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Monitoring NO2 Production of a Diesel Oxidation Catalyst

2012-01-24
A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.
Journal Article

Effects of Secondary Air Injection During Cold Start of SI Engines

2010-10-25
2010-01-2124
An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.
Journal Article

Speciated Engine-Out Organic Gas Emissions from a PFI-SI Engine Operating on Ethanol/Gasoline Mixtures

2009-11-02
2009-01-2673
Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.
Journal Article

Ash Effects on Diesel Particulate Filter Pressure Drop Sensitivity to Soot and Implications for Regeneration Frequency and DPF Control

2010-04-12
2010-01-0811
Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.
Journal Article

Study of On-Board Ammonia (NH3) Generation for SCR Operation

2010-04-12
2010-01-1071
Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.
Journal Article

Reduction of Cold-Start Emissions through Valve Timing in a GDI Engine

2016-04-05
2016-01-0827
This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.
Journal Article

Lubricant-Derived Ash Impact on Gasoline Particulate Filter Performance

2016-04-05
2016-01-0942
The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.
Journal Article

Assessment of Gasoline Direct Injection Engine Cold Start Particulate Emission Sources

2017-03-28
2017-01-0795
The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.
Journal Article

Analysis of Ash in Low Mileage, Rapid Aged, and High Mileage Gasoline Exhaust Particle Filters

2017-03-28
2017-01-0930
To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.
Journal Article

A Comparison of Spray-Guided Stratified-Charge Combustion Performance with Outwardly-Opening Piezo and Multi-Hole Solenoid Injectors

2011-04-12
2011-01-1217
This investigation was aimed at measuring the relative performance of two spray-guided, single-cylinder, spark-ignited direct-injected (SIDI) engine combustion system designs. The first utilizes an outwardly-opening poppet, piezo-actuated injector, and the second a conventional, solenoid operated, inwardly-opening multi-hole injector. The single-cylinder engine tests were limited to steady state, warmed-up conditions. The comparison showed that these two spray-guided combustion systems with two very different sprays had surprisingly close results and only differed in some details. Combustion stability and smoke emissions of the systems are comparable to each other over most of the load range. Over a simulated Federal Test Procedure (FTP) cycle, the multi-hole system had 15% lower hydrocarbon and 18% lower carbon monoxide emissions.
Journal Article

Particulate Matter Emissions from a Direct Injection Spark Ignition Engine under Cold Fast Idle Conditions for Ethanol-Gasoline Blends

2011-04-12
2011-01-1305
The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.
Journal Article

Fatigue Behavior and Life Prediction for Aluminum Castings in the Absence of Casting Flaws

2011-04-12
2011-01-0193
Cast aluminum alloys are increasingly used in cyclically loaded automotive structural applications for light weight and fuel economy. The fatigue resistance of aluminum castings strongly depends upon the presence of casting flaws and characteristics of microstructural constituents. The existence of casting flaws significantly reduces fatigue crack initiation life. In the absence of casting flaws, however, crack initiation occurs at the fatigue-sensitive microstructural constituents. Cracking and debonding of large silicon (Si) and Fe-rich intermetallic particles and crystallographic shearing from persistent slip bands in the aluminum matrix play an important role in crack initiation. This paper presents fatigue life models for aluminum castings free of casting flaws, which complement the fatigue life models for aluminum castings containing casting flaws published in [1].
Journal Article

Fundamental Approach to Investigate Pre-Ignition in Boosted SI Engines

2011-04-12
2011-01-0340
A comprehensive experimental and theoretical approach was undertaken to understand the phenomenon of pre-ignition and to assess parameters to improve or even eliminate it completely. Oil mixing with fuel was identified as the leading theory of self ignition of the fuel. End of compression temperature has to meet a minimum level for pre-ignition to take place. In this work a comprehensive list of parameters were identified that have a direct and crucial role in the onset of pre-ignition including liner wetting, injection targeting, stratification, mixture motion and oil formulation. Many secondary effects were identified including ring dynamics, ring tension, spark plug electrode temperature and coolant temperature. CFD has been extensively used to understand test results including wall film, A/F ratio distribution and temperature at the end of compression when looked at in the context of fuel evaporation and mixing.
Journal Article

Challenges in Real Time Controls Simulation (Hardware-In-the-Loop) in Active Safety for Subsystem Level Software Verification

2011-04-12
2011-01-0450
As the new features for driver assistance and active safety systems are growing rapidly in vehicles, the simulation within a virtual environment has become a necessity. The current active safety system consists of Electronic Control Units (ECUs) which are coupled to camera and radar sensors. Two methods of implementation exists, integrated sensors with control modules or separation of sensors form control modules. The subsystem integration testing poses new challenges for virtual environment for simulation of active safety features. The comprehensive simulation environment for integration testing consists of chassis controls, powertrain, driver assistance, body and displays controllers. Additional complexity in the system is the serial communication strategy. Multiple communication protocols such as GMLAN, LIN, standard CAN, and Flexray could be present within the same vehicle topology.
Journal Article

Vehicle Safety Communications - Applications: System Design & Objective Testing Results

2011-04-12
2011-01-0575
The USDOT and the Crash Avoidance Metrics Partnership-Vehicle Safety Communications 2 (CAMP-VSC2) Consortium (Ford, GM, Honda, Mercedes, and Toyota) initiated, in December 2006, a three-year collaborative effort in the area of wireless-based safety applications under the Vehicle Safety Communications-Applications (VSC-A) Project. The VSC-A Project developed and tested communications-based vehicle safety systems to determine if Dedicated Short Range Communications (DSRC) at 5.9 GHz, in combination with vehicle positioning, would improve upon autonomous vehicle-based safety systems and/or enable new communications-based safety applications.
Journal Article

Modeling/Analysis of Pedestrian Back-Over Crashes from NHTSA's SCI Database

2011-04-12
2011-01-0588
An analysis of the first 35 back-over crashes reported by NHTSA's Special Crash Investigations unit was undertaken with two objectives: (1) to test a hypothesized classification of backing crashes into types, and (2) to characterize scenario-specific conditions that may drive countermeasure development requirements and/or objective test development requirements. Backing crash cases were sorted by type, and then analyzed in terms of key features. Subsequent modeling of these SCI cases was done using an adaptation of the Driving Reliability and Error Analysis Methodology (DREAM) and Cognitive Reliability and Error Analysis Methodology (CREAM) (similar to previous applications, for instance, by Ljung and Sandin to lane departure crashes [10]), which is felt to provide a useful tool for crash avoidance technology development.
Journal Article

Vehicle Safety Communications - Applications: Multiple On-Board Equipment Testing

2011-04-12
2011-01-0586
The United States Department of Transportation (USDOT) and the Crash Avoidance Metrics Partnership-Vehicle Safety Communications 2 (CAMP-VSC2) Consortium (Ford, General Motors, Honda, Mercedes-Benz, and Toyota) initiated, in December 2006, a three-year collaborative effort in the area of wireless-based safety applications under the Vehicle Safety Communications-Applications (VSC-A) Project. The VSC-A Project developed and tested Vehicle-to-Vehicle (V2V) communications-based safety systems to determine if Dedicated Short Range Communications (DSRC) at 5.9 GHz, in combination with vehicle positioning, would improve upon autonomous vehicle-based safety systems and/or enable new communications-based safety applications.
Journal Article

Development of a Camera-Based Forward Collision Alert System

2011-04-12
2011-01-0579
Forward Collision Alert (or Forward Collision Warning) systems provide alerts intended to assist drivers in avoiding or mitigating the harm caused by rear-end crashes. These systems currently use front-grille mounted, forward-looking radar devices as the primary sensor. In contrast, Lane Departure Warning (LDW) systems employ forward-looking cameras mounted behind the windshield to monitor lane markings ahead and warn drivers of unintended lane violations. The increasing imaging sensor resolution and processing capability of forward-looking cameras, as well recent important advances in machine vision algorithms, have pushed the state-of-the-art for camera-based features. Consequently, camera-based systems are emerging as a key crash avoidance system component in both a primary and supporting sensing role. There are currently no production vehicles with cameras used as the sole FCA sensing device.
Journal Article

Reliability and Safety/Integrity Analysis for Vehicle-to-Vehicle Wireless Communication

2011-04-12
2011-01-1045
Vehicle-to-vehicle (V2V) and vehicle-to-infrastructure (V2I) communications are gaining increasing importance in automotive research and engineering domains. The novel communication scheme is targeted to improve driver safety (e.g., forward collision warnings) and comfort (e.g., routing to avoid congestion, automatic toll collection, etc.). Features exploiting these communication schemes are still in the early stages of research and development. However, growing attention to system wide infrastructure - in terms of OEM collaboration on interface standardization, protocol standardization, and government supported road/wireless infrastructure - will lead to popularity of such features in the future. This paper focuses on evaluating reliability and safety/integrity of data communicated over the wireless channels for early design verification. Analysis of a design can be done based on formal models, simulation, emulation, and testing.
Journal Article

Analysis of Pre-Crash Data Transferred over the Serial Data Bus and Utilized by the SDM-DS Module

2011-04-12
2011-01-0809
The primary function of an airbag control module is to detect crashes, discriminate and predict if a deployment is necessary, then deploy the restraint systems including airbags and where applicable, pretensioners. At General Motors (GM), the internal term for airbag control module is Sensing and Diagnostic Module (SDM). In the 1994 model year, GM introduced its SDM on some of its North American airbag-equipped vehicles. A secondary function of that SDM and all subsequent SDMs is to record crash related data. This data can include data regarding impact severity from internal accelerometers and pre-crash vehicle data from various chassis and powertrain modules. Previous researchers have addressed the accuracy of both the velocity change data, recorded by the SDM, and the pre-crash data, but the assessment of the timing of the pre-crash data has been limited to a single family of modules (Delphi SDM-G).
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