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Particulate and manganese mass emissions have been measured as a function of mileage for four Escort and four Explorer vehicles using 1) MMT (Methylcyclopentadienyl Manganese Tricarbonyl) added to the gasoline at 1/32 g Mn/gal and 2) gasoline without MMT. The MMT was used in half of the fleet starting at 5,000 miles. The vehicles were driven on public roads at an average speed of 54 mph to accumulate mileage. This report describes the particulate and manganese emissions, plus emissions of four air toxics at 5,000, 20,000, 55,000, 85,000 and 105,000 miles. Four non-regulated emissions were measured and their average values for vehicles without MMT were 0.6 mg/mi for formaldehyde, 0.7 mg/mi for 1,3-butadiene, 9 mg/mi for benzene and 12 mg/mi for toluene. Corresponding values for MMT-fueled vehicles were between 1.5 and 2.4 times higher.

It is frequently useful to calculate the theoretical composition of the major components of vehicle exhaust. A software program has been written in Basic (or Quick Basic) which allows the convenient calculation of volume percents of CO, CO2, O2, H2, and H2O from fuel composition (H/C and O/C ratios), the water content (dew point) of the combustion air, and a chosen stoichiometry (air/fuel ratio). The program considers the Water Gas Shift reaction and the production of hydrogen under fuel rich conditions. The program is valid for both standard gasolines and oxygenated blends. Vehicle emissions data, collected to compare values calculated by the program with actual experimentally determined values from vehicle exhaust, show good agreement for measurements made at a series of air/fuel ratios ranging from lambda of 0.85-1.2.