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Internal combustion (IC) engines fueled by hydrogen are among the most efficient means of converting chemical energy to mechanical work. The exhaust has near-zero carbon-based emissions, and the engines can be operated in a manner in which pollutants are minimal. In addition, in automotive applications, hydrogen engines have the potential for efficiencies higher than fuel cells.[1] In addition, hydrogen engines are likely to have a small increase in engine costs compared to conventionally fueled engines. However, there are challenges to using hydrogen in IC engines. In particular, efficient combustion of hydrogen in engines produces nitrogen oxides (NOx) that generally cannot be treated with conventional three-way catalysts. This work presents the results of experiments which consider changes in direct injection hydrogen engine design to improve engine performance, consisting primarily of engine efficiency and NOx emissions.

A single-cylinder Direct Injection Spark Ignition (DISI) engine with optical access was used to investigate the effects of ethanol/gasoline blends on in-cylinder formation of particulate matter (PM) and fuel spray characteristics. Indolene was used as a baseline fuel and two blends of 50% and 85% ethanol (by volume, balance indolene) were investigated. Time resolved thermal radiation (incandescence/natural luminosity) of soot particles and fuel spray characteristics were recorded using a high speed camera. The images were analyzed to quantify soot formation in units of relative image intensity as a function of important engine operating conditions, including ethanol concentration in the fuel, fuel injection timing (250, 300 and 320° bTDC), and coolant temperature (25°C and 90°C). Spatially-integrated incandescence was used as a metric to quantify the level of in-cylinder PM formed at the different operating conditions.

Injecting liquid water into a fuel/air charge is a means to reduce NOx emissions. Such strategies are particularly important to hydrogen internal combustion engines, as engine performance (e.g., maximum load) can be limited by regulatory limits on NOx. Experiments were conducted in this study to quantify the effects of direct injection of water into the combustion chamber of a port-fueled, hydrogen IC engine. The effects of DI water injection on NOx emissions, load, and engine efficiency were determined for a broad range of water injection timing. The amount of water injected was varied, and the results were compared with baseline data where no water injection was used. Water injection was a very effective means to reduce NOx emissions. Direct injection of water into the cylinder reduced NOx emissions by 95% with an 8% fuel consumption penalty, and NOx emissions were reduced by 85% without any fuel consumption penalty.