fuel ratio control is essential. Positioning the oxygen sensor in the first part of the substrate helps to protect the oxygen sensor from being splashed by water during cold start, so that early heating and activation becomes a less limiting factor. For emission control purpose, a position of a rear sensor in the warm part of the catalyst gives improved possibilities for oxygen buffer control during catalyst warming up conditions. This enhances balancing HC and NOx in an early phase. In addition, for OBD reasons it is possible to locate the sensor in any axial position in the catalyst, which improves design possibilities for cold start detection, even for single brick catalyst systems. The paper describes the construction of the catalyst with an integrated oxygen sensor.
Technical Paper

SCR and SCRi® as After-treatment Systems for Low CO2 and Low NOx Vehicles

2011-01-19
2011-26-0038
On one hand, latest worldwide emissions legislation developments aim to reduce NOx and Particulate Matter (PM) emissions of all diesel engines, while on the other hand lower fuel consumption diesel engines are still required for lower fleet average CO₂ emissions. As a consequence of the chosen CO₂ optimized combustion mode, the raw NOx emission increases and as such Selective Catalytic Reduction (SCR) technology will be the future choice for high efficiency NOx aftertreatment. This paper deals with SCR technology and its derivative SCRi® technology, when diesel particle reduction is required, especially for heavy-duty applications. Alongside the developed metal catalyst technologies, a complete SCR reducing agent dosing system is presented. Emission results gained with the SCR or SCRi® technologies on European commercial engines illustrate the potential of these technologies for conversion of NOx and PM emissions.
Technical Paper

Benefits of LS-Design™, a Structured Metal Foil for Two and Three Wheelers Catalyst Substrates, to Minimize Catalyst Volumes, PGM Loads and the Route Towards Low NOx Emissions

2011-10-06
2011-28-0042
More efficient and durable catalytic converters for the two- and three-wheeler industry in developing countries are required at an affordable cost to reduce vehicle emissions, to maintain them at a low level and therefore to participate in a cleaner and healthier environment. This particularly is true nowadays, because the demand and prices of Platinum Group Metal (PGM) for catalyst are continuously increasing due to i) the worldwide progressive implementation of motorcycles emission legislations similar to Euro 3 Stage requiring catalysts, ii) the need for non-road diesel vehicles to be equipped now with catalyst systems, and iii) the constant increase of the worldwide automobile market. A new generation of metallic substrates with structured foils for catalytic converters is proven to be capable of improving conversion behavior, even with smaller catalyst size.
Technical Paper

Investigation of Underbody Metal SCR Systems with Active Thermal Management: Experience Update

2013-01-09
2013-26-0048
The Selective Catalytic Reduction (SCR) is the main after-treatment solution for high efficient diesel engines under development to cope with future lower fuel consumption and NOx emissions requirements (EU6+ legislation). Exhaust gas temperatures are decreasing too, leading to new after-treatment system developments in a close coupled position. Nevertheless before all vehicle architectures allow it, SCR systems are and will still be installed in underbody position. The current paper deals with an underbody metal SCR after-treatment systems, which is capable of active thermal management, and an ultra-compact SCR dosing system. These technologies are described and emission results obtained on several application examples (from passenger cars to light duty commercial vehicles) are presented and discussed in conjunction with an effective active thermal management of the SCR function.
Technical Paper

Achieving BS-IV Emission Targets for Diesel Small Commercial Vehicle (SCV) with Close Coupled Advanced EnviCat® DOC and Coated PM Metalit® After - Treatment System

2013-01-09
2013-26-0054
Small Commercial Vehicle (SCV) is an emerging Commercial Vehicle (CV) segment both in India and throughout the world. Vehicles in this segment have diesel engine of capacity less than 1 l and GVW of less than 3.5 t. Normally for the CV, engines are tested on engine dynamometer for emission test, but SCV are tested on chassis dynamometer as they are classified as N1.1 class vehicles. Hence SCV have to follow same emission regulations as diesel passenger cars. The main challenge is to meet BS-IV NOx and PM emission target together with high torque optimization along with required durability targets. This paper addresses this challenge and reports the work carried out on an Indian SCV with 0.7 l naturally aspirated indirect injection diesel engine.
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