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A model of Ford's current FTP based OBD-II catalyst monitor has been developed and used in determining the optimal monitored catalyst volume for several LEV applications. The model predictions were found to agree reasonably well with the available experimental data. Furthermore, the results of this study indicate that the optimal monitored catalyst volume for meeting LEV requirements is vehicle application specific. As a result, it is concluded that a general guideline for sizing of the monitored catalyst volume for LEVs will most likely be inadequate and could result in grossly suboptimal catalyst monitor function for some applications. The model which is described in this paper offers a potentially more effective means of determining the best monitored catalyst volume for a given vehicle application. It should be possible to utilize this model during the early phase of a vehicle program in order to provide for the optimal packaging of the catalyst monitor sensor (CMS).

An improved process for determining oven aging times and temperatures for OBD-II threshold catalyst aging has been developed. The new process makes use of a catalyst model along with a kinetic data base in order to project vehicle tailpipe emissions for oven aged catalyst systems. The catalyst oven aging time and temperature required for a given vehicle can be specified such that the actual HC tailpipe emissions are within 15-20% of the desired threshold emission level. It is believed that this process could greatly reduce the need for much of the trial and error iteration which is currently associated with obtaining threshold catalysts for OBD-II calibration purposes.

The effect of fuel sulfur on the dual HEGO sensor OBD-II catalyst monitor has been investigated. Laboratory studies revealed two competing effects of the fuel sulfur on the operation of the catalyst monitor: 1. the loss of catalyst oxygen storage capacity, and 2. the degradation in the response rate of the rear HEGO sensor. The magnitude of the loss in catalyst OSC relative to the increase in rear HEGO sensor response time determined whether the rear HEGO sensor index increased, decreased, or remained constant as the fuel sulfur level was increased. The effect of fuel sulfur on tailpipe emissions and the catalyst monitor was also measured for two LEVs equipped with Pd-only catalyst technology (a 1997MY Escort and a 1998MY Crown Victoria). For both vehicles, the effect of the fuel sulfur on the rear HEGO sensor response characteristics dominated; as the fuel sulfur level was increased, tailpipe emissions increased, but the rear HEGO sensor index decreased.