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Video

SCR Deactivation Study for OBD Applications

2012-06-18
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
Video

Brief Investigation of SCR High Temperature N2O Production

2012-06-18
Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.
Video

Evaluation of a NOx Transient Response Method for OBD of SCR Catalysts

2012-01-30
OBD requirements for aftertreatment system components require monitoring of the individual system components. One such component can be an NH3-SCR catalyst for NOx reduction. An OBD method that has been suggested is to generate positive or negative spikes in the inlet NH3 concentration, and monitor the outlet NOx transient response. A slow response indicates that the catalyst is maintaining its NH3 storage capacity, and therefore it is probably not degraded. A fast response indicates the catalyst has lost NH3 storage capacity, and may be degraded. The purpose of the work performed at Southwest Research Institute was to assess this approach for feasibility, effectiveness and practicality. The presentation will describe the work performed, results obtained, and implications for applying this method in test laboratory and real-world situations. Presenter Gordon J. Bartley, Southwest Research Institute
Technical Paper

The Effect of Hydrogen Enrichment on EGR Tolerance in Spark Ignited Engines

2007-04-16
2007-01-0475
Small (up to 1% by volume) amounts of hydrogen (H2) were added to the intake charge of a single-cylinder, stoichiometric spark ignited engine to determine the effect of H2 addition on EGR tolerance. Two types of tests were performed at 1500 rpm, two loads (3.1 bar and 5.5 bar IMEP), two compression ratios (11:1 and 14:1) and with two fuels (gasoline and natural gas). The first test involved holding EGR level constant and increasing the H2 concentration. The EGR level of the engine was increased until the CoV of IMEP was > 5% and then small amounts of hydrogen were added until the total was 1% by volume. The effect of increasing the amount of H2 on engine stability was measured along with combustion parameters and engine emissions. The results showed that only a very small amount of H2 was necessary to stabilize the engine. At amounts past that level, increasing the level of H2 had no or only a very small effect.
Technical Paper

The Potential for Achieving Low Hydrocarbon and NOx Exhaust Emissions from Large Light-Duty Gasoline Vehicles

2007-04-16
2007-01-1261
Two large, heavy light-duty gasoline vehicles (2004 model year Ford F-150 with a 5.4 liter V8 and GMC Yukon Denali with a 6.0 liter V8) were baselined for emission performance over the FTP driving cycle in their stock configurations. Advanced emission systems were designed for both vehicles employing advanced three-way catalysts, high cell density ceramic substrates, and advanced exhaust system components. These advanced emission systems were integrated on the test vehicles and characterized for low mileage emission performance on the FTP cycle using the vehicle's stock engine calibration and, in the case of the Denali, after modifying the vehicle's stock engine calibration for improved cold-start and hot-start emission performance.
Technical Paper

Performance Test Results of a New On Board Emission Measurement System Conformed with CFR Part 1065

2007-04-16
2007-01-1326
A new on-board portable emission measurement system (PEMS) for gaseous emissions has been designed and developed to meet CFR Part 1065 requirements. The new system consists of a heated flame ionization detector (HFID) for the measurement of total hydrocarbon, a heated chemiluminescence detector (HCLD) for the measurement of NOx, and a heated non-dispersive infra-red detector (HNDIR) for the measurement of CO and CO2. The oxygen interference and relative sensitivity of several hydrocarbon components have been optimized for the HFID. The CO2 and H2O quenching effect on the HCLD have been compensated using measured CO2 and H2O concentration. The spectral overlap and molecular interaction of H2O on the HNDIR measurement has also been compensated using an independent H2O concentration measurement. The basic performance of the new on-board emission measurement system has been verified accordingly with CFR part 1065 and all of the performances have met with CFR part 1065 requirement.
Technical Paper

The Use of Radioactive Tracer Technology to Measure Real-Time Wear in Engines and Other Mechanical Systems

2007-04-16
2007-01-1437
Radioactive tracer technology (RATT™) is an important tool for measuring real-time wear in operating engines and other mechanical systems. The use of this technology provides important wear information that is not available by other, more conventional wear measurement methods. The technology has advanced to the point where several components can be interrogated simultaneously, and new methods have extended the method to materials that are normally not amenable to radioactive tracer evaluation. In addition, sensitivity has increased so that the onset of wear can be detected long before practical with non-tracer methods. This improves the ability to measure and determine cause and effect relationships, thus providing a better understanding of wear responses to specific operating conditions and to changes in operating conditions. This paper reviews the radioactive tracer process and recent improvements that have extended its reach in both automotive and non-automotive applications.
Technical Paper

Investigation of Alternative Combustion Crossing Stoichiometric Air Fuel Ratio for Clean Diesels

2007-07-23
2007-01-1840
Alternative combustion crossing stoichiometric air fuel ratio was investigated to utilize a 4-way catalyst system with LNT (lean NOx trap). The chemical mechanism of restricting soot formation reactions with low combustion temperature was combined with the physical mechanism of reducing smoke by lowering local equivalence ratio to enable low smoke rich and near rich combustion. A new combustion chamber for spatially and timely mixture formation phasing was developed to combine the two mechanisms and allow smooth EGR changing over a wide load range. Through this investigation, rich and near rich combustion to effectively utilize a 4-way catalyst system was realized. In addition, conditions suitable for LNT sulfur regeneration were realized from light to medium load.
Technical Paper

Engine Crankshaft Position Tracking Algorithms Applicable for Given Arbitrary Cam- and Crank-Shaft Position Signal Patterns

2007-04-16
2007-01-1597
This paper describes algorithms that can recognize and track the engine crankshaft position for arbitrary cam- and crank-shaft tooth wheel patterns in both steady-state and transient operating conditions. Crankshaft position tracking resolution is adjustable to accommodate different application requirements. The instantaneous crankshaft position information provided by the position tracking module form the basis for crankshaft angle domain (CAD) engine control and measurement functions such as precise injection / ignition controls and on-line cylinder pressure CAD analyses. The algorithms described make reconfiguration of the tracking module for different and arbitrary cam- and crank-shaft tooth wheel patterns very easy, which is valuable especially for prototyping engine control systems. The effectiveness of the algorithms is shown using test engines with different cam and crank signal patterns.
Technical Paper

US 2010 Emissions Capable Camless Heavy-Duty On-Highway Natural Gas Engine

2007-07-23
2007-01-1930
The goal of this project was to demonstrate a low emissions, high efficiency heavy-duty on-highway natural gas engine. The emissions targets for this project are to demonstrate US 2010 emissions standards on the 13-mode steady state test. To meet this goal, a chemically correct combustion (stoichiometric) natural gas engine with exhaust gas recirculation (EGR) and a three way catalyst (TWC) was developed. In addition, a Sturman Industries, Inc. camless Hydraulic Valve Actuation (HVA) system was used to improve efficiency. A Volvo 11 liter diesel engine was converted to operate as a stoichiometric natural gas engine. Operating a natural gas engine with stoichiometric combustion allows for the effective use of a TWC, which can simultaneously oxidize hydrocarbons and carbon monoxide and reduce NOx. High conversion efficiencies are possible through proper control of air-fuel ratio.
Technical Paper

Impact of Lubricant Oil on Regulated Emissions of a Light-Duty Mercedes-Benz OM611 CIDI-Engine

2001-05-07
2001-01-1901
The Partnership for a New Generation Vehicle (PNGV) has identified the compression-ignition, direct-injection (CIDI) engine as a promising technology in meeting the PNGV goal of 80 miles per gallon for a prototype mid-size sedan by 2004. Challenges remain in reducing the emission levels of the CIDI-engine to meet future emission standards. The objective of this project was to perform an initial screening of crank case lubricant contribution to regulated engine-out emissions, particularly when low particulate forming diesel fuel formulations are used. The test engine was the Mercedes-Benz OM611, the test oils were a mineral SAE 5W30, a synthetic (PAO based) SAE 5W30, and a synthetic (PAO based) SAE 15W50, and the test fuels were a California-like certification fuel and an alternative oxygenated diesel fuel.
Technical Paper

Oxygenates screening for AdvancedPetroleum-Based Diesel Fuels: Part 2. The Effect of Oxygenate Blending Compounds on Exhaust Emissions

2001-09-24
2001-01-3632
Adding oxygenates to diesel fuel has shown the potential for reducing particulate (PM) emissions in the exhaust. The objective of this study was to select the most promising oxygenate compounds as blending components in diesel fuel for advanced engine testing. A fuel matrix was designed to consider the effect of molecular structure and boiling point on the ability of oxygenates to reduce engine-out exhaust emissions from a modern diesel engine. Nine test fuels including a low-sulfur (∼1 ppm), low-aromatic hydrocracked base fuel and 8 oxygenate-base fuel blends were utilized. All oxygenated fuels were formulated to contain 7% wt. of oxygen. A DaimlerChrysler OM611 CIDI engine for light-duty vehicles was controlled with a SwRI Rapid Prototyping Electronic Control System. The base fuel was evaluated in four speed-load modes and oxygenated blends only in one mode. Each operating mode and fuel combination was run in triplicate.
Technical Paper

Heavy-Duty Diesel Truck In-Use Emission Test Program for Model Years 1950 through 1975

2001-03-05
2001-01-1327
Criteria pollutants were measured from ten Class 7 and 8 (i.e., gross vehicle weights > 33,000 lb) heavy-duty diesel trucks with engine model years between 1953 and 1975. The data was used by EPA to estimate that period's particulate matter emission rates for these type engines and will be used to develop dose response relationships with existing epidemiological data. Particulate samples were analyzed for sulfate and volatile organic fraction. Carbon soot was estimated. The trucks had particulate emissions of 2 to 10 g/mi as compared to 1 to 6 g/mi for trucks with model year engines from 1975 through the mid-1980s, and less than 1 g/mi for post-1988 trucks.
Technical Paper

Aging of Zeolite Based Automotive Hydrocarbon Traps

2007-04-16
2007-01-1058
This paper analyzes the aging of zeolite based hydrocarbon traps to guide development of diagnostic algorithms. Previous research has shown the water adsorption ability of zeolite ages along with the hydrocarbon adsorption ability, and this leads to a possible diagnostic algorithm: the water concentration in the exhaust can be measured and related to aging. In the present research, engine experiments demonstrate that temperature measurements are also related to aging. To examine the relationship between temperature-based and moisture-based diagnostic algorithms, a transient, nonlinear heat and mass transfer model of the exhaust during cold-start is developed. Despite some idealizations, the model replicates the qualitative behavior of the exhaust system. A series of parametric studies reveals the sensitivity of the system response to aging and various noise factors.
Technical Paper

Validation Method for Diesel Particulate Filter Durability

2007-10-29
2007-01-4086
The diesel particulate filter (DPF) is a critical aftertreatment device for control of particulate matter (PM) emissions from a diesel engine. DPF survivability is challenged by several key factors such as: excessive thermal stress due to DPF runaway regenerations (or uncontrolled regeneration) may cause DPF substrate and washcoat failure. Catalyst poisoning elements from the diesel fuel and engine oil may cause performance degradation of the catalyzed DPF. Harsh vibration from the powertrain, as well as from the road surface, may lead to mechanical failure of the substrate and/or the matting material. Evaluations of these important validation parameters were performed.
Technical Paper

Effect of Contamination on Filter Performance

2007-10-29
2007-01-4139
Excessive wear and malfunctions in fluid power handling systems are often caused by contaminants or small particles that may be built-in, self-generated, or ingested from the environment. Filtration subsystems in such systems are designed to prevent these problems from happening. However, machine performance degradation, shortened service life, and even catastrophic failures are occasionally encountered in the real world. Then, what is the missing linkage? This paper tries to address the issue using a multi-disciplinary approach that employs failure analyses, laboratory experimentation, predictive correlation, and concurrent engineering with an emphasis on contaminant characterization and filtration strategies. Practical contamination analysis methodologies are discussed via examples and case studies.
Technical Paper

Feasibility Investigation of a High-Efficiency NOx Aftertreatment System for Diesel Engines

2007-10-29
2007-01-3983
A high-efficiency NOx aftertreatment system has been proposed for use in Diesel engines. This system includes a Lean NOx Trap (LNT) in series with a Selective Catalyst Reduction (SCR) catalyst [6], [7], [8], and is hereinafter referred to as the LNT-SCR system. The combined LNT-SCR system can potentially overcome many of the drawbacks of LNT-only and SCR-only operation and achieve very high NOx conversion efficiency without external addition of ammonia (or urea). A laboratory test procedure was developed to validate the LNT-SCR system concept, and a series of tests was conducted to test the NOx conversion of this system under various conditions. A Synthetic Gas Reactor (SGR) system was modified to accommodate LNT and SCR catalyst cores and synthetic gas mixtures were used to simulate rich-lean regeneration cycles from a diesel engine. A Fourier Transform Infrared (FTIR) system was used to measure gas compositions within the LNT-SCR system.
Technical Paper

Effects of Water-Fuel Emulsions on Spray and Combustion Processes in a Heavy-Duty DI Diesel Engine

2002-10-21
2002-01-2892
Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.
Technical Paper

A New Approach to Improving Fuel Economy and Performance Prediction through Coupled Thermal Systems Simulation

2002-03-04
2002-01-1208
Vehicle designers make use of vehicle performance programs such as RAPTOR™ to predict the performance of concept vehicles over ranges of industry standard drive cycles. However, the accuracy of such predictions may be greatly influenced by factors requiring more specialist simulation capabilities. For example, fuel economy prediction will be heavily influenced by the performance of the engine cooling system and its impact on the vehicle's aerodynamic drag, and the load from the air-conditioning system. To improve the predictions, specialist simulation capabilities need to be applied to these aspects, and brought together with the vehicle performance calculations through co-simulation. This paper describes the approach used to enable this cosimulation and the benefits achieved by the vehicle designer.
Technical Paper

42 Catalytic Reduction of Marine Sterndrive Engine Emissions

2002-10-29
2002-32-1811
A 2001 General Motors 4.3 liter V-6 marine engine was baseline emissions tested and then equipped with catalysts. Emission reduction effects of exhaust gas recirculation (EGR) were also explored. Because of a U.S. Coast Guard requirement that inboard engine surface temperatures be kept below 200°F, the engine's exhaust system, including the catalysts, was water-cooled. Engine emissions were measured using the ISO-8178-E4 5-mode steady-state test for recreational marine engines. In baseline configuration, the engine produced 16.6 g HC+NOx/kW-hr, and 111 g CO/kW-hr. In closed-loop control with catalysts, HC+NOx emissions were reduced by 75 percent to 4.1 g/kW-hr, and CO emissions were reduced by 36 percent to 70 g/kW-hr of CO. The catalyzed engine was then installed in a Sea Ray 190 boat, and tested for water reversion on both fresh and salt water using National Marine Manufacturers Association procedures.
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