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This paper presents the modeling of the transient phase of catalyst heating on a high-performance turbocharged spark ignition engine with the aim to accurately predict the exhaust thermal energy available at the catalyst inlet and to provide a “virtual test rig” to assess different design and calibration options. The entire transient phase, starting from the engine cranking until the catalyst warm-up is completed, was taken into account in the simulation, and the model was validated using a wide data-set of experimental tests. The first step of the modeling activity was the combustion analysis during the transient phase: the burn rate was evaluated on the basis of experimental in-cylinder pressure data, considering both cycle-to-cycle and cylinder-to-cylinder variations.