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In spark-ignited direct-injected engines, the formation of fuel pools on the piston is one of the major promoters of unburnt hydrocarbons and soot: in order to comply with the increasingly stringent emission regulations (EU6 and forthcoming), it is therefore necessary to limit fuel deposit formation. The combined use of advanced experimental techniques and detailed 3D-CFD simulations can help to understand the mechanisms driving fuel pool formation. In the paper, a combined experimental and numerical characterization of pool formation in a GDI engine is carried out to investigate and understand the complex interplay of all the mentioned factors. In particular, a low-load low-rpm engine operation is investigated for different ignition phasing, and the impact of both fuel formulation and instantaneous piston temperature variations in the CFD analyses are evaluated.