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Technical Paper

The Effect of Pt-Pd Ratio on Oxidation Catalysts Under Simulated Diesel Exhaust

2011-04-12
2011-01-1134
With a tighter regulatory environment, reduction of hydrocarbon emissions has emerged as a major concern for advanced low-temperature combustion engines. Currently precious metal-based diesel oxidation catalysts (DOC) containing platinum (Pt) and palladium (Pd) are most commonly used for diesel exhaust hydrocarbon oxidation. The efficiency of hydrocarbon oxidation is greatly enhanced by employing both Pt and Pd together compared to the case with Pt or Pd alone. However, there have been few systematic studies to investigate the effects of the ratio of platinum to palladium on catalytic oxidation over the DOC. The present study illustrates the relationship between the Pt-Pd ratio and catalyst activity and stability by evaluating a series of catalysts with various Pt to Pd ratios (1:0, 7:1, 2:1, 1:2, 1:5, 0:1). These catalysts were tested for their CO and hydrocarbon light-off temperatures under simulated conditions where both unburned and partially burned hydrocarbons were present.
Technical Paper

Three-Way Catalyst Design for Urealess Passive Ammonia SCR: Lean-Burn SIDI Aftertreatment System

2011-04-12
2011-01-0306
Lean-burn SIDI engine technology offers improved fuel economy; however, the reduction of NOx during lean-operation continues to be a major technical hurdle in the implementation of energy efficient technology. There are several aftertreatment technologies, including the lean NOx trap and active urea SCR, which have been widely considered, but they all suffer from high material cost and require customer intervention to fill the urea solution. Recently reported passive NH₃-SCR system - a simple, low-cost, and urea-free system - has the potential to enable the implementation of lean-burn gasoline engines. Key components in the passive NH₃-SCR aftertreatment system include a close-coupled TWC and underfloor SCR technology. NH₃ is formed on the TWC with short pulses of rich engine operation and the NH₃ is then stored on the underfloor SCR catalysts.
Technical Paper

Electrically Heated Catalysts for Cold-Start Emissions in Diesel Aftertreatment

2012-04-16
2012-01-1092
With a tighter regulatory environment, reduction of hydrocarbon (HC) and NOx emissions during cold-start has emerged as a major challenge for diesel engines. In the complex diesel aftertreatment system, more than 90% of engine-out NOx is removed in the underfloor SCR. However, the combination of low temperature exhaust and heat sink over DOC delays the SCR light-off during the cold start. In fact, the first 350 seconds during the cold light-duty FTP75 cycle contribute more than 50% of the total NOx tailpipe emission due to the low SCR temperature. For a fast SCR light-off, electrically heated catalyst (EHC) technology has been suggested to be an effective solution as a rapid warm-up strategy. In this work, the EHC, placed in front of DOC, utilizes both electrical power and hydrocarbon fuel. The smart energy management during the cold-start was crucial to optimize the EHC integrated aftertreatment system.
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