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A numerical investigation on a series of Diesel spray experiments in constant-volume vessels is proposed. Non reacting conditions were used to assess the spray models and to determine the grid size required to correctly predict the fuel-air mixture formation process. To this end, not only computed liquid and vapor penetrations were compared with experimental data, but also a detailed comparison between computed and experimental mixture fraction distributions was performed at different distances from the injector. Grid dependency was reduced by introducing an Adaptive Local Mesh Refinement technique (ALMR) with an arbitrary level of refinement. Once the capabilities of the current implemented spray models have been assessed, reacting conditions at different ambient densities and temperatures were considered. A Perfectly Stirred Reactor (PSR) combustion model, based on a direct integration of complex chemistry mechanisms over a homogenous cell, was adopted.

The s.i. combustion process and its corresponding pollutant formation are investigated by means of a quasiD approach and a CFD model. This work has been motivated by the need to better understand the reliability of such models and to assess their accuracies with respect to the prediction of engine performances and emissions. An extended dissertation about the fundamental mechanisms governing the pollutant formation in the turbulent premixed combustion which characterizes the s.i. engines is given. The conclusion of such analysis is the definition of a new reduced chemical scheme, based on the application of partial-equilibrium and steady-state assumptions for the radicals and the solution of a transport equation for each specie which is kinetically controlled. For this purpose the CFD code OpenFOAM [1, 2, 3] and the thermo-fluid dynamic code GASDYN [4, 5] have been applied and enhanced.

Aim of this work is to present and discuss the possibility and the limits of two zone models for spark-ignition engines using a detailed kinetic scheme for the characterization of the evolution of the air-fuel mixture, while an equilibrium approach is used for the burnt zone. Simple experimental measurements of knocking tendency of different fuels in ideal reactors, such as rapid compression machines and shock tube reactors, cannot be directly used for the analysis of octane numbers and sensitivity of hydrocarbon mixtures. Thus a careful investigation is very useful, not only of the combustion chamber behavior, including the modelling of the turbulent flame front propagation, but also of the fluid dynamic behavior of the intake and exhaust system, accounting for the volumetric efficiency of the engine.